SUBSTITUTED THIOPYRIDINES
    193.
    发明专利

    公开(公告)号:CA2265483A1

    公开(公告)日:1998-03-19

    申请号:CA2265483

    申请日:1997-08-29

    Applicant: BASF AG

    Abstract: Substituted thiopyridines having general formula (I), wherein n means 1 or 2, R1 means chlorine, C1-C3 fluoralkyl, nitro or methylsulfonyl; a nonsubstituted or halogen, C1-C4 - alkoxy, C1-C4 aloxycarbonyl, di- (C1-C4-alkylamino) carbonyl, cyano or nitro substituted C1-C10-Alkyl, C2-C10-alkenyl or C2-C10 alkinyl radical, a C3-C8-cycloalkyl radical or a non-substituted in the phenyl part or hydrogen, C1-C3-alkyl, C1-C3-alkoxy, trifluormethyl, cyano or nitro substituted C1-C4-alkylene phenyl, phenyl or naphthyl radical.

    PREPARATION OF NITROBIPHENYLS
    195.
    发明专利

    公开(公告)号:CA2248157A1

    公开(公告)日:1997-09-18

    申请号:CA2248157

    申请日:1997-03-06

    Applicant: BASF AG

    Abstract: The invention concerns a process for preparing nitrobiphenylene of formula (I) wherein m stands for 1 or 2, R means halogen, R' or OR', R' being a C-organic group which can carry groups which are inert in the reaction conditions, n stands for 0, 1, 2 or 3 and, if n is 2 or 3, the R groups can also be different. According to the invention, a chloronitrobenzene of formula (II) is reacted in the presence of a palladium catalyst and a base in a solvent with a phenyl boric acid (IIIa), one of its alkyl esters of formula (IIIb), R1 meaning C1-C6 alkyl, or one of its anhydrides. The compounds (I) are suitable as initial products for biphenylamines which are in turn intermediate products for fungicidal plant-growth substances.

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