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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    1.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2016184884A1

    公开(公告)日：2016-11-24

    申请号：PCT/EP2016/061078

    申请日：2016-05-18

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  KASHULIN, Igor ,  MORINI, Giampiero ,  NIFANT'EV, Ilya

    IPC: C08F4/651 ,  C08F10/00

    CPC classification number: C08F4/651 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15

    Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where independently, Z is a bridging group, the R 2 groups, equal to or different from each other, are hydrogen or a C 1 -C 20 hydrocarbon radicals, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10, R 1 and R 4 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O; and R 3 group, is hydrogen or R 4 groups. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.

    Abstract translation: 一种用于烯烃聚合的固体催化剂组分，其包含Mg，Ti和式（I）的电子给体，其中独立地Z为桥连基，R2基彼此相同或不同，为氢或C1- C20烃基，m是满足Z的化合价的数，n是1至10的整数，R 1和R 4选自C 1 -C 15烃基，任选地含有选自卤素，P，S，N， O; 和R 3基团，是氢或R 4基团。 基于固体催化剂组分的催化剂体系具有高活性和立体定向性。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    3.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2016156473A1

    公开(公告)日：2016-10-06

    申请号：PCT/EP2016/057031

    申请日：2016-03-31

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  KASHULIN, Igor ,  MORINI, Giampiero ,  NIFANT'EV, Ilya

    IPC: C08F110/06 ,  C08F4/651 ,  C08F4/654

    CPC classification number: C08F110/06 ,  C08F4/6455 ,  C08F4/6457 ,  C08F4/649 ,  C08F4/6495 ,  C08F4/6498 ,  C08F4/654 ,  C08F4/655 ,  C08F2410/01 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/651 ,  C08F4/6543 ,  C08F4/6465

    Abstract: Catalyst component for the polymerization of olefins comprising Mg. Ti and an electron donor belonging to mercaptoester derivatives of specific formula (I) in which Z is selected from C, Si, O, N, S or P with the proviso that the atoms O, S, P and N are not directly linked to either the carboxylic group or the sulphur atom of formula (I), the R 2 groups, equal to or different from each other, are hydrogen or a C 1 -C 20 hydrocarbon radicals, optionally containing a heteroatom selected from halogen, P, S, N,O and Si, which can be fused together to form one or more cycles, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10, X is O or S, Y is -OR 3 , -NR 4 R 5 ) or R 6 groups in which R 1 and R 3 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O, and Si, R 4 -R 5 groups, independently, are hydrogen or R 1 groups and R 6 groups have the same meaning as R 1 groups.

    Abstract translation: 包含Mg的烯烃聚合的催化剂组分。 Ti和属于特定式（I）的巯基酯衍生物的电子给体，其中Z选自C，Si，O，N，S或P，条件是原子O，S，P和N不直接连接到 式（I）的羧基或硫原子，相同或不同的R 2基团是氢或C 1 -C 20烃基，任选地含有选自卤素，P，S，N， O和Si，其可以融合在一起形成一个或多个循环，m是满足Z的化合价的数，n是1至10的整数，X是O或S，Y是-OR 3，-NR 4 R 5） 或R6基团，其中R 1和R 3选自C 1 -C 15烃基，任选地含有选自卤素，P，S，N，O和Si的杂原子，R 4 -R 5基团独立地为氢或R 1基团，R 6 组与R1组具有相同的含义。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    4.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2013182585A1

    公开(公告)日：2013-12-12

    申请号：PCT/EP2013/061546

    申请日：2013-06-05

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  GUIDOTTI, Simona ,  KASHULIN, Igor ,  MORINI, Giampiero ,  NIFANT'EV, Ilya ,  PATER, Joachim T. M.

    IPC: C08F4/651 ,  C08F110/06

    CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

    Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.

    Abstract translation: 包含Mg，Ti和其中R基彼此相同或不同的下式（I）的电子给体化合物的烯烃聚合催化剂组分是C 1 -C 15烃基，R 1 -R 2基， 相同或不同的是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N和Si的杂原子，其可以一起稠合形成一个或多个循环; n和m是0-3的整数，条件是它们中的至少一个不同于0，并且排除邻苯二乙酸二异丁酯。

    COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
    10.
    发明公开
    COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的组分和催化剂

    公开(公告)号：EP1730204A1

    公开(公告)日：2006-12-13

    申请号：EP05715867.7

    申请日：2005-03-08

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： GULEVICH, Yuri ,  BALBONTIN, Giulio ,  MORINI, Giampiero ,  NIFANT'EV, Ilya

    IPC: C08F10/00 ,  C08F4/651

    CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/651

    Abstract: The present invention relates to a solid catalyst component for the polymerization of olefins CH2=CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from ß-keto-ester derivatives of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

    Abstract translation: 本发明涉及用于烯烃CH 2 = CHR聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自β-酮酯的电子供体 特定配方的衍生物。 所述催化剂组分当用于烯烃聚合，特别是丙烯聚合时，能够以高收率得到聚合物并且具有以高二甲苯不溶性表示的高等规指数。

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