公开(公告)号：AT108301T

公开(公告)日：1994-07-15

申请号：AT91106993

申请日：1991-04-30

Applicant: BASF AG

Inventor： SAUPE THOMAS DR ,  KAST JUERGEN DR ,  MISSLITZ ULF DR ,  HAGEN HELMUT DR ,  NILZ GERHARD DR ,  PFISTER JUERGEN DR ,  WALTER HELMUT DR ,  LANDES ANDREAS DR

IPC: A01N25/32 ,  A01N35/10 ,  A01N37/34 ,  A01N37/44 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/28 ,  A01N43/653 ,  A01N43/80 ,  A01N43/836

Abstract: Herbicidal agent containing a naphthalene derivative I (R = alkyl, alkylthio, haloalkyl, alkoxy, halogen, OH, NO2 and/or benzyl; m = 0, 1, 2 or 3; R = -CN, -C(NH2)NOH, -C(Z)TR , R = halogen, -NR R , -N=CH-R , -NR -SO2R , COOR , OH, Z = O, S; T = O, -NR ; R = H, optionally substituted alkyl, phenyl or benzyl; R = optionally substituted phenyl; R = H, optionally substituted alkyl or phenyl; R = H or optionally substituted alkyl; R = optionally substituted alkyl, phenyl or an optionally substituted heteroaromatic ring; R = optionally substituted alkyl or phenyl, or the R radicals together are an optionally substituted alkylene or alkenylene chain, or an optionally substituted fused benzene ring; R and R = alkyl or, together with the joint carbon atom, cycloalkyl; B = H, optionally substituted alkyl, alkoxycarbonyl, phenyl or -NR R -) as an antidote, and at least one herbicidal active substance from the group of the cyclohexenone derivatives.

公开(公告)号：DE4135265A1

公开(公告)日：1993-04-29

申请号：DE4135265

申请日：1991-10-25

Applicant: BASF AG

Inventor： KAST JUERGEN DR ,  ZIERKE THOMAS DR ,  BRATZ MATTHIAS DR ,  MISSLITZ ULF DR ,  MEYER NORBERT DR ,  LANDES ANDREAS DR ,  RADEMACHER WILHELM DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

IPC: A01N37/42 ,  A01N37/48 ,  A01N37/50 ,  A01N39/00 ,  C07C67/313 ,  C07C69/757 ,  C07C249/02 ,  C07C249/08 ,  C07C251/18 ,  C07C251/42 ,  C07C251/52 ,  C07C251/54 ,  C07C255/56 ,  C07C255/61 ,  C07C255/62 ,  C07C317/28 ,  C07D295/18 ,  C07D521/00

Abstract: Cyclohexenone derivates have the formula (I), in which R stands for alkyl, alkenyl, alkinyl, cycloalkyl, aloxyalkyl, alkylthioalkyl, possibly substituted phenyl, possibly substituted benzyl, possibly substituted 5-/6-membered heteroaryl; W stands for 0, =N-OR or =N-R ; R stands for possibly substituted alkyl, alkenyl or alkinyl residue, possibly substituted 3- to 6-membered alkyl chain or 4- to 6-membered alkenyl or alkinyl chain, a chain link in each of the chains being substituted by -0-, -S-, -S0-, -S02- or -N(R )-; R stands for H, alkyl, alkenyl, alkinyl, alkylcarbonyl, benzoyl; R stands for H, alkyl hydroxyakyl, alkoxyalkyl or alkylthioalkyl, possibly substituted phenyl, possibly substituted benzyl; X, Y stand for -OR or -NR R ; R stands for H, alkyl, akenyl, alkinyl, alkoxyalkyl, alkylthioalkyl; R stands for H, alkyl, alkenyl, alkinyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl and R stands for H, alkyl, alkenyl, alkinyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl, alkylcarbonyl, possibly substituted benzoyl or R -R form together with the shared N atom a 5-/6-membered heterocycle that may contain -O-, -S- or -N(R )- as ring element; R stands for H, alkyl, alkenyl, alkinyl, alkylcarbonyl, benzoyl. Also disclosed are the agriculturally useful salts and esters of C1-C10-carboxylic acids and anorganic acids of the compounds having the formula (I). These cyclohexenone derivates (I) are useful as herbicides and plant growth regulators.

公开(公告)号：DE4123469A1

公开(公告)日：1993-01-21

申请号：DE4123469

申请日：1991-07-16

Applicant: BASF AG

Inventor： LANDES ANDREAS DR ,  WALTER HELMUT DR ,  HAMPRECHT GERHARD DR

IPC: A01N25/32 ,  A01N43/50 ,  A01N43/52 ,  A01N43/56 ,  A01N43/90

Abstract: Herbicidal compsns. contain an N-dichloroacetyl-diazacycloalkane safener of formula (I) and one or more herbicides of formula (II)-(V). In the formulae, A = 1-4C alkylene with each CH2 gp. opt. substd.; B =a bond or 2-4C alkylene with each CH2 gp. opt. substd.; R1 =H, Me or Et; R2 and R3 = H or Me when B = bond, or R2+R3 = a bond when B = alkylene; Ar = 2-methoxycarbonyl-4-methylphenyl, 2-methoxycarbonyl-5-methylphenyl, etc.; Z = N or CH; X = O or S; W = 2-R4CO-3-R5-phenyl or CH(R10)COR0); R4 = H; pyrrolyl, pyrazolyl, imidazolyl or triazolyl opt. substd., etc. R5 = H; halogen; opt. halogenated 1-4C alkyl or alkoxy; CHO; 2-9C alkoxycarbonyl; opt. halogenated 3-6C alkenyl, alkynyl, etc. R9 = H, 1-10C alkoxy, 1-4C haloalkoxy, 3-6C alkenyloxy, 3-6C alkynyloxy, etc. R10 = 1-10C alkyl opt. substd. or 3-12C cycloalkyl opt. substd.; R11 - H 1-10C alkyl, 3-6C alkenyl, 3-6C ''''nyl, alkali(ne earth) metal, NH4, mono-, di- or tri(1-4C alkyl) ammonium, etc.; R16 = H or Me; R17 = F, Cl, Me, OMe, OCHF2, NHMe or NMe2; R18 = Me, CF3, OMe, OCHF2, OCF3, OCF2Cl, OEt or OCH2CF3; U = 2-R19-phenyl (opt. ring-monosubstd. by halogen or Me), 2-methoxycarbonylbenzyl, 3-dimethylcarbamoyl-2-pyridyl, etc.; R19 = Cl, 2-chloroethoxy, 2-methoxyethoxy, COOMe or COOEt. ADVANTAGE - (I) reduce the phytotoxicity of (II)-(V) to crops, esp. barley, wheat, maize, sorghum and rice.

公开(公告)号：DE4039734A1

公开(公告)日：1992-06-17

申请号：DE4039734

申请日：1990-12-13

Applicant: BASF AG

Inventor： HAGEN HELMUT DR ,  NILZ GERHARD DR ,  WALTER HELMUT DR ,  LANDES ANDREAS DR

IPC: A01N25/32 ,  A01N35/06 ,  A01N39/02 ,  A01N43/10 ,  C07D333/26 ,  C07D333/38 ,  C07D333/62 ,  C07D333/68 ,  C07D333/70 ,  C07D409/04 ,  C07D409/12 ,  C07D417/12

Abstract: Herbicidal agents contain as antagonistic compound at least one substituted 2-aminothiophene having formula (I), in which R , R stand for H, CN, alkyl, halogen alkyl, if necessary substituted phenyl, CO-R or R + R stand for a C3-C6 alkylene chain, upon which a benzene ring, if necessary substituted, may be annulated, a C2-C3 alkylene chain broken by -O- or -N(R )-, which may also carry 1-4 alkenyl residues or a group CO-N(R )-CO; R stands for CN, if necessary substituted -C(NH2)=N-C6H5, -C(NH3 Hal )=N-C6H5, CX-R ; Hal stands for halogen; R stands for H, alkyl, alkenyl, if necessary substituted phenyl, if necessary substituted triazin, -PX(OR )2, -CX-R , -SO2R , -SO2-NHR , -CX-N(R )-CY-R , -CX-N(R )-SO2-R or R =R stand for CO-O-CO; R stands for H, alkyl, -CX-R , -SO2-R ; X, Y stand for O, S; R stands for H, phenyl, alkyl; R stands for H, alkyl, if necessary substituted phenyl; R stands for alkyl, halogen alkyl, alkenyl, halogen alkenyl, if necessary substituted cycloalkyl or cycloalkenyl, NH2, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted phenyl or phenylamino; R stands for alkyl, if necessary substituted phenyl; R stands for NH2, alkylamino, dialkylamino, if necessary substituted pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl; R + R stand for =CR R or -CO-W-CO-; R stands for H, NH2, alkylamino, cycloalkylamino; R stands for NH2, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted thienylamino, pyrrolidinyl, piperidinyl, morpholinyl, if necessary substituted phenyl or pyridyl; W stands for an ethylene or ethenylene bridge, if necessary substituted, or for an aromatic or heteroaromatic 5/6 membered cycloalkylene or cycloalkenylene bridge, if necessary substituted. Also disclosed are a basic salt of compound (I), in which R stands for hydroxycarbonyl, hydroxythiocarbonyl, or an acid salt of compound (I) which contains a basic hydrogen atom, and at least one herbicidal active substance from (A) the group of 4-aryloxy- and 4-heteroaryloxy-phenoxyacetic acid derivates or from (B) the group of cyclohexan-1,3-dione derivates.

公开(公告)号：DE4035479A1

公开(公告)日：1992-05-14

申请号：DE4035479

申请日：1990-11-08

Applicant: BASF AG

Inventor： HAGEN HELMUT DR ,  RAATZ PETER DR ,  WALTER HELMUT DR ,  LANDES ANDREAS DR

IPC: A01N43/54 ,  A01N25/32 ,  C07D471/04

Abstract: Pyrido[2,3-d]pyrimidin-2,4(1H,3H)-diones are disclosed, having formulas (Ia) and (Ib), in which R and R stand for H, substituted or unsubstituted alkyl, cycloalkyl; R stands for H, substituted or unsubstituted alkyl; R stands for H, alkyl, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, cyano or aminocarbonyl; or R and R represent together alkylene, alkenylene or 1,2-phenylene; R stands for H, alkyl, cyano, C(O)R ; R stands for alkyl, possibly substituted aralkenyl, aryl or hetaryl, CH2R , alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, OH, SH, alkoxy, alkylthio, NH2, alkylamino, NHCXR , NHSO2R ; R and R represent together substituted alkylene, alkenylene or 1,2-phenylene, which may also contain carbonyl or thiocarbonyl groups; R stands for H, alkyl, OH, SH, alkoxy, alkylthio, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, NH2 alkylamino, dialkylamino, possibly substituted aryl or arylamino; R stands for halogen, OH, SH, alkoxy, alkylthio, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl or the formula (a); R stands for alkyl, halogen alkyl, NR R or OR ; R stands for alkyl, substituted or unsubstituted aryl; R stands for halogen, OH, SH, alkoxy, alkylthio, alkyl, nitro or amino; X stands for oxygen or sulphur. Also disclosed are the salts of compounds (Ia) and (Ib) that can be used in agriculture and that contain nitrogen or hydroxy substituants, as well as herbicides that contain 2-[4-(hetero)-aryloxy]-phenoxyacetic acid or propionic acid derivates and/or cyclohexenone derivates as active herbicidal substances and substituted pyrido[2,3-d[pyrimidin-2,4(1H, 3H)-diones, as well as the salts of (Ia) or (Ib) as antidotes when acid end groups or basic nitrogen atoms are present.