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公开(公告)号:DE50205026D1
公开(公告)日:2005-12-29
申请号:DE50205026
申请日:2002-03-15
Applicant: BASF AG
Inventor: HENNINGSEN MICHAEL , KUSCHE ANDREAS , HUELLMANN MICHAEL , RUEB LOTHAR , KAESHAMMER STEFAN , GERLACH TILL
IPC: C07D265/30 , C07B61/00 , C07D295/02 , C07D295/023 , C07D295/03 , C07D295/033 , A01N43/84
Abstract: The present invention relates to a process for the preparation of N-substituted 2,6-dialkylmorpholines of the formula I in which R 1 and R 2 , independently of one another, are hydrogen, alkyl or cycloalkyl, or R 1 and R 2 together with the carbon atom to which they are bonded are a 5- to 14-membered carbocycle, and R 3 and R 4 , independently of one another, are alkyl or cycloalkyl, by reacting at least one carbonyl compound of the formula II in which R 1 and R 2 have the meanings given above, with at least one morpholine of the formula III in which R 3 and R 4 have the meanings given above, in the presence of hydrogen and at least one metal-containing catalyst, wherein the active component of the catalyst consists essentially of platinum group metals.
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公开(公告)号:PL366457A1
公开(公告)日:2005-02-07
申请号:PL36645702
申请日:2002-03-15
Applicant: BASF AG
Inventor: HENNINGSEN MICHAEL , KUSCHE ANDREAS , HUELLMANN MICHAEL , RUEB LOTHAR , KAESHAMMER STEFAN , GERLACH TILL
IPC: C07D265/30 , C07B61/00 , C07D295/02 , C07D295/023 , C07D295/03 , C07D295/033
Abstract: The present invention relates to a process for the preparation of N-substituted 2,6-dialkylmorpholines of the formula I in which R 1 and R 2 , independently of one another, are hydrogen, alkyl or cycloalkyl, or R 1 and R 2 together with the carbon atom to which they are bonded are a 5- to 14-membered carbocycle, and R 3 and R 4 , independently of one another, are alkyl or cycloalkyl, by reacting at least one carbonyl compound of the formula II in which R 1 and R 2 have the meanings given above, with at least one morpholine of the formula III in which R 3 and R 4 have the meanings given above, in the presence of hydrogen and at least one metal-containing catalyst, wherein the active component of the catalyst consists essentially of platinum group metals.
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公开(公告)号:HU0303478A2
公开(公告)日:2004-03-01
申请号:HU0303478
申请日:2002-03-15
Applicant: BASF AG
Inventor: GERLACH TILL DR , HENNINGSEN MICHAEL , HUELLMANN MICHAEL , KUSCHE ANDREAS , KAESHAMMER STEFAN , RUEB LOTHAR
IPC: C07D265/30 , C07B61/00 , C07D295/02 , C07D295/023 , C07D295/03 , C07D295/033
Abstract: The present invention relates to a process for the preparation of N-substituted 2,6-dialkylmorpholines of the formula I in which R 1 and R 2 , independently of one another, are hydrogen, alkyl or cycloalkyl, or R 1 and R 2 together with the carbon atom to which they are bonded are a 5- to 14-membered carbocycle, and R 3 and R 4 , independently of one another, are alkyl or cycloalkyl, by reacting at least one carbonyl compound of the formula II in which R 1 and R 2 have the meanings given above, with at least one morpholine of the formula III in which R 3 and R 4 have the meanings given above, in the presence of hydrogen and at least one metal-containing catalyst, wherein the active component of the catalyst consists essentially of platinum group metals.
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公开(公告)号:DE10139293A1
公开(公告)日:2003-02-27
申请号:DE10139293
申请日:2001-08-09
Applicant: BASF AG
Inventor: STEINBRENNER ULRICH , HAUBNER MARTIN , GERSTLAUER ACHIM , DOMSCHKE THOMAS , SIGWART CHRISTOPH , KAESHAMMER STEFAN
Abstract: In a process for the single-stage preparation of polytetrahydrofuran and/or tetrahydrofuran copolymers having a mean molecular weight of from 650 to 5000 dalton by polymerization of tetrahydrofuran over an acid catalyst in the presence of at least one telogen and/or comonomer, the telogen and/or comonomer is added at at least two addition points in different segments of the polymerization apparatus.
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