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公开(公告)号:DE3900713A1
公开(公告)日:1990-07-19
申请号:DE3900713
申请日:1989-01-12
Applicant: BASF AG
Inventor: HISGEN BERND DR , POHLEMANN HEINZ DR , HEINZ GERHARD DR , ROSENAU BERNHARD DR , ZEINER HARTMUT DR , SCHLEMMER LOTHAR , MERTES JUERGEN DR
Abstract: Polymer compositions comprising A) thermotropic-mesomorphic polycondensates (5-99.9% by weight), B) apatite (0.1-70% by weight) and optionally C) fillers other than B) and D) non-thermotropic-mesomorphic polymers other than A), have an interesting property profile.
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公开(公告)号:DE3900708A1
公开(公告)日:1990-07-19
申请号:DE3900708
申请日:1989-01-12
Applicant: BASF AG
Inventor: POHLEMANN HEINZ DR , HISGEN BERND DR
Abstract: An implant material for replacing hard tissue containing as essential components A) 30 to 95% by weight of a thermotropically mesomorphic polymer, B) 5 to 70% by weight of an apatite and C) 0 to 60% by weight of a fibrous or particulate filler which differs from B).
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公开(公告)号:AT46710T
公开(公告)日:1989-10-15
申请号:AT86116324
申请日:1986-11-25
Applicant: BASF AG
Inventor: HISGEN BERND DR , PORTUGALL MICHAEL DR , BLINNE GERD DR
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公开(公告)号:DE3704146A1
公开(公告)日:1988-09-29
申请号:DE3704146
申请日:1987-02-11
Applicant: BASF AG
Inventor: WAGENBLAST GERHARD DR , ETZBACH KARL-HEINZ DR , HISGEN BERND DR
Abstract: Optical laser writing and reading method, in which the thermally variable recording layer, containing liquid-crystal bonds oriented in a homogeneously planar manner, of a multilayer sheet-like recording material is inscribed by means of a writing laser beam with analog or digital data in the form of thermally varied regions, after which the written data are read by means of a reading laser beam. In this method - the light transmitted or reflected by the recording material is analysed, - the data is read out by determining the optical polarisation contrast between the thermally varied and the non-varied regions and/or use is made for this of the interference of light waves which form from the laser light waves with Gaussian intensity distribution as a result of the different phase velocity of the light in the centre of thermally varied regions on the one hand and of their thermally non-varied environment on the other hand, - use is made of a recording layer which constitutes an optically uniaxial medium, to the refractive indices n1 (perpendicular to the plane of the recording layer), n2 (in the plane of the recording layer and perpendicular to the major optical axis), n3 (in the plane of the recording layer and parallel to the major optical axis) and niso (refractive index of the thermally varied regions), with niso = 1/3(n1 + n2 + n3), of light of the wavelength lambda = 780 nm, of which apply the relations n1 = n2 n3 and | DELTA n| = |n3-n2| > 0.05 or | DELTA n| = |niso-n2| > 0.05 or alternatively | DELTA n| = |niso-n3| > 0.05, and which has a thickness d of 0.05 lambda '/| DELTA n| to 0.6 lambda '/| DELTA n|, lambda ' = wavelength of the reading laser light, - the reading laser beam is guided over the recording material in a relative movement in the direction of the major optical axis of the recording layer or perpendicularly to this and the reading laser beam is at the same time so radiated that, when it strikes the recording layer, the plane of its polarisation @ forms with its major optical axis an angle of 0 DEG +/- 10 DEG , 45 DEG +/- 10 DEG or 90 DEG +/- 10 DEG , and - in the event that the transmitted light is analysed, a laser beam of light of the wavelength lambda ' of 1.66 d | DELTA n| to 5 d | DELTA n| is used and, in the event that the reflected light is analysed, a laser beam of light of the wavelength lambda ' of 3.33 d | DELTA n| to 20 d | DELTA n| is used. The invention also relates to new optical laser writing and reading devices for carrying out this method and new multilayer optical laser data plates, the thermally variable recording layer of which contains liquid-crystal bonds in a homogeneously planar and radial or homogeneously planar and tangential orientation.
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公开(公告)号:DE3700821A1
公开(公告)日:1988-07-28
申请号:DE3700821
申请日:1987-01-14
Applicant: BASF AG
Inventor: KOCK HANS-JAKOB DR , HISGEN BERND DR , PORTUGALL MIACHAL DR , SEILER ERHARD DR , BLINNE GERD DR
Abstract: Wholly aromatic thermotropic polyesters are based on (A) 30 to 60 mol % of 4-hydroxybenzoic acid, (B) 20 to 35 mol % of terephthalic acid and (C) 20 to 35 mol % of a mixture of (C1) trimethylhydroquinone and (C2) resorcinol the molar ratio of C1:C2 being within the range from 0.4:1 to 0.7:1 and the molar ratio of B:C within the range from 0.9:1 to 1.1:1.
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公开(公告)号:DE3622137A1
公开(公告)日:1988-01-07
申请号:DE3622137
申请日:1986-07-02
Applicant: BASF AG
Inventor: KOCK HANS-JAKOB DR , PORTUGALL MICHAEL DR , HISGEN BERND DR , MERTES JUERGEN DR
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公开(公告)号:DE3542796A1
公开(公告)日:1987-06-11
申请号:DE3542796
申请日:1985-12-04
Applicant: BASF AG
Inventor: HISGEN BERND DR , PORTUGALL MICHAEL DR , STEINBERGER ROLF DR
IPC: C08G63/68 , C08G63/685 , C08G73/14 , C08G73/16 , C09K19/38 , C08G73/12 , C08L79/08 , C08J5/18 , D01F6/78 , D01F6/74
Abstract: Wholly aromatic mesomorphic polyester amide imides which form a liquid-crystalline fiber-forming melt below 320 DEG C. and are composed of (a) from 5 to 35 mole % of repeat units of the formula I and/or II I II where the Xs in the formulae I and II can be identical or different and each is -O-, -S-, -SO2-, -CO-, -CH2-or =C(CH3)2 and n is 0 or 1, (b) from 0 to 30 mole % of repeat units of the formulae III and/or IV III IV (c) a molar amount corresponding to the total amount of components a and b of one or more of the repeat units of the formulae V, VI, VII, VIII and IX V VI VII VIII IX (d) if desired from 5 to 25 mole % of one or more of the repeat units of the formulae X, XI and XII X XI XII (e) repeat units of the formula XIII XIII the mole percentages of components (a), (b), (c), (d) and (e) adding up to 100 mole % in each case, the preparation thereof and fibers, films and moldings prepared therefrom.
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公开(公告)号:AT101862T
公开(公告)日:1994-03-15
申请号:AT86116272
申请日:1986-11-24
Applicant: BASF AG
Inventor: HISGEN BERND DR , PORTUGALL MICHAEL , STERZEL HANS-JOSEF DR
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公开(公告)号:DE3782583D1
公开(公告)日:1992-12-17
申请号:DE3782583
申请日:1987-08-22
Applicant: BASF AG
Inventor: HISGEN BERND DR , KOCK HANS-JAKOB DR , PORTUGALL MICHAEL DR , SEILER ERHARD DR , BLINNE GERD DR
IPC: C08G63/60 , C08G63/68 , C08G63/682 , C08G63/685 , C08G69/44 , C08J5/18 , C09K19/38 , D01F6/84
Abstract: Fully aromatic thermotropic polyesters consist, by mol., of: (A) 25-60% mixt. of (A1) 4-hydroxybenzoic acid and (A2) 3-hydroxybenzoic acid, 4-aminobenzoic acid and/or 3-aminobenzoic acid or their ring-substd. Cl-, Br-, 1-18C alkyl- or 1-8C alkoxy derivs., in molar ratio (A1) : (A2) 5:1 to 41:1 (6:1 to 20:1), (B) 20-37.5% mixt. of (B1) terephthalic acid and (B2) isophthalic acid, in molar ratio (B1) : (B2) 1.04:1 to 19:1 (1.5:1 to 10:1), and (C) 20-37.5% mixt. of (C1) hydroquinone, (C2) 4,4'-dihydroxydiphenyl, in molar ratio (C1) : (C2) 0.1:1 to 2.67:1 (0.5:1 to 2.33:1). The molar ratio of (B) : (C) is 0.9:1 to 1.1:1.
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公开(公告)号:DE4103403A1
公开(公告)日:1992-08-06
申请号:DE4103403
申请日:1991-02-05
Applicant: BASF AG
Inventor: ROSENAU BERNHARD DR , VOGEL WILFRIED DR , HEINZ GERHARD DR , HISGEN BERND DR , HEDTMANN-REIN CAROLA DR , MUEHLBACH KLAUS DR
Abstract: Prodn. comprises conversion of liq. crystal forming monomers in presence of resin and aromatic hydrocarbon during the conversion. Aromatic hydrocarbon is pref. (i) a 7-12C alkylbenzene; (ii) a 1-3 halogen-substd. benzene; or (iii) a partially or wholly- hydrogenated naphthalene-, biphenyl- or terphenyl-deriv.. The use of mesitylene and of p-xylene is exemplified. ADVANTAGE - Improved c.f. prior-art processes (e.g. DE3505142) where relatively large amts. of solvents were used with consequent low space-time yields and difficulties in prod. isolation
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