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公开(公告)号:JPH11147865A
公开(公告)日:1999-06-02
申请号:JP24707398
申请日:1998-09-01
Applicant: BASF AG
Inventor: KRAMER ANDREAS , SIEGEL WOLFGANG , HENNINGSEN MICHAEL , GROSCH GEORG HEINRICH
IPC: B01J23/02 , C07B61/00 , C07C253/00 , C07C255/06 , C07C255/07 , C07C255/31
Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound in a short retention time and in a good yield by dehydrating a specific oxime in the presence of a specific heterogeneous catalyst in a gaseous or liquid phase at a temperature within a specified temperature range. SOLUTION: This method for producing an aliphatic unsaturated nitrile of formula II [R, R and R are each a 1-20C alkyl or the like; (n) is 0-20] comprises hydrating (A) an oxime of formula I (preferably citral oxime) in the presence of (B) (i) a heterogeneous catalyst comprising an oxide, carbide or nitride carrier (preferably aluminum trioxide) doped with a basic oxide and/or hydroxide [preferably an alkali(ne earth) metal oxide or the like] or a compound capable of being converted into one of the compounds under the reaction conditions, preferably in an amount of 0.1-50 wt.% (converted into the oxide) or (ii) a heterogeneous catalyst comprising a basic oxide, at a temperature of 150-300 deg.C in a gaseous or liquid phase under a pressure of preferably 0.5-5 bars.
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公开(公告)号:WO2004006666A2
公开(公告)日:2004-01-22
申请号:PCT/EP0306888
申请日:2003-06-30
Applicant: BASF AG , AMMERMANN EBERHARD , STIERL REINHARD , SCHOEFL ULRICH , SCHELBERGER KLAUS , SCHERER MARIA , HENNINGSEN MICHAEL , GOLD RANDALL EVEN
Inventor: AMMERMANN EBERHARD , STIERL REINHARD , SCHOEFL ULRICH , SCHELBERGER KLAUS , SCHERER MARIA , HENNINGSEN MICHAEL , GOLD RANDALL EVEN
IPC: A01N25/04 , A01N43/32 , A01N43/653 , A01N
CPC classification number: A01N43/32 , A01N43/653 , A01N2300/00
Abstract: The invention relates to fungicidal mixtures containing, in a synergistically effective amount: A) the compound of formula (I) and; B) at least one azole derivative II selected from the group consisting of compounds (II-1) to (II-7). The invention also relates to methods for controlling harmful fungi by using mixtures of compounds (I) and (II), and to the use of compounds (I) and (II) for producing mixtures of this type.
Abstract translation: 一种杀真菌混合物,包含:A)通式(I)和B)至少一种唑类衍生物选自化合物(II-1的IIausgewäht)至(II-7)的化合物在协同有效量,方法用于控制使用混合物防治有害真菌的 化合物(I)和(II)以及化合物(I)和(II)在制备这种混合物中的用途。
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公开(公告)号:EP0813518A1
公开(公告)日:1997-12-29
申请号:EP96905802
申请日:1996-02-27
Applicant: BASF AG
Inventor: HENNINGSEN MICHAEL , KANDZIA CHRISTOF , DOYE SVEN
IPC: C07D241/06 , B01J23/04 , C07B61/00 , C07C253/00 , C07C255/30 , C07C303/02 , C07C303/32 , C07C309/08 , C07C309/14 , C07C253/08
CPC classification number: C07C303/22 , C07C303/02 , C07C303/32 , C07D241/06 , C07C309/08 , C07C309/14
Abstract: An improved process is disclosed for preparing α,β-diaminoacrylnitriles having the general formula (I) R?3R2NC(R1)=C(NR2R3¿)CN, in which R1 stands for hydrogen, substituted or non-substituted aliphatic residues with 1 to 30 carbon atoms, cycloaliphatic residues with 3 to 8 ring members or aromatic, heteroaromatic or araliphatic residues with 7 to 12 carbon atoms; R?2 and R3¿ are the same or different and stand for hydrogen or an aliphatic residue with 1 to 15 carbon atoms, a cycloaliphatic residue with 3 to 8 ring members or an aromatic, heterocyclic or araliphatic residue with 7 to 12 carbon atoms, or residues R?2 and R3¿ may be bound together into a 5- or 6-membered ring that may also carry another heteroatom. In this process, component (A) is reacted with components (B), (C) and (D) in any desired order. (A) is an α-dicarbonyl compound having the general formula R1COCHO, in which R1 has the above-said meaning, or a reactive derivative of said carbonyl compound. (B) is a salt of sulphurous acid, sulphur dioxide or a sulphur dioxide-releasing reactive. (C) is an amine having the general formula HNR2R3 or an aliphatic diamine having the general formula R3HN-(CH¿2?)n-NHR?3¿, in which the alkylene chain may also bear an R1 substituent having, like R3, the above-said meaning and n equals 2 or 3, or derivatives that are converted into amine or diamine in reaction conditions. (D) is liquid or gaseous hydrocyanic acid or a hydrocyanic acid-releasing reactive. The reaction is carried out with at least 3.5 equivalent alkali compounds per mole of component A. The most part of the alkaline compound consists of potassium compounds and at least one alkali equivalent is added as a free alkaline lye, provided that the proportion of potassium equivalents be sufficiently high for all inorganic salts to remain practically completely in solution at the end of the reaction.
Abstract translation: 公开了用于制备具有通式(I)R 3 R 2 NC(R 1)= C(NR 2 R 3)CN的α,β-二氨基丙烯腈的改进方法,其中R 1代表氢,取代或未取代的脂族残基, 30个碳原子,具有3至8个环成员的环脂族残基或具有7至12个碳原子的芳族,杂芳族或芳脂族残基; R 2和R 3相同或不同,代表氢或具有1至15个碳原子的脂族残基,具有3至8个环成员的脂环族残基或具有7至12个碳原子的芳族,杂环或芳脂族残基, 或者残基R 2和R 3可以一起结合成也可带有另一个杂原子的5-或6-元环。 在该方法中,组分(A)以任何所需顺序与组分(B),(C)和(D)反应。 (A)是具有通式R 1 COCHO的α-二羰基化合物,其中R 1具有上述含义或所述羰基化合物的反应性衍生物。 (B)是亚硫酸,二氧化硫或释放二氧化硫的活性成分的盐。 (C)是具有通式HNR2R3的胺或具有通式R3HN-(CH2)n-NHR'3的脂族二胺,其中亚烷基链还可以带有R1取代基,其具有如R3, 上述含义和n等于2或3,或在反应条件下转化为胺或二胺的衍生物。 (D)是液态或气态氢氰酸或释放氢氰酸的反应性物质。 该反应用每摩尔组分A至少3.5当量碱性化合物进行。碱性化合物的大部分由钾化合物组成并且至少一种碱当量以游离碱性碱液形式加入,条件是钾当量 对于所有无机盐而言足够高以在反应结束时实际上完全保留在溶液中。
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公开(公告)号:PL206012B1
公开(公告)日:2010-06-30
申请号:PL37326403
申请日:2003-06-30
Applicant: BASF AG
Inventor: AMMERMANN EBERHARD , STIERL REINHARD , SCHOEFL ULRICH , SCHELBERGER KLAUS , SCHERER MARIA , HENNINGSEN MICHAEL , GOLD RANDALL EVEN
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公开(公告)号:CR7620A
公开(公告)日:2008-10-06
申请号:CR7620
申请日:2004-12-10
Applicant: BASF AG
Inventor: AMMERMANN EBERHARD , STIERL REINHARD , SCHOFL ULRICH , SCHELBERGER KLAUS , SCHERER MARIA , HENNINGSEN MICHAEL , GOLD RANDALL EVEN
Abstract: Mezclas fungicidas que contienen A) el compuesto de la formula I y B) una bifenilamid de la f romula II, en la que Z significa un anillo piridiilo o un anillo heteroarilo con cinco miembros, que contiene junto con atomos de carbono uno o dos atomso de nitrogeno o un atomo de nitrogeno y un atomo de oxigeno o de azufre, en dode Z lleva uno a tres sustituyentes iguales o diferentes del grupo: halogeno, metilo o trifluorometilo, y X significa halogeno, en una cantidad sinergetica activa, procedimientos para controlar hongos nocivos con mezclas de los compuestos I y II y el uso de los compuestos I y II y el uso de los compuestos I y II para la obtencion de tales mezclas.
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公开(公告)号:AU2003246636B2
公开(公告)日:2008-08-28
申请号:AU2003246636
申请日:2003-06-30
Applicant: BASF AG
Inventor: GOLD RANDALL EVEN , SCHOFL ULRICH , SCHERER MARIA , STIERL REINHARD , HENNINGSEN MICHAEL , SCHELBERGER KLAUS , AMMERMANN EBERHARD
Abstract: Fungicidal mixtures, comprising A) a phenylhydrazide I selected from the compounds Ia and Ib and B) the compound of the formula II in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II and the use of the compounds I and II for preparing such mixtures are described.
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公开(公告)号:AU2002310949C1
公开(公告)日:2008-08-07
申请号:AU2002310949
申请日:2002-03-15
Applicant: BASF AG
Inventor: KUSCHE ANDREAS , GERLACH TILL , KASHAMMER STEFAN , HULLMANN MICHAEL , HENNINGSEN MICHAEL , RUB LOTHAR
IPC: C07D265/30 , C07B61/00 , C07D295/02 , C07D295/023 , C07D295/03 , C07D295/033
Abstract: The present invention relates to a process for the preparation of N-substituted 2,6-dialkylmorpholines of the formula I in which R 1 and R 2 , independently of one another, are hydrogen, alkyl or cycloalkyl, or R 1 and R 2 together with the carbon atom to which they are bonded are a 5- to 14-membered carbocycle, and R 3 and R 4 , independently of one another, are alkyl or cycloalkyl, by reacting at least one carbonyl compound of the formula II in which R 1 and R 2 have the meanings given above, with at least one morpholine of the formula III in which R 3 and R 4 have the meanings given above, in the presence of hydrogen and at least one metal-containing catalyst, wherein the active component of the catalyst consists essentially of platinum group metals.
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公开(公告)号:NZ537164A
公开(公告)日:2007-07-27
申请号:NZ53716403
申请日:2003-06-30
Applicant: BASF AG
Inventor: AMMERMANN EBERHARD , STIERL REINHARD , SCHELBERGER KLAUS , SCHERER MARIA , HENNINGSEN MICHAEL , GOLD RANDALL EVEN , SCHOFL ULRICH
IPC: A01N43/32 , A01N29/04 , A01N35/06 , A01N43/18 , A01N43/653
Abstract: Disclosed are fungicidal mixtures containing in a synergistically effective amount the compound of formula I and the compound of formula II-3, the mixture may additionally comprise a selected azole derivative. Also disclosed are methods for controlling harmful fungi by using mixtures of compounds I and II-3.
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公开(公告)号:UA79803C2
公开(公告)日:2007-07-25
申请号:UA2005000944
申请日:2003-06-30
Applicant: BASF AG
Inventor: AMMERMANN EBERHARD , STIERL REINHARD , SCHOEFL ULRICH , SCHELBERGER KLAUS , SCHERER MARIA , HENNINGSEN MICHAEL , GOLD RANDALL EVEN
IPC: A01N25/04 , A01N43/32 , A01N43/653 , A01P3/00
Abstract: The invention relates to fungicidal mixtures containing, in a synergistically effective amount: A) the compound of formula (I) and; B) at least one azole derivative II selected from the group consisting of compounds (II-l) to (II-7). The invention also relates to methods for controlling harmful fungi by using mixtures of compounds (1) and (II), and to the use of compounds (I) and (II) for producing mixtures of this type.
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公开(公告)号:DK1524906T3
公开(公告)日:2007-07-16
申请号:DK03740378
申请日:2003-06-30
Applicant: BASF AG
Inventor: AMMERMANN EBERHARD , STIERL REINHARD , SCHOEFL ULRICH , SCHELBERGER KLAUS , SCHERER MARIA , HENNINGSEN MICHAEL , GOLD RANDALL EVEN
Abstract: Fungicidal mixtures, comprising A) the compound of the formula I and B) the compound of the formula II in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II and the use of the compounds I and II for preparing such mixtures are described.
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