公开(公告)号：ES2109092T3

公开(公告)日：1998-01-01

申请号：ES95908266

申请日：1995-02-06

Applicant: BASF AG

Inventor： KNEIP MICHAEL ,  DANISCH PETER

IPC: C08L83/06 ,  C08L83/08 ,  C14C9/00

Abstract: PCT No. PCT/EP95/00418 Sec. 371 Date Aug. 15, 1996 Sec. 102(e) Date Aug. 15, 1996 PCT Filed Feb. 6, 1995 PCT Pub. No. WO95/22627 PCT Pub. Date Aug. 24, 1995Leather and skins are water repellent in aqueous emulsion in the presence of emulsifiers with polysiloxanes which are functionalized with carboxyl groups in a comb-like manner and in which the carboxyl groups are bonded to the polymer main chain via spacer groups in the form of linear or branched C2-C40-alkylene groups which may be interrupted by up to 8 non-neighboring oxygen atoms or groups of the formula -NR1-, CO- [sic] or -CO-NR1- and in addition may carry up to 5 carboxyl groups or carboxamido groups of the formula -CO-NR1R2-, where R1 and R2 are each hydrogen or C1-C4-alkyl, the spacer groups being bonded to the polymer main chain via a direct bond or via an oxygen atom or a group of the formula -NR1-, -CO-, -CO-NR1- or -CO-O-.

公开(公告)号：ES2108289T3

公开(公告)日：1997-12-16

申请号：ES93915893

申请日：1993-07-13

Applicant: BASF AG

Inventor： BIRKHOFER HERMANN ,  DANISCH PETER ,  DENZINGER WALTER ,  HARTMANN HEINRICH ,  KNEIP MICHAEL

IPC: C14C9/00

Abstract: PCT No. PCT/EP93/01831 Sec. 371 Date Mar. 3, 1994 Sec. 102(e) Date Mar. 3, 1994 PCT Filed Jul. 13, 1993 PCT Pub. No. WO94/02650 PCT Pub. Date Feb. 3, 1994Soft leathers with a pleasant hand are obtained on fatliquoring and filling leather and fur skins with water-soluble or water-dispersible graft polymers of vegetable and animal oils, obtainable by radically initiated polymerization A) of a monomer or monomer mixture comprising (a) from 20 to 100% by weight of monoethylenically unsaturated carboxylic acids and/or monoethylenically unsaturated sulfonic acids and/or monoethylenically unsaturated phosphonic acids or their alkali metal, alkaline earth metal or ammonium salts, (b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a), and (c) from 0 to 5% by weight of at least doubly ethylenically unconjugatedly unsaturated monomers in the presence of B) vegetable and/or animal oils in a weight ratio of A:B of (80-1):(20-99).

公开(公告)号：AU1139897A

公开(公告)日：1997-07-03

申请号：AU1139897

申请日：1996-12-02

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  KISTENMACHER AXEL ,  WOLF GERHARD ,  KNEIP MICHAEL ,  GREIF NORBERT ,  OPPENLANDER KNUT

IPC: C08F216/38 ,  C08F222/00 ,  C14C3/22 ,  C14C3/28

公开(公告)号：DE59305160D1

公开(公告)日：1997-02-27

申请号：DE59305160

申请日：1993-05-12

Applicant: BASF AG

Inventor： KNEIP MICHAEL ,  SCHNEIDER JUERGEN ,  OFTRING ALFRED

IPC: C07C227/02 ,  C07C227/00 ,  C07C227/14 ,  C07C227/26 ,  C07C229/16

Abstract: PCT No. PCT/EP93/01171 Sec. 371 Date Oct. 21, 1994 Sec. 102(e) Date Oct. 21, 1994 PCT Filed May 12, 1993 PCT Pub. No. WO93/23363 PCT Pub. Date Nov. 25, 1993.The invention relates to a process for preparing beta -alaninediacetic acid (Ia) or its alkali metal or ammonium salts (Ib) which comprises reacting iminodiacetic acid with acrylonitrile or C1-C4-alkyl acrylates in weakly acid to weakly basic aqueous medium and subsequently hydrolyzing the nitrile or ester moiety to the acid or a salt. The products prepared according to the invention can be used, in particular, to form complexes.

公开(公告)号：AU5003196A

公开(公告)日：1996-10-02

申请号：AU5003196

申请日：1996-03-04

Applicant: BASF AG

Inventor： DANISCH PETER ,  DIX JOHANNES PETER ,  DENZINGER WALTER ,  KISTENMACHER AXEL ,  KNEIP MICHAEL ,  MULLER HANS-JOACHIM ,  ROSCH JOACHIM ,  SCHORNICK GUNNAR

IPC: C08F210/14 ,  C08F222/00 ,  C08F255/02 ,  C08F290/04 ,  C09B67/46 ,  C09D17/00 ,  C09K23/52 ,  C14C9/00

Abstract: Aqueous solutions or aqueous emulsions of copolymers are obtainable by copolymerization of(a) from 20 to 95 mol % of at least one monoethylenically unsaturated C4-C12-dicarboxylic acid or the anhydride thereof with(b) from 5 to 80 mol % of at least one branched oligomer or polymer which has a vinyl, vinylidene or alkylvinylene terminal group and is of at least 9 carbon atoms and(c) from 0 to 50 mol % of at least one further monoethylenically unsaturated compound which is copolymerizable with the monomers (a) and (b)and contain from 0.5 to 70% by weight, based on the total amount of the solutions or emulsions, of these copolymers. These copolymer solutions or emulsions are suitable as leather assistants and as dispersants for pigments.

公开(公告)号：ES2174322T3

公开(公告)日：2002-11-01

申请号：ES97951194

申请日：1997-11-13

Applicant: BASF AG

Inventor： FRIEDRICH HOLGER ,  KNEIP MICHAEL ,  LEUTNER BERND

IPC: C08G77/388 ,  C08L83/08 ,  C09D183/08 ,  C14C9/00 ,  D06M15/643

Abstract: PCT No. PCT/EP97/06348 Sec. 371 Date Jul. 16, 1999 Sec. 102(e) Date Jul. 16, 1999 PCT Filed Nov. 13, 1997 PCT Pub. No. WO98/21369 PCT Pub. Date May 22, 1998Specific carboxyamide-polysiloxanes of the formula IV or the formula IVa having a carboxyl content of from 0.02 to 1.0 mmol/g and an average molar mass (number average) [Mn] in the range from 2x103 to 60x103 g/mol are used for hydrophobicizing materials of fibrous structure, especially leather or fur skins.

公开(公告)号：AU736657B2

公开(公告)日：2001-08-02

申请号：AU2292697

申请日：1997-03-27

Applicant: BASF AG

Inventor： KNEIP MICHAEL ,  KISTENMACHER AXEL ,  DANISCH PETER ,  WOLF GERHARD

IPC: C14C3/28 ,  C09D123/08 ,  C14C9/00 ,  C14C9/02

Abstract: Aqueous solutions or dispersions of copolymers obtainable by free-radical copolymerization of(a) from 20 to 90% by weight of at least one monoethylenically unsaturated C4-6-dicarboxylic acid or the anhydride thereof, as component A,(b) from 5 to 50% by weight of at least one olefin having 2 to 6 carbon atoms, as component B,(c) from 5 to 50% by weight of at least one hydrophobic comonomer from the group consisting of long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, long-chain amides of acrylic acid or methacrylic acid, and long-chain alkyl vinyl ethers, as component C,(d) from 0 to 40% by weight of further comonomers which can be copolymerized with the above monomers, as component D,where the sum of the amounts of components A, B, C and, if used, D is 100% by weight, followed by at least partial esterification or hydrolysis and neutralization and/or reaction of the carboxyl groups formed during the hydrolysis with bases, for treating leather and/or fur skins.

公开(公告)号：ES2136390T3

公开(公告)日：1999-11-16

申请号：ES96906734

申请日：1996-03-04

Applicant: BASF AG

Inventor： DANISCH PETER ,  DIX JOHANNES PETER ,  DENZINGER WALTER ,  KISTENMACHER AXEL ,  KNEIP MICHAEL ,  MULLER HANS-JOACHIM

IPC: C08F210/14 ,  C08F222/00 ,  C08F255/02 ,  C08F290/04 ,  C09B67/46 ,  C09D17/00 ,  C09K23/52 ,  C14C9/00

Abstract: Aqueous solutions or aqueous emulsions of copolymers are obtainable by copolymerization of(a) from 20 to 95 mol % of at least one monoethylenically unsaturated C4-C12-dicarboxylic acid or the anhydride thereof with(b) from 5 to 80 mol % of at least one branched oligomer or polymer which has a vinyl, vinylidene or alkylvinylene terminal group and is of at least 9 carbon atoms and(c) from 0 to 50 mol % of at least one further monoethylenically unsaturated compound which is copolymerizable with the monomers (a) and (b)and contain from 0.5 to 70% by weight, based on the total amount of the solutions or emulsions, of these copolymers. These copolymer solutions or emulsions are suitable as leather assistants and as dispersants for pigments.

公开(公告)号：DE59602443D1

公开(公告)日：1999-08-19

申请号：DE59602443

申请日：1996-03-04

Applicant: BASF AG

Inventor： DANISCH PETER ,  DIX JOHANNES ,  DENZINGER WALTER ,  KISTENMACHER AXEL ,  KNEIP MICHAEL ,  MUELLER HANS-JOACHIM ,  ROESCH JOACHIM DR ,  SCHORNICK GUNNAR

IPC: C08F210/14 ,  C08F222/00 ,  C08F255/02 ,  C08F290/04 ,  C09B67/46 ,  C09D17/00 ,  C09K23/52 ,  C14C9/00

Abstract: Aqueous solutions or aqueous emulsions of copolymers are obtainable by copolymerization of(a) from 20 to 95 mol % of at least one monoethylenically unsaturated C4-C12-dicarboxylic acid or the anhydride thereof with(b) from 5 to 80 mol % of at least one branched oligomer or polymer which has a vinyl, vinylidene or alkylvinylene terminal group and is of at least 9 carbon atoms and(c) from 0 to 50 mol % of at least one further monoethylenically unsaturated compound which is copolymerizable with the monomers (a) and (b)and contain from 0.5 to 70% by weight, based on the total amount of the solutions or emulsions, of these copolymers. These copolymer solutions or emulsions are suitable as leather assistants and as dispersants for pigments.

公开(公告)号：BR9708491A

公开(公告)日：1999-08-03

申请号：BR9708491

申请日：1997-03-27

Applicant: BASF AG

Inventor： KNEIP MICHAEL ,  KRISTENMACHER AXEL ,  DANISCH PETER ,  WOLFERT GERHARD

IPC: C14C3/28 ,  C09D123/08 ,  C14C9/00 ,  C14C9/02

Abstract: Aqueous solutions or dispersions of copolymers obtainable by free-radical copolymerization of(a) from 20 to 90% by weight of at least one monoethylenically unsaturated C4-6-dicarboxylic acid or the anhydride thereof, as component A,(b) from 5 to 50% by weight of at least one olefin having 2 to 6 carbon atoms, as component B,(c) from 5 to 50% by weight of at least one hydrophobic comonomer from the group consisting of long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, long-chain amides of acrylic acid or methacrylic acid, and long-chain alkyl vinyl ethers, as component C,(d) from 0 to 40% by weight of further comonomers which can be copolymerized with the above monomers, as component D,where the sum of the amounts of components A, B, C and, if used, D is 100% by weight, followed by at least partial esterification or hydrolysis and neutralization and/or reaction of the carboxyl groups formed during the hydrolysis with bases, for treating leather and/or fur skins.