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公开(公告)号：JP2005179673A
公开(公告)日：2005-07-07
申请号：JP2004363611
申请日：2004-12-15
Applicant: Basf Ag , ビーエーエスエフ アクチェンゲゼルシャフト
Inventor： HAUBNER MARTIN , PINKOS ROLF , WOHLFARTH MICHAEL , WECK ALEXANDER
Abstract: PROBLEM TO BE SOLVED: To provide a method for copolymerizing THF with an α, ω-diol in the presence of heteropolyacid, more economically, at a higher polymerization conversion, and more accurately in control of average-molecular weight.
SOLUTION: The method for continuously producing tetrahydrofuran-copolymer comprises copolymerizing tetrahydrofuran with an α, ω-diol in a reaction cascade in the presence of a heteropolyacid and a telogen, wherein the telogen and/or the α, ω-diol are added in the first reactor of the cascade and water is distilled away from at least one reactor to outside the polymerization reaction.
COPYRIGHT: (C)2005,JPO&NCIPIAbstract translation: 待解决的问题：为了提供在杂多酸存在下，更经济地，更高的聚合转化率，更准确地控制平均分子量的THF与THF，THF的共聚方法。 解决方案：连续生产四氢呋喃共聚物的方法包括在杂多酸和脱氨基的存在下，在反应级联中使四氢呋喃与α，ω-二醇共聚，其中前体和/或α，ω-二醇是 加入到级联的第一反应器中，并将水从至少一个反应器蒸馏除去聚合反应。 版权所有（C）2005，JPO＆NCIPI
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公开(公告)号：WO2004058855A8
公开(公告)日：2004-10-14
申请号：PCT/EP0314790
申请日：2003-12-23
Applicant: BASF AG , SCHLITTER STEPHAN , HAUBNER MARTIN , ZEHNER PETER , HESSE MICHAEL , WECK ALEXANDER , PINKOS ROLF , GRASSLER THOMAS
Inventor： SCHLITTER STEPHAN , HAUBNER MARTIN , ZEHNER PETER , HESSE MICHAEL , WECK ALEXANDER , PINKOS ROLF , GRASSLER THOMAS
CPC classification number: C08G65/2654 , C08G65/2657
Abstract: The invention relates to a method for producing polytetrahydrofuran, polytetrahydrofuran copolymer, polytetrahydrofuran diester, or polytetrahydrofuran monoester by polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer and an acid heterogeneous catalyst based on activated layered silicates or mixed metal oxides in a fluidized bed.
Abstract translation: 本发明涉及一种通过在基于在流化床活化的层状硅酸盐或混合的金属氧化物的酸性非均相催化剂中的至少一个休止期和/或共聚单体的存在和聚合四氢呋喃制备的聚四氢呋喃，聚四氢呋喃共聚物，二酯或单酯的方法。
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公开(公告)号：WO2004026853A3
公开(公告)日：2004-11-18
申请号：PCT/EP0308403
申请日：2003-07-30
Applicant: BASF AG , PINKOS ROLF , KAESHAMMER STEFAN , MENGER VOLKMAR , HAUBNER MARTIN , GROLL PETER , SCHLITTER STEPHAN , PFAFF KLAUS-PETER
Inventor： PINKOS ROLF , KAESHAMMER STEFAN , MENGER VOLKMAR , HAUBNER MARTIN , GROLL PETER , SCHLITTER STEPHAN , PFAFF KLAUS-PETER
IPC: C07D307/08 , C08G65/20 , C08G65/26
CPC classification number: C08G65/20 , C07D307/08 , C08G65/2666
Abstract: The invention relates to a method for the continuous production of THF by reacting a reaction mixture containing 1.4-butandiol with a non-predried heteropolyacidic catalyst. The invention is characterised in that the reaction mixture contains 2-(4-hydroxybutoxy)-tetrahydrofuran.
Abstract translation: 本发明涉及一种用于通过向干燥的非预杂多酸催化剂的含1,4-丁二醇的反应混合物的反应连续制备THF的过程，其特征在于，2-（4-羟基丁氧基） - 四氢呋喃的反应混合物中包含的内容。
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公开(公告)号：WO2004087787A3
公开(公告)日：2005-01-06
申请号：PCT/EP2004003345
申请日：2004-03-30
Applicant: BASF AG , HAUBNER MARTIN , PINKOS ROLF , SCHLITTER STEPHAN
Inventor： HAUBNER MARTIN , PINKOS ROLF , SCHLITTER STEPHAN
IPC: C08G65/20
CPC classification number: C08G65/20 , C08G2650/08 , C08G2650/68
Abstract: The invention relates to a method for single-step production of polyoxyalkylene glycols by copolymerization of THF and neopentyl glycol in the presence of a heteropoly acid, characterized in that the overall amount of all impurities of general formula (I), wherein R and R represent hydrogen when R is an oxyformyl or isopropionate radical, R represents hydrogen and R represents hydroxy when R is an isopropyl radical and R represents hydrogen when R and R together represent an OCH2-C(CH3)-CH2 radical, in the neopentyl glycol is less than 1000 ppm.
Abstract translation: 本发明是一种用于单级制备聚氧化烯二醇的通过THF和在杂多酸的存在下的新戊二醇的共聚发现，其特点是在一个过程，在通式（I）的所有杂质的总量，其中R <1>和R <2 意味着>氢，当R <3>是Oxyformyl-或Isopropionatrest，R <2>的羟基<1>是氢并且R，当R <3>表示异丙基团和R <1>是氢，当R <2> 且R <3>一起形成-OCH 2 C（CH 3）-CH 2残基，新戊基二醇是小于1000ppm。
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公开(公告)号：DE50303129D1
公开(公告)日：2006-06-01
申请号：DE50303129
申请日：2003-09-04
Applicant: BASF AG
Inventor： PINKOS ROLF , GERSTLAUER ACHIM , HAUBNER MARTIN , SCHLITTER STEPHAN , KAESHAMMER STEFAN , PFAFF KLAUS-PETER
IPC: C08G65/20
Abstract: Process for preparation of mono- or diesters of tetrahydrofuran homo- or copolymer by polymerisation of tetrahydrofuran in the presence of at least one telogen and/or comonomers using an acid catalyst where the polymerisation reactor is started with a mixture of polytetrahydrofuran, its mono- or diester and /or tetrahydrofuran copolymer, tetrahydrofuran, optionally a copolymer and at least one carboxylic acid and/or a carboxylic acid anhydride is new.
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Patent Agency Ranking
公开(公告)号：DE10359810A1
公开(公告)日：2005-07-21
申请号：DE10359810
申请日：2003-12-19
Applicant: BASF AG
Inventor： GERSTLAUER ACHIM , HAUBNER MARTIN , SCHLITTER STEPHAN , KAESHAMMER STEFAN
Abstract: A method for the production of mono- and di-esters of poly-tetrahydrofuran (poly-THF) or THF copolymers by polymerisation of THF on an acid catalyst in presence of telogen(s) and/or comonomer(s) (I), in which (I) is/are added to the first reactor of a reactor cascade and the amount of catalyst required for one reactor is divided between all the reactors.
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公开(公告)号：DE10359808A1
公开(公告)日：2005-07-21
申请号：DE10359808
申请日：2003-12-19
Applicant: BASF AG
Inventor： HAUBNER MARTIN , PINKOS ROLF , WOHLFARTH MICHAEL , WECK ALEXANDER
Abstract: A tetrahydrofuran-copolymer is obtained by co-polymerizing tetrahydrofuran with an alpha , omega -diol, in the presence of a heteropolyacid and a telogen. The telogen and/or diol are added in reactor (I) of the process. Water is distilled off directly from reactor (I), besides polymerization, throughout the reaction.
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公开(公告)号：DE10261484A1
公开(公告)日：2004-07-01
申请号：DE10261484
申请日：2002-12-23
Applicant: BASF AG
Inventor： SCHLITTER STEPHAN , HAUBNER MARTIN , ZEHNER PETER , HESSE MICHAEL , WECK ALEXANDER , PINKOS ROLF , GRASLER THOMAS
Abstract: The present invention relates to a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymer, diester or monoester by polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer and of an acidic heterogeneous catalyst based on activated sheet silicates or mixed metal oxides in a fluidized bed.
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公开(公告)号：DE10242286A1
公开(公告)日：2004-03-18
申请号：DE10242286
申请日：2002-09-12
Applicant: BASF AG
Inventor： PINKOS ROLF , GERSTLAUER ACHIM , HAUBNER MARTIN , SCHLITTER STEPHAN , KAESHAMMER STEFAN , PFAFF KLAUS-PETER
Abstract: Process for preparation of mono- or diesters of tetrahydrofuran homo- or copolymer by polymerisation of tetrahydrofuran in the presence of at least one telogen and/or comonomers using an acid catalyst where the polymerisation reactor is started with a mixture of polytetrahydrofuran, its mono- or diester and /or tetrahydrofuran copolymer, tetrahydrofuran, optionally a copolymer and at least one carboxylic acid and/or a carboxylic acid anhydride is new.
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公开(公告)号：DE10210728A1
公开(公告)日：2003-10-02
申请号：DE10210728
申请日：2002-03-12
Applicant: BASF AG
Inventor： HAUBNER MARTIN , MAASEN SIEGMAR , FISCHER ROLF-HARTMUTH , SIGWART CHRISTOPH
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