公开(公告)号：CA2001988A1

公开(公告)日：1990-05-11

申请号：CA2001988

申请日：1989-11-01

Applicant: BASF AG

Inventor： WILD JOCHEN ,  HARREUS ALBRECHT ,  SCHIRMER ULRICH ,  MEYER NORBERT ,  KAST JUERGEN ,  KOLASSA DIETER

IPC: C07C239/20 ,  C07C323/19 ,  C07D209/48

Abstract: Hydroxylamine derivatives have the general formula I Aryl-A-O-B I where Aryl is an unsubstituted or substituted, mononuclear or binuclear, isocyclic radical; A is a 1,4-butenylene group of the general formulae IIa or IIb IIa IIb where R1, R2, R3, R4 and R5 are each hydrogen, halogen, C1-C6-alkyl or C1-C6-alkenyl; B is NH2 or a dicarboximide group of the general formula III III where Z is unsubstituted or substituted phenylene, naphthylene, pyridinylene, cyclopentylene, cyclohexylene, cyclohexenylene, C2-C4-alkenylene or C2-C4-alkylene. The dicarboximides are intermediates for the compounds wherein B is NH2. The latter are used in synthesizing herbicidal compounds.

公开(公告)号：DE10140551A1

公开(公告)日：2003-02-27

申请号：DE10140551

申请日：2001-08-17

Applicant: BASF AG

Inventor： PABST GUNTHER ,  WOLF GERHARD ,  KAST JUERGEN ,  WERNER JUERGEN

IPC: C08G8/28 ,  C08L61/14 ,  C14C3/20 ,  C08G14/08

Abstract: The invention relates to a method for producing a solution of tanning agents containing sulphone. In said method, a) a component A is produced as follows: a1) phenol is reacted with concentrated sulphuric acid or with oleum with an SO3 content of between 20 and 65 wt. %, or with a mixture of sulphuric acid and oleum with an SO3 content of between 20 and 65 wt. %, whereby the molar ratio of total sulphuric acid, calculated in the form of SO3 to phenol is between 0.7: 1 and 1.5: 1, at a temperature of between 100 and 180 DEG C to obtain a mixture containing phenolsulphonic acid, dihydroxydiphenyl sulphone and sulphuric acid, or the individual components are blended to produce a corresponding mixture; a2) said mixture is subsequently condensed at between 40 and 90 DEG C per mol of phenol units present with between 0.25 and 4 mol of urea and between 0.5 and 4 mol of an aliphatic aldehyde comprising between 1 and 6 C atoms, a3) optionally a pH value of between 4 and 5 is set by adding a base; b) a component B is produced as follows: b1) dihydroxydiphenyl sulphone is reacted with between 0.5 and 5 mol of an aliphatic aldehyde comprising between 1 and 6 C atoms and between 0.4 and 2 mol of sodium sulphite per mol of dihydroxydiphenyl sulphone, at a temperature of between 90 and 180 DEG C; b2) optionally a pH value of between 3.5 and 5.5 is set by adding an acid. c) Between 10 and 90 wt. % of component A is mixed with between 90 and 10 wt. % of component B, (the sum of A and B amounting to 100 wt. %) and if not already accomplished in steps a3) and b2), the pH value of the mixture is set at between 3.5 and 5.5.

公开(公告)号：AT164583T

公开(公告)日：1998-04-15

申请号：AT94905039

申请日：1994-01-12

Applicant: BASF AG

Inventor： PLATH PETER ,  RENTZEA COSTIN ,  MEYER NORBERT ,  KAST JUERGEN ,  KARDORFF UWE ,  GERBER MATTHIAS ,  WALTER HELMUT ,  LANDES ANDREAS ,  WESTPHALEN KARL-OTTO

IPC: A01N43/42 ,  A01N43/90 ,  C07D221/08 ,  C07D491/04 ,  C07D491/052 ,  C07D311/00 ,  C07D221/00

Abstract: A process is disclosed for controlling undesirable plant growth and for regulating plant growth, by applying to the plants derivatives of azaanthraquinones and/or azaxanthones having formula (I), in which X, Y, Z and the residues R to R have the following meanings: R is hydrogen, methyl; R -R are (a) hydrogen, (b) halogen, (c) nitro, (d) COOR , in which R stands for C1-C4-alkyl, (e) CONH2 and CONR R , in which R and R stand for C1-C4-alkyl, (f) C1-C8-alkyl, which may bear one to three of the following substituents: halogen, hydroxy, C1-C6-alkoxy, (g) C3-C6-alkenyl, (h) C1-C4-alkoxy, (i) hydroxy, (j) amino or NR R , (k) phenyl, which may bear one to five halogen atoms or one to three of the following substituents: nitro, C1-C4-alkoxy, C1-C4-alkyl or C1-C4alkyl halide; X, Y are N, N -O or CH, with the proviso that only a nitrogen atom or a N-oxide group be contained in the ring; Z is oxygen, sulphur or a C = O group; A is oxygen or sulphur. Also disclosed are new azaanthraquinones and azaxanthones and herbicidal and bioregulatory agents containing the same.

公开(公告)号：HU212702B

公开(公告)日：1996-10-28

申请号：HU154191

申请日：1991-05-08

Applicant: BASF AG

Inventor： HAGEN HELMUT ,  KAST JUERGEN ,  LANDES ANDREAS ,  MISSLITZ ULF ,  NILZ GERHARD ,  PFISTER JUERGEN ,  SAUPE THOMAS ,  WALTER HELMUT

IPC: A01N25/32 ,  A01N35/10 ,  A01N37/34 ,  A01N37/44 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/28 ,  A01N43/653 ,  A01N43/80 ,  A01N43/836 ,  A01N43/82

Abstract: Herbicidal agent containing a naphthalene derivative I (R = alkyl, alkylthio, haloalkyl, alkoxy, halogen, OH, NO2 and/or benzyl; m = 0, 1, 2 or 3; R = -CN, -C(NH2)NOH, -C(Z)TR , R = halogen, -NR R , -N=CH-R , -NR -SO2R , COOR , OH, Z = O, S; T = O, -NR ; R = H, optionally substituted alkyl, phenyl or benzyl; R = optionally substituted phenyl; R = H, optionally substituted alkyl or phenyl; R = H or optionally substituted alkyl; R = optionally substituted alkyl, phenyl or an optionally substituted heteroaromatic ring; R = optionally substituted alkyl or phenyl, or the R radicals together are an optionally substituted alkylene or alkenylene chain, or an optionally substituted fused benzene ring; R and R = alkyl or, together with the joint carbon atom, cycloalkyl; B = H, optionally substituted alkyl, alkoxycarbonyl, phenyl or -NR R -) as an antidote, and at least one herbicidal active substance from the group of the cyclohexenone derivatives.

公开(公告)号：HU212620B

公开(公告)日：1996-09-30

申请号：HU154591

申请日：1991-05-08

Applicant: BASF AG

Inventor： GERBER MATTHIAS ,  GOETZ NORBERT ,  HARREUS ALBRECHT ,  KAST JUERGEN ,  MEYER NORBERT ,  MISSLITZ ULF ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  WUERZER BRUNO

IPC: A01N35/10 ,  A01N43/14 ,  C07C239/20 ,  C07D309/06 ,  C07D335/02 ,  A01N43/76 ,  A01N43/80 ,  C07C251/50 ,  C07D261/08 ,  C07D263/32 ,  C07D309/04

公开(公告)号：AT141266T

公开(公告)日：1996-08-15

申请号：AT93917360

申请日：1993-01-30

Applicant: BASF AG

Inventor： MISSLITZ ULF ,  MEYER NORBERT ,  KAST JUERGEN ,  BOTT KASPAR ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  KARDORFF UWE ,  GERBER MATTHIAS

IPC: A01N35/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/56 ,  A01N43/80 ,  C07C251/54 ,  C07C323/28 ,  C07C323/47 ,  C07D231/12 ,  C07D261/08 ,  C07D309/06 ,  C07D333/22 ,  C07D335/02

Abstract: PCT No. PCT/EP93/00215 Sec. 371 Date Aug. 11, 1994 Sec. 102(e) Date Aug. 11, 1994 PCT Filed Jan. 30, 1993 PCT Pub. No. WO93/16063 PCT Pub. Date Aug. 19, 1993.Cyclohexenone oxime ethers I I R1=C1-C6-alkyl; W=unsubstituted or C1-C3-alkyl-substituted C2-C4-alkylene chain; X=NO2, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl; n=0-3 or 1-5 if all X's are halogen; R2 =C1-C4-alkoxy-C1-C6-alkyl, C1-C4-alkylthio-C1-C6-alkyl, substituted or unsubstituted C3-C7-cycloalkyl, substituted or unsubstituted C5-C7-cycloalkenyl, a substituted or unsubstituted 5-membered saturated heterocycle containing 1 or 2 oxygen and/or sulfur atoms, substituted or unsubstituted 6- or 7-membered heterocycle having 1 or 2 non-adjacent oxygen and/or sulfur atoms and which is saturated or mono- or diunsaturated, substituted or unsubstituted 5-membered heteroaromatic containing 1 or 2N atoms and one O or S atom, phenyl or pyridyl, both of which are unsubstituted or bear 1-3 halogen, NO2, CN, alkyl, alkoxy, alkyl-thio, haloalkyl, alkenyloxy, alkynyloxy and/or -NRaRb substituents; Ra=H, alkyl, alkenyl or alkynyl and Rb=H, alkyl, alkenyl, alkynyl, acyl or substituted or unsubstituted benzoyl; and agriculturally utilizable salts and esters of compounds I with C1-C10-carboxylic acids and inorganic acids.

公开(公告)号：HUT72271A

公开(公告)日：1996-04-29

申请号：HU9502175

申请日：1994-01-12

Applicant: BASF AG

Inventor： GERBER MATTHIAS ,  KARDORFF UWE ,  KAST JUERGEN ,  LANDES ANDREAS ,  MEYER NORBERT ,  PLATH PETER ,  RENTZEA COSTIN ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO

IPC: A01N43/42 ,  A01N43/90 ,  C07D221/08 ,  C07D491/04 ,  C07D491/052

Abstract: A process is disclosed for controlling undesirable plant growth and for regulating plant growth, by applying to the plants derivatives of azaanthraquinones and/or azaxanthones having formula (I), in which X, Y, Z and the residues R to R have the following meanings: R is hydrogen, methyl; R -R are (a) hydrogen, (b) halogen, (c) nitro, (d) COOR , in which R stands for C1-C4-alkyl, (e) CONH2 and CONR R , in which R and R stand for C1-C4-alkyl, (f) C1-C8-alkyl, which may bear one to three of the following substituents: halogen, hydroxy, C1-C6-alkoxy, (g) C3-C6-alkenyl, (h) C1-C4-alkoxy, (i) hydroxy, (j) amino or NR R , (k) phenyl, which may bear one to five halogen atoms or one to three of the following substituents: nitro, C1-C4-alkoxy, C1-C4-alkyl or C1-C4alkyl halide; X, Y are N, N -O or CH, with the proviso that only a nitrogen atom or a N-oxide group be contained in the ring; Z is oxygen, sulphur or a C = O group; A is oxygen or sulphur. Also disclosed are new azaanthraquinones and azaxanthones and herbicidal and bioregulatory agents containing the same.

公开(公告)号：HU9502175D0

公开(公告)日：1995-09-28

申请号：HU9502175

申请日：1994-01-12

Applicant: BASF AG

Inventor： KARDORFF UWE ,  KAST JUERGEN ,  WESTPHALEN KARL-OTTO ,  RENTZEA COSTIN ,  WALTER HELMUT ,  LANDES ANDREAS ,  MEYER NORBERT ,  PLATH PETER ,  GERBER MATTHIAS

IPC: A01N43/42 ,  A01N43/90 ,  C07D221/08 ,  C07D491/04 ,  C07D491/052

Abstract: A process is disclosed for controlling undesirable plant growth and for regulating plant growth, by applying to the plants derivatives of azaanthraquinones and/or azaxanthones having formula (I), in which X, Y, Z and the residues R to R have the following meanings: R is hydrogen, methyl; R -R are (a) hydrogen, (b) halogen, (c) nitro, (d) COOR , in which R stands for C1-C4-alkyl, (e) CONH2 and CONR R , in which R and R stand for C1-C4-alkyl, (f) C1-C8-alkyl, which may bear one to three of the following substituents: halogen, hydroxy, C1-C6-alkoxy, (g) C3-C6-alkenyl, (h) C1-C4-alkoxy, (i) hydroxy, (j) amino or NR R , (k) phenyl, which may bear one to five halogen atoms or one to three of the following substituents: nitro, C1-C4-alkoxy, C1-C4-alkyl or C1-C4alkyl halide; X, Y are N, N -O or CH, with the proviso that only a nitrogen atom or a N-oxide group be contained in the ring; Z is oxygen, sulphur or a C = O group; A is oxygen or sulphur. Also disclosed are new azaanthraquinones and azaxanthones and herbicidal and bioregulatory agents containing the same.

公开(公告)号：LV10361A

公开(公告)日：1995-02-20

申请号：LV930433

申请日：1993-05-27

Applicant: BASF AG

Inventor： MISSLITZ ULF ,  MEYER NORBERT ,  KAST JUERGEN ,  GOETZ NORBERT ,  HARREUS ALBRECHT ,  KUEKENHOEHNER THOMAS ,  WUERZER BRUNO ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  GERBER MATTHIAS

IPC: C07D213/30 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/36 ,  A01N43/40 ,  A01P13/00 ,  C07D207/32 ,  C07D207/333 ,  C07D307/38 ,  C07D307/42 ,  C07D333/16 ,  C07D333/28 ,  C07D405/08 ,  C07D405/12 ,  C07D407/08 ,  C07D407/12 ,  C07D409/08 ,  C07D409/12 ,  A01N33/24 ,  A01N35/10 ,  C07C251/32

Abstract: Cyclohexenone oxime ethers of the formula I (I) (R1=C1-C6-alkyl; A=substituted or unsubstituted alkylene or alkenylene; Z=a 5-membered or 6-membered heteroaromatic structure; X=substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkyl, C1-C4-haloalkoxy, carboxyl, C1-C4-alkoxycarbonyl, substituted or unsubstituted benzyloxycarbonyl and phenyl; n=0 to 3, or 1 to 4 where Z is halogen-substituted pyridyl; and R2=alkoxyalkyl or alkylthioalkyl; substituted or unsubstituted cycloalkyl or cycloalkenyl; a substituted or unsubstituted 5-membered saturated heterocyclic structure which contains one or two hetero atoms; a substituted or unsubstituted 6-membered or 7-membered saturated or mono- or diunsaturated heterocyclic structure containing one or two hereto atoms; a substituted or unsubstituted 5-membered heteroaromatic structure containing one to three hereto atoms; substituted or unsubstituted phenyl or pyridyl) and their agriculturally useful salts and esters of C1-C10-carboxylic acids and inorganic acids. The compounds are suitable as herbicides.

公开(公告)号：AT110708T

公开(公告)日：1994-09-15

申请号：AT91107095

申请日：1991-05-02

Applicant: BASF AG

Inventor： MISSLITZ ULF DR ,  MEYER NORBERT DR ,  KAST JUERGEN ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR ,  WUERZER BRUNO DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

IPC: A01N35/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/28 ,  A01P13/00 ,  C07C215/50 ,  C07C239/20 ,  C07C251/42 ,  C07C251/48 ,  C07C251/50 ,  C07C251/54 ,  C07C323/29 ,  C07C323/47 ,  C07D233/88 ,  C07D249/04 ,  C07D249/14 ,  C07D263/32 ,  C07D275/02 ,  C07D277/20 ,  C07D277/24 ,  C07D277/26 ,  C07D277/28 ,  C07D277/30 ,  C07D307/14 ,  C07D307/40 ,  C07D307/42 ,  C07D309/04 ,  C07D309/06 ,  C07D309/20 ,  C07D317/28 ,  C07D333/16 ,  C07D333/26 ,  C07D335/02 ,  C07D339/06 ,  C07D401/08 ,  C07D403/08 ,  C07D405/08 ,  C07D407/12 ,  C07D409/08 ,  C07D409/12 ,  C07D411/08 ,  C07D413/08 ,  C07D417/12

Abstract: Cyclohexenone oxime ethers (I) where R1 is alkyl; A is substituted or unsubstituted alkylene or alkenylene, where methylene is replaced by an oxygen atom, a sulfur atom, a sulfoxyl group, a sulfonyl group or -NRa-, Z is phenyl or a 5- or 6-membered heteroaromatic structure; X is substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkyl, C1-C4-haloalkoxy, carboxyl, C1-C4-alkoxycarbonyl, substituted or unsubstituted benzyloxycarbony or phenyl; n is 0 to 3, or 1 to 5 where X is halogen; R2 is alkoxyalkyl or alkylthioalkyl, substituted or unsubstituted cycloalkyl or cycloalkenyl, a substituted or unsubstituted 5-membered saturated heterocyclic structure with one or two heteroatoms, a substituted or unsubstituted 6- or 7-membered heterocyclic structure with 1-2 heteroatoms and 0-2 double bonds, a substituted or unsubstituted 5-membered heteroaromatic radical with 1-3 heteroatoms, or substituted or unsubstituted phenyl or pyridyl, and their agriculturally useful salts and esters of C1-C10-carboxylic acids and inorganic acids, processes for their manufacture, and their use as herbicides.