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公开(公告)号:ES2130320T3
公开(公告)日:1999-07-01
申请号:ES94113935
申请日:1994-09-06
Applicant: BASF AG
Inventor: GUENTHER ERHARD DR , REUTHER WOLFGANG , SCHERR GUNTER , DIMMLER MANFRED DR
IPC: B01J27/16 , B01J29/82 , C07B61/00 , C07D251/70 , C08K5/34
Abstract: Hydroxyoxaalkylmelamines of the formula I wherein R is a radical of the formula II H &lparstr& O-CHR'-CHR' &rparstr& n (II), in which the radicals R' can be identical or different and represent hydrogen or C1-C4-alkyl and n has the meanings 2 or 3 and the radicals R and R represent one of the radicals R or hydrogen, are prepared by reaction of melamine with a compound of the formula III H &lparstr& O-CHR'-CHR' &rparstr& n-NH2 (III), wherein R' and n have the meanings indicated above, at a temperature from 120 to 250 DEG C in the presence of an acidic catalyst, the acidic catalyst being employed in an amount from 0.01 to 0.15 mol, relative to 1 mol of melamine.
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公开(公告)号:DE19530178A1
公开(公告)日:1997-02-20
申请号:DE19530178
申请日:1995-08-17
Applicant: BASF AG
Inventor: GUENTHER ERHARD DR , REUTHER WOLFGANG DR
IPC: C07D251/18 , C08G14/09 , C08G14/10 , C08L61/14 , D01F6/76
Abstract: Condensation products obtainable by the condensation of a mixture containing as the essential components: (A) 90 to 99.9 mol% of a mixture substantially consisting of (a) 30 to 100 mol% melamine and (b) 0 to 70 mol% of a substituted melamine of general formula (I) in which X, X' and X'' are selected from the group consisting of -NH2, -NHR and -NRR', and X, X' and X'' are not -NH2- simultaneously, and R and R' are selected from the group consisting of hydroxy-C2-C10-alkyl, hydroxy-C2-C4-alkyl-(oxa-C2-C4-alkyl)n, where n = 1 to 5, and amino-C2-C12-alkyl, or mixtures of melamines of general formula (I), and (c) 1 to 70 mol%, related to (a)+(b), of a substituted triazine of general formula (II) in which R'' is methyl or phenyl and Z' and Z'' are selected from the group consisting of -NH2, -NHR and NR R , and R and R are selected from the group consisting of hydroxy-C2-C10-alkyl, hydroxy-C2-C4-alkyl-CH2CH2-S-CH2CH2OH and amino-C2-C12-alkyl, or mixtures of the triazines of general formula (II), and (B) 0.1 to 10 mol%, related to (A) (a), (A) (b) and (B), of unsubstituted phenols or phenols substituted by radicals selected from the group C1-C9-alkyl and hydroxy, C1-C4-alkanes substituted with two or three phenol groups, di(hydroxy phenyl)sulphones or mixtures of these phenols, with formaldehyde or formaldehyde-yielding compounds, in which the molar ratio of melamine, substituted melamine of general formula (I) and triazine of general formula (II) to formaldehyde is in the range from 1:1.15 to 1:4.5, and a process for their production, their use in the manufacture of mouldings and such mouldings.
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公开(公告)号:AT141356T
公开(公告)日:1996-08-15
申请号:AT93118978
申请日:1993-11-25
Applicant: BASF AG
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公开(公告)号:DE4444713A1
公开(公告)日:1996-06-20
申请号:DE4444713
申请日:1994-12-15
Applicant: BASF AG
Inventor: MARCZINKE BERND LOTHAR DR , MUELLER PATRIK DR , KOESSLER LUDWIG , SCHERR GUENTER DR , BROSIUS SIBYLLE DR , GUENTHER ERHARD DR , HOFMANN JUERGEN
IPC: C08K5/3492 , C08L23/10 , C08L23/14 , C08L51/06 , D01F6/46
Abstract: Plastic materials with a melt flow index 230/2.16 of 0.1-100 g/10 minutes contain: (a1) propylene homopolymer with a melt flow index 230/2.16 of 0.1-100 g/10 minutes, or(a2) statistical copolymer of propylene and 2-10C alkene-1 with a comonomer content of less than 15 wt.%, or (a3) a mixt. of 25-97 wt.% of a copolymer of propylene and 0.1-15 wt.% 2-10C alkene-1 and 3-75 wt.% of another propylene copolymer contg. 15-80 wt.% 2-10C alkene-1 units, or(a4) a mixt. of 25-97 wt.% propylene homopolymer and 3-75 wt.% propylene/2-10C alkene-1 copolymer, with a comonomer content of 15-80 wt.% w.r.t. the second polymer, (b) a propylene or ethylene polymer grafted with 0.1-5 wt.% alpha , beta -unsatd. carboxylic acid or acid deriv., with a melt flow index 230/2.16 of 0.01-400 g/10 minutes, and (c) a nitrogen cpd. of formula (I): R =H, 1-30C alkyl, 2-30C alkyl or alk-1-enyl substd. with O atom(s) and/or amino gps., or a gp. of formula (II):HO-(CHR -CHR )m- (II)R =H, 1-4C alkyl or amino; andm=1-100. Also claimed are: (i) a process for the prodn. of the materials, by reacting components (a)-(c) together at 180-280 deg C and 1-100 bar for a mean residence time of 0.2-10 minutes; and(ii) film, fibres and mouldings made from the materials.
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公开(公告)号:DE4408688A1
公开(公告)日:1995-09-21
申请号:DE4408688
申请日:1994-03-15
Applicant: BASF AG
Inventor: SEYFFER HERMANN DR , RUPANER ROBERT DR , GUENTHER ERHARD DR , HUMMERICH RAINER DR
IPC: C08L33/00 , C08G65/333 , C08J3/24 , C08K5/04 , C08L33/02 , C08L35/00 , C08L57/04 , C08L71/02 , D04H1/4209 , D04H1/4218 , D04H1/435 , D04H1/587 , D04H1/64 , D04H1/645 , D06M13/148 , D06M13/152 , D06M13/358 , D06M15/263 , D06N3/04 , D06N5/00 , H01M2/16 , D04H1/48 , H01M2/14
Abstract: HCHO-free binders, impregnants or coating materials comprise (A) a polymer contg. 2-100 wt.% of an ethylenically-unsatd. acid or anhydride as a constituent monomer; and (B) a polyol which is a triazine of formula (I), a triazine-trione of formula (II), a benzene deriv. of formula (III) and/or a cyclohexyl deriv. of formula (IV). R -R = X((CmH2mO)nH) or N((CmH2mO)nH)2; R -R = ((CmH2mO)nH); R -R = (X(CmH2mO)nH; N((CmH2mO)nH)2; (Y(CmH2mO)nH); or ((CmH2mO)nH); X = NH, O or S; Y = divalent 1-6C alkyl or acyl gp.; m = 2-5; and n = 1-10.
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