公开(公告)号：JPH1060040A

公开(公告)日：1998-03-03

申请号：JP14884897

申请日：1997-06-06

Applicant: BASF AG

Inventor： HUEFFER STEPHAN DR ,  BIDELL WOLFGANG DR ,  MUELLER PATRIK DR ,  MOLL ULRICH DR ,  HINGMANN ROLAND DR ,  SCHWEIER GUENTHER DR

IPC: C08F4/654 ,  C08F4/02 ,  C08F4/646 ,  C08F4/658 ,  C08F10/00 ,  C08F110/06

Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition comprising a specific titanium- containing solid component, a cocatalyst and an electron-donating compound and enabling the production of a polymer having a high bulk density and reduced in xylene and heptane-soluble contents. SOLUTION: This Ziegler/Natta type catalyst composition comprises (A) a Ti-containing solid component comprising a Ti compound, a Mg compound, a halogen, an inorganic oxide and a carboxylate ester as an electron-donating compound, (B) an aluminum compound as a cocatalyst, and selectively (C) one or more other electron-donating compounds. The inorganic oxide in the component A has a pH of 1-6, an average particle diameter of 5-200μm, an average primary particle diameter of 1-20μm, pore spaces and grooves of 0.1-20μm and the whole particle volume marcroshare of 5-30%. The catalyst can give polymers good in mechanical characteristics, and the polymers are suitable for producing shaped products such as films and fibers.

公开(公告)号：ES2098639T3

公开(公告)日：1997-05-01

申请号：ES93119725

申请日：1993-12-08

Applicant: BASF AG

Inventor： MUELLER PATRIK DR ,  SCHWAGER HARALD DR ,  HUNGENBERG KLAUS-DIETER DR ,  OVERTHUN KLAUS

IPC: C08F2/00 ,  C08F2/34 ,  C08F2/38 ,  C08F4/60 ,  C08F4/642 ,  C08F4/645 ,  C08F4/646 ,  C08F10/00 ,  C08F210/04 ,  C08F210/06 ,  C08F210/16 ,  C08F297/08 ,  C08L23/10 ,  C08L23/14

公开(公告)号：DE59305753D1

公开(公告)日：1997-04-17

申请号：DE59305753

申请日：1993-12-08

Applicant: BASF AG

Inventor： MUELLER PATRIK DR ,  SCHWAGER HARALD DR ,  HUNGENBERG KLAUS-DIETER DR ,  OVERTHUN KLAUS

IPC: C08F2/00 ,  C08F2/34 ,  C08F2/38 ,  C08F4/60 ,  C08F4/642 ,  C08F4/645 ,  C08F4/646 ,  C08F10/00 ,  C08F210/04 ,  C08F210/06 ,  C08F210/16 ,  C08F297/08 ,  C08L23/10 ,  C08L23/14

公开(公告)号：DE59304971D1

公开(公告)日：1997-02-13

申请号：DE59304971

申请日：1993-10-27

Applicant: BASF AG

Inventor： MUELLER PATRIK DR ,  SCHWAGER HARALD DR

IPC: B29C41/00 ,  B29C41/04 ,  C08L23/10 ,  C09D123/14

公开(公告)号：DE59205285D1

公开(公告)日：1996-03-21

申请号：DE59205285

申请日：1992-08-08

Applicant: BASF AG

Inventor： KERSTING MEINOLF DR ,  MUELLER PATRIK DR ,  SCHWAGER HARALD DR ,  KOELLE PETER DR ,  WEBER SIEGFRIED DR ,  MUELLER HANS-JOACHIM DR

IPC: C08F4/02 ,  C08F4/647 ,  C08F10/00

公开(公告)号：DE4316049A1

公开(公告)日：1993-12-09

申请号：DE4316049

申请日：1993-05-13

Applicant: BASF AG

Inventor： KERSTING MEINOLF DR ,  HUNGENBERG KLAUS-DIETER DR ,  MUELLER PATRIK DR ,  KOELLE PETER DR

IPC: C08F2/34 ,  C08F4/642 ,  C08F4/649 ,  C08F210/06 ,  C08L23/14

Abstract: Copolymers of propylene (prop) and hex-1-ene (hex) are claimed (I). (I) are obtd. by copolymerisation at 10-50 br and 50-100 deg. C for 1-5 hrs. (mean residence time) in the presence of a Ziegler-Natta catalyst system comprising a solid, Ti-contg. component (A), an Al component (B) and an electron donor (C). The temp. at the given pressure is high enough to prevent condensn. of the monomer mixt. in the gas space and the ratio of partial pressures (prop):(hex) = (1:1)-(120:1). USE/ADVANTAGE - Enables the prodn. of propylene/hex-1-ene copolymers (I), which are useful for the mfr. of film (e.g, for use in the food industry), tubes, coatings, fibres hollow mouldings, injection moulded prods. and moulded prods. for use in cars. (I) are statistical copolymers with mol. wt of 10,000-500,000 and MFI 0.1-100 (pref. 0.2-50) g/10 mins., esp. contg. 0.1-10 wt. % hexene and with a low heptane-solubles content. The claims also include films and moulded prods. made from (I).

公开(公告)号：DE4216548A1

公开(公告)日：1993-11-25

申请号：DE4216548

申请日：1992-05-19

Applicant: BASF AG

Inventor： MUELLER PATRIK DR ,  HUNGENBERG KLAUS-DIETER DR ,  KERTH JUERGEN DR ,  ZOLK RALF DR

IPC: C08F4/654 ,  C08F4/642 ,  C08F4/646 ,  C08F10/00 ,  C08L23/02

Abstract: Catalyst systems of the Ziegler-Natta type containing as active components: a) a titanium-containing solid component in the production of which a titanium compound, a compound of magnesium, a halogenating agent and an electron donor component are used, b) an aluminium compound and c) as a further electron donor component, a silicon-organic compound of general formula (I): R R Si(OR )2 in which R is a C1-C10 alkyl radical or a C3-C18 cycloalkyl radical, R is a secondary butyl radical and R is a C1-C8 alkyl radical. The catalyst systems of the invention are particularly suitable for the production of C2-C10-alkyl-1-enes.

公开(公告)号：DE4117144A1

公开(公告)日：1992-11-26

申请号：DE4117144

申请日：1991-05-25

Applicant: BASF AG

Inventor： HUNGENBERG KLAUS-DIETER DR ,  SCHWAGER HARALD DR ,  RUEMPLER KLAUS-DIETER DR ,  MUELLER PATRIK DR

IPC: C08F2/34 ,  C08F2/38 ,  C08F4/642 ,  C08F4/646 ,  C08F210/06 ,  C08F255/02 ,  C08F297/08

Abstract: Propylene-ethylene copolymers having a melt flow index of from 2 to 200 g/min, at 230 DEG C and under a weight of 2.16 kg, are obtainable by two-step polymerisation from the gas phase in an agitated fixed bed in the presence of hydrogen as molecular weight regulator by means of a Ziegler-Natta catalyst system comprising a titanium-containing solids component which contains a magnesium compound on finely divided silica or alumina or an aluminosilicate of the empirical formula SiO2.aAl2O3, where a is a value of from 0.001 to 2, and an aluminium component, in which a) in a first polymerisation step, propylene is polymerised at a pressure of from 20 to 40 bar and a temperature of from 60 to 90 DEG C, the ratio between the partial pressures of hydrogen and propylene being set to from 1:100 to 10:100, and subsequently b) in a second polymerisation step, a mixture of propylene and ethylene is polymerised onto the propylene product from the first polymerisation step, at a pressure of from 10 to 30 bar, this pressure being at least 7 bar below the pressure in the first polymerisation step, at a temperature of from 40 to 100 DEG C, and the weight ratio between the monomers reacted in the first polymerisation step and those reacted in the second polymerisation step being set in the range from 1:1 to 20:1. t

公开(公告)号：ES2137275T3

公开(公告)日：1999-12-16

申请号：ES94103544

申请日：1994-03-09

Applicant: BASF AG

Inventor： MARCZINKE BERND LOTHAR DR ,  MUELLER PATRIK DR ,  KERTH JUERGEN DR

IPC: C08F8/00 ,  C08F8/46 ,  C08F255/02 ,  C08J5/18 ,  C09J151/06 ,  D01F6/30

公开(公告)号：DE19529240A1

公开(公告)日：1997-02-13

申请号：DE19529240

申请日：1995-08-09

Applicant: BASF AG

Inventor： HUEFFER STEFAN DR ,  KERTH JUERGEN DR ,  KOELLE PETER DR ,  MUELLER PATRIK DR ,  HEMMERICH RAINER DR

IPC: C08F4/02 ,  C08F4/58 ,  C08F4/642 ,  C08F10/00 ,  C08F10/06

Abstract: Ziegler/Natta-type catalyst systems (A), comprising: (a) a solid component contg. a Ti cpd., a Mg cpd., a halogen, a silica gel support (B) and a carboxylate ester as electron donor; (b) an Al cpd. as cocatalyst; and opt. (c) another electron donor. The silica (B) has an average particle dia. of 5-200 mu m and an average prim. particle dia. of 1-10 mu m, and contains cavities or channels with an average dia. of 1-10 mu m and a macroscopic vol. content of 5-20% based on the whole particle. Also claimed are: (i) a process for the prodn. of (A) by reacting (a), (b) and opt. (c) together at 0-150[deg]C and 1-100 bar; (ii) a process for the prodn. of polymers by polymerisation of propylene and opt. comonomers at 20-150[deg]C and 1-100 bar in presence of (A); (iii) polymers of propylene obtd. by this process; and (iv) film, fibres and mouldings made from these polymers.