公开(公告)号：WO2013057036A1

公开(公告)日：2013-04-25

申请号：PCT/EP2012/070136

申请日：2012-10-11

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： NIFANT'EV, Ilya ,  MIGNOGNA, Alessandro ,  BAGROV, Vladimir ,  ESPOSITO, Simona ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  TOLORAYA, Sophia A.

IPC: C08F4/651 ,  C08F10/00 ,  C08F4/654

CPC classification number: C08F4/6498 ,  C08F10/00 ,  C08F4/6543 ,  C08F4/651

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R 12 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, with the proviso that R groups cannot be hydrogen and that the carboxylate groups are in trans configuration with respect to each other.

Abstract translation: 用于包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分其中R至R12基团彼此相同或不同的是氢，卤素或C 1 -C 15烃基，任选地 含有选自卤素，P，S，N和Si的杂原子，条件是R基团不能是氢，并且羧酸酯基团相对于反式构型。

公开(公告)号：WO2013057026A2

公开(公告)日：2013-04-25

申请号：PCT/EP2012/070071

申请日：2012-10-10

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MIGNOGNA, Alessandro ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M.

IPC: C08F110/06 ,  C08F4/651

CPC classification number: C08F4/52 ,  C08F110/06 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6545

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R 4 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which may be linked to form a saturated or unsaturated mono or polycycle and R 5 groups are selected from C 1 -C 15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si.

Abstract translation: 用于烯烃聚合的催化剂组分包含Mg，Ti和下式（I）的电子给体化合物：其中R 1至R 4基团等于或不同于 彼此之间为氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N和Si的杂原子，其可以是 连接形成饱和或不饱和的单环或多环并且R 5 5基团选自任选含有选择的杂原子的C 1 -C 15烃基 来自卤素，P，S，N和Si。

公开(公告)号：WO2012175425A1

公开(公告)日：2012-12-27

申请号：PCT/EP2012/061466

申请日：2012-06-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim, T. M.

Inventor： MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim, T. M.

IPC: C08F10/00 ,  C08F4/651

CPC classification number: C08F4/50 ,  C08F4/16 ,  C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12 ,  C08F4/6541

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R 1 to R 4 groups, equal to or different from each other, are hydrogen, C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and S i ,, R 6 group is selected from C 1 -C 15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R 5 is selected from phenyl groups mono or poly substituted with halogens, said groups R 1 -R 4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.

Abstract translation: 包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分，其中相同或不同的R 1至R 4基团为氢，任选地含有 选自卤素，P，S，N和Si，R 6基团的杂原子选自任选含有选自卤素，P，S，N和Si的杂原子的C 1 -C 15烃基，R 5选自苯基单或多 被卤素取代，所述基团R 1 -R 4也任选地连接形成饱和或不饱和的单或多环。

公开(公告)号：WO2012130614A1

公开(公告)日：2012-10-04

申请号：PCT/EP2012/054447

申请日：2012-03-14

Applicant: Basell Poliolefine Italia S.r.l. ,  LIGUORI, Dario ,  VITALE, Gianni ,  PATER, Joachim T. M. ,  MORINI, Giampiero ,  GUIDOTTI, Simona ,  DALL'OCCO, Tiziano

Inventor： LIGUORI, Dario ,  VITALE, Gianni ,  PATER, Joachim T. M. ,  MORINI, Giampiero ,  GUIDOTTI, Simona ,  DALL'OCCO, Tiziano

IPC: B01J31/02 ,  C08F4/00

CPC classification number: C08F4/76 ,  B01J31/0202 ,  B01J2531/22 ,  B01J2531/46 ,  C08F4/10 ,  C08F4/52 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/651 ,  C08F4/6555

Abstract: Catalyst components for the polymerization of olefins CH 2 =CHR wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, comprising Mg, Ti, CI and a diol or a derivative thereof.

Abstract translation: 用于烯烃CH 2 = CHR的聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包含Mg，Ti，Cl和二元醇或其衍生物。

公开(公告)号：WO2012052387A1

公开(公告)日：2012-04-26

申请号：PCT/EP2011/068080

申请日：2011-10-17

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MORINI, Giampiero ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M.

Inventor： MORINI, Giampiero ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/654 ,  C08F4/649

CPC classification number: C08F4/16 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6543 ,  C08F4/6494 ,  C08F4/651 ,  C08F2/14 ,  C08F2500/03 ,  C08F2500/12

Abstract: A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from diolesters of a specific formula (b) an alkylaluminum cocatalyst and (c) an ester of formula R'OOC-(CR" 2 ) m -COOR' in which m is an integer from 2 to 8, the R' groups, equal to or different from each other, are C1-C10 alkyl groups and the R" groups, independently, are hydrogen or C1 -C15 hydrocarbon groups.

Abstract translation: 一种催化剂体系，其包括通过使（a）含有Mg，Ti，卤素和至少一种选自特定式（b）的二极体的电子给体化合物的（a）固体催化剂组分与烷基铝助催化剂和（c）式 R'OOC-（CR“2）m-COOR'，其中m为2至8的整数，R'基彼此相同或不同，为C1-C10烷基，R”基团独立地为 是氢或C 1 -C 15烃基。

公开(公告)号：WO2012017040A1

公开(公告)日：2012-02-09

申请号：PCT/EP2011/063450

申请日：2011-08-04

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MORINI, Giampiero ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  Pater, Jochem, T., M.

Inventor： MORINI, Giampiero ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  Pater, Jochem, T., M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/646 ,  C08F4/654

CPC classification number: C08F4/6494 ,  C08F10/06 ,  C08F4/6465 ,  C08F4/651 ,  C08F4/6543

Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and at least two electron donor compounds, one of which (A) belonging to specific diolesters and the other electron donor compound (B) being selected from aromatic monoesters of the following formula (B) in which R groups equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups which can be also linked to form one or more cycles, m is an integer from 1 to 5 and R 5 is a C 1 -C 15 alkyl group, said electron donors A and B being in amounts such that the A/B molar ratio is lower than 20.

Abstract translation: 一种用于烯烃聚合的催化剂组分，包括Mg，Ti和至少两种电子给体化合物，其中一种（A）属于特定二极体，另一种电子给体化合物（B）选自下式的芳族单酯（B ）其中R基彼此相同或不同，选自可以连接形成一个或多个周期的C 1 -C 15烃基，m是1至5的整数，R 5是C 1 -C 15烷基 所述电子给体A和B的量使得A / B摩尔比低于20。

公开(公告)号：WO2011042269A1

公开(公告)日：2011-04-14

申请号：PCT/EP2010/062949

申请日：2010-09-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  GUIDOTTI, Simona ,  LIGUORI, Dario ,  MORINI, Giampiero ,  PATER, Joachim T.M.

Inventor： GUIDOTTI, Simona ,  LIGUORI, Dario ,  MORINI, Giampiero ,  PATER, Joachim T.M.

IPC: C08F10/06 ,  C08F4/02 ,  C08F4/651

CPC classification number: C08F110/06 ,  C08F10/06 ,  C08F4/022 ,  C08F4/651 ,  C08F4/6545

Abstract: Solid adducts comprising a MgCl 2 , ethanol and a compound (A), said compounds being present in molar ratios defined by the following formula MgCl 2 (EtOH) n (A) p in which n is from 0.1 to 6, p ranges from 0.001 to 0.5 and A is a compound selected from cyclic hydrocarbon structures which are substituted with at least two hydroxy groups.

Abstract translation: 包含MgCl 2，乙醇和化合物（A）的固体加合物，所述化合物以下列通式MgCl 2（EtOH）n（A）p定义的摩尔比存在，其中n为0.1至6，p为0.001至0.5 A是选自被至少两个羟基取代的环状烃结构的化合物。

公开(公告)号：WO2008019802A1

公开(公告)日：2008-02-21

申请号：PCT/EP2007/007089

申请日：2007-08-10

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  FUSHIMI, Masaki ,  SCHMITT, Maria ,  SCHNEIDER, Martin ,  MORINI, Giampiero

Inventor： FUSHIMI, Masaki ,  SCHMITT, Maria ,  SCHNEIDER, Martin ,  MORINI, Giampiero

IPC: C08F4/654 ,  C08F4/656 ,  C08F10/00

CPC classification number: C08F110/02 ,  C08F2410/01 ,  C08F10/00 ,  C08F4/6548 ,  C08F4/025 ,  C08F4/6565 ,  C08F2500/17 ,  C08F2500/18

Abstract: The instant invention relates to a process for preparing a catalyst component for the polymerization of olefins. Catalysts prepared with this catalyst component provide a high mileage for the production of polyolefin with a high bulk density of the polymer produced therewith. Particularly, catalysts prepared with this catalyst component are suitable for the improved economical production of polyolefin in gas phase processes.

Abstract translation: 本发明涉及制备用于烯烃聚合的催化剂组分的方法。 用该催化剂组分制备的催化剂为生产具有高密度聚合物的聚烯烃提供了高里程。 特别地，用该催化剂组分制备的催化剂适用于改进气相工艺中聚烯烃的经济生产。

公开(公告)号：WO2007147740A1

公开(公告)日：2007-12-27

申请号：PCT/EP2007/055618

申请日：2007-06-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  COLLINA, Gianni ,  DI DIEGO, Maria ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  VINCENZI, Paolo

Inventor： COLLINA, Gianni ,  DI DIEGO, Maria ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  VINCENZI, Paolo

IPC: B01J27/135 ,  B01J27/138 ,  C08F4/642 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F210/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and an electron donor is obtained by a batch process comprising: (A) A first step comprising reacting an adduct of formula MgCl 2 (ROH) n , where R is a C1-C10 alkyl group, and n is from 0.5 to 6, in a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature ranging from 0°C to 80°C and then removing the liquid medium; (B) A subsequent step comprising reacting the solid product obtained in (A) in a liquid medium comprising an electron donor ED selected from ethers, esters, ketones, silanes, amines, nitriles and amides, and a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C and then, after removing the liquid medium; (C) A subsequent step comprising reacting the solid product coming from (B) with a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C.

Abstract translation: 通过分批方法获得包含Mg，Ti，卤素和电子给体的烯烃聚合的催化剂组分，包括：（A）第一步，包括使式MgCl 2（ROH） 在含有至少Ti-Cl键的钛化合物的液体介质中，其中R为C1-C10烷基，n为0.5至6，其中R为0〜 至80℃，然后除去液体介质; （B）后续步骤，包括使（A）中获得的固体产物在包含选自醚，酯，酮，硅烷，胺，腈和酰胺的电子给体ED的液体介质中，和至少具有Ti -Cl键在高于80℃的温度下，然后除去液体介质; （C）随后的步骤包括使来自（B）的固体产物与包含在高于80℃的温度下具有至少Ti-Cl键的钛化合物的液体介质反应。

公开(公告)号：WO2006103171A1

公开(公告)日：2006-10-05

申请号：PCT/EP2006/060738

申请日：2006-03-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MORINI, Giampiero ,  CAMURATI, Isabella, Maria, Vittoria ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  VITALE, Gianni

Inventor： MORINI, Giampiero ,  CAMURATI, Isabella, Maria, Vittoria ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  VITALE, Gianni

IPC: C08F4/654 ,  C08F10/00 ,  B01J31/12 ,  B01J31/14 ,  B01J27/135 ,  B01J27/138 ,  C08F4/656

CPC classification number: C08F110/02 ,  C08F210/16 ,  C08F4/6565 ,  C08F4/6548 ,  C08F2500/12 ,  C08F210/08

Abstract: Catalyst components for the(co)polymerization of ethylene comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio in the range 0.1-1.5, a Mg/Ti molar ratio of less than 8, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight characterized by a specific SS-NMR pattern are particularly useful for preparing narrow MWD crystalline ethylene polymers.

Abstract translation: 含有Ti，Mg，卤素，ORI基团的乙烯（共）聚合的催化剂组分，其中RI是任选含有杂原子的C 1 -C 12烃基，ORI / Ti摩尔比在0.1-1.5范围内，Mg / Ti 摩尔比小于8，相对于所述固体催化剂组分的总重量，钛的量高于4重量％，其特征在于特定的SS-NMR图案，特别适用于制备窄MWD晶体乙烯聚合物。