公开(公告)号：MD332C2

公开(公告)日：1996-03-31

申请号：MD950016

申请日：1994-12-13

Applicant: BASF AG

Inventor： ECKHARD HICKMANN ,  SEELE RAINER ,  REINER KOBER ,  ISAK HEINZ

IPC: C07D301/18 ,  C07D405/06 ,  C07D521/00

Abstract: Invenţia se referă la procedeul de obţinere a cis-2-(1H-1,2,4-triazol-1-il-metil)-2-(halogenfenil)-3-(halogenfenil)-oxiranei cu formula I:Scopul invenţiei îl reprezintă sporirea randamentului produsului cu destinaţie specialăşi minimizarea consumului pentru purificare.Procedeul se efectuează pe calea epoxidării Z-3-(1H-1,2,4-triazol-1-il)-2-(halogenfenil)-1-(halogenfenil)-propenei cu acid permaleinic, reducând-o ulterior. În calitate de reducător este folosit hidrosulfitul de sodiu, ditionitul de sodiu sau tiosulfatul de sodiu sau hidrogenul în prezenţa nichelului Renei. Reducătorul se adaugă la amestecul reactant într-o cantitate excedentă faţă de cantitatea necesară pentru descompunerea acidului permaleinic, posibil prezent.

公开(公告)号：CA2192594A1

公开(公告)日：1995-12-21

申请号：CA2192594

申请日：1995-05-26

Applicant: BASF AG

Inventor： BAYER HERBERT ,  ISAK HEINZ ,  WINGERT HORST ,  SAUTER HUBERT ,  KEIL MICHAEL ,  NETT MARKUS ,  BENOIT REMY ,  MUELLER RUTH

IPC: C07C67/22 ,  C07C69/716 ,  C07C69/738 ,  C07C235/78 ,  C07C249/08 ,  C07C249/12 ,  C07C251/48 ,  C07C251/60 ,  C07C255/41 ,  C07C255/62 ,  C07D249/12 ,  C07D521/00 ,  C07C315/04 ,  C07C319/20 ,  C07D231/22 ,  C07C317/28 ,  C07C253/30 ,  C07D277/34 ,  C07D209/48 ,  C07C251/58 ,  C07C255/64

Abstract: The invention concerns a method of preparing .alpha.-methoxyiminocarboxylic acid methylamides of formula (I)(X = nitro, trifluoromethyl, halogen, alkyl or alkoxy; n = 0, 1, 2, 3 or 4; Y = an organic carbon group) by the Pinner reaction of cyanoketone of formula (II) with an alcohol, followed by reaction of the ester of formula (IV) formed in the Pinner reaction with hydroxylamine to give an oxime of formula (V), methylation of (V) to give an oxime ether of formula (VI) and subsequent reaction of (VI) with methylamine. The invention also concerns the intermediates used in the method.

公开(公告)号：HUT66608A

公开(公告)日：1994-12-28

申请号：HU9400996

申请日：1994-04-07

Applicant: BASF AG

Inventor： WETTLING THOMAS ,  WOLF BERND ,  KEIL MICHAEL ,  ISAK HEINZ ,  DOETZER REINHARD

IPC: C07C253/14 ,  C07C255/32 ,  C07C255/40

Abstract: A process for preparing halomethylbenzoyl cyanides I Ph-CO-CNI (Ph=phenyl radical substituted by chloromethyl or bromomethyl which, if desired, can additionally carry 1-4 further radicals) by reacting halomethylbenzoyl chlorides II Ph-CO-ClII with an alkali metal cyanide or transition metal cyanide, if appropriate in an organic diluent, and novel halomethylbenzoyl cyanides I' I' (X=halogen, C1-C4-alkyl, C1-C4-alkoxy, CF3, C1-C5-alkyl-(C1-C5-alkyl)hydroxyimino or C1-C5-alkyl-(C2-C5-alkenyl)hydroxyimino; m=0 to 4 and Y=chloromethyl or bromomethyl) are described. The halomethylbenzoyl cyanides I are important intermediates for the synthesis of plant protection agents.

公开(公告)号：HU905712D0

公开(公告)日：1991-03-28

申请号：HU571290

申请日：1990-08-30

Applicant: BASF AG

Inventor： KOBER REINER ,  SEELE RAINER ,  ZIERKE THOMAS ,  ISAK HEINZ ,  KARBACH STEFAN ,  WEGNER GUENTER

IPC: C07B49/00 ,  C07F3/02 ,  C07F7/08

Abstract: Preparation of ether solutions of arylmethylmagnesium halides… Ar-CH2-Mg-Hal I… (Aryl = unsubstituted or substituted aryl; Hal = Cl, Br) by the Grignard process from arylmethyl halides II… Ar-CH2-Hal II… with magnesium in an ether as a solvent, by using III… tert-butyl-O-R III… (R = C1-C3-alkyl) for this purpose.

公开(公告)号：HU228793B1

公开(公告)日：2013-05-28

申请号：HU0300766

申请日：2001-08-16

Applicant: BASF AG

Inventor： ISAK HEINZ ,  SENDHOFF NORBERT ,  SCHUETZ FRANZ ,  THERRE JOERG ,  DROEGEMUELLER MICHAEL ,  FRANKE DIRK ,  MUNZINGER MANFRED ,  WECK ALEXANDER ,  BURKART KIRSTEN

IPC: C07D285/34 ,  A01N25/12 ,  A01N43/88

Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction.

公开(公告)号：EA007106B1

公开(公告)日：2006-06-30

申请号：EA200400593

申请日：2002-10-31

Applicant: BASF AG

Inventor： MAYER HORST ,  GOLSCH DIETER ,  ISAK HEINZ ,  SCHRODER JOCHEN

IPC: C07D213/81 ,  C07D213/82

Abstract: Изобретениекасаетсяспособаполученияамидов 2-галогенпиридинкарбоновыхкислотпервичныхароматическихмоноаминов I, которыев орто-положениипоотношениюк аминогруппеимеютзаместители, отличающиесяотводорода, путемвзаимодействияхлорида 2-галогенпиридинкарбоновойкислоты II сароматическиммоноамином I. Способсогласноизобретениюотличаетсятем, чтореакциюпроводятв смесирастворителей, состоящейизводыи минимумодногоорганическогорастворителя, несмешивающегосяс водой, гдесмесьнесодержитилисодержитменьшечем 10 мол.% поотношениюк хлориду 2-галогенпиридинкарбоновойкислоты II основания, отличающегосяот I и II.

公开(公告)号：DE50205766D1

公开(公告)日：2006-04-13

申请号：DE50205766

申请日：2002-10-31

Applicant: BASF AG

Inventor： MAYER HORST ,  GOLSCH DIETER ,  ISAK HEINZ ,  SCHROEDER JOCHEN

IPC: C07D213/81 ,  C07D213/82

Abstract: The invention relates to a process for preparing 2-halopyridinecarboxamides of primary aromatic monoamines I which have a substituent other than hydrogen in the ortho-position to the amino group by reaction of 2-halopyridinecarbonyl chloride II with the aromatic monoamine I, which comprises carrying out the reaction in a solvent mixture comprising water and at least one water-immiscible organic solvent in the presence of none or less than 10 mol %, based on the 2-halopyridinecarbonyl chloride II, of a base other than I or II.

公开(公告)号：HU0401595A2

公开(公告)日：2004-11-29

申请号：HU0401595

申请日：2002-10-31

Applicant: BASF AG

Inventor： MAYER HORST ,  GOLSCH DIETER ,  ISAK HEINZ ,  SCHROEDER JOCHEN

IPC: C07D213/81 ,  C07D213/82

Abstract: The invention relates to a process for preparing 2-halopyridinecarboxamides of primary aromatic monoamines I which have a substituent other than hydrogen in the ortho-position to the amino group by reaction of 2-halopyridinecarbonyl chloride II with the aromatic monoamine I, which comprises carrying out the reaction in a solvent mixture comprising water and at least one water-immiscible organic solvent in the presence of none or less than 10 mol %, based on the 2-halopyridinecarbonyl chloride II, of a base other than I or II.

公开(公告)号：PT793642E

公开(公告)日：2000-06-30

申请号：PT95939274

申请日：1995-11-14

Applicant: BASF AG

Inventor： KEIL MICHAEL ,  HORST WINGER DR ,  BERND WOLF DR ,  WETTLING THOMAS ,  ISAK HEINZ

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.

公开(公告)号：GR3032559T3

公开(公告)日：2000-05-31

申请号：GR20000400256

申请日：2000-02-02

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST ,  WETTLING THOMAS

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.