公开(公告)号：DE19738084A1

公开(公告)日：1999-03-04

申请号：DE19738084

申请日：1997-09-01

Applicant: BASF AG

Inventor： MENKE OLAF DR ,  GOETZ ROLAND DR ,  RACK MICHAEL DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  REINHARD ROBERT DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISLITZ ULF DR

IPC: A01N43/80 ,  C07D405/06 ,  C07D413/06 ,  C07D417/06 ,  C07F9/6584 ,  C07D239/54 ,  A01N43/54 ,  A01N43/84 ,  A01N57/02 ,  C07D403/06 ,  C07F9/6564 ,  C07F9/6571

Abstract: 3-Arylmethyluracil derivatives (I.1)-(I.4) are new, where A = H, 1-4C alkyl, NH2, 1-4C alkylamino or di-(1-4C alkyl)amino; X = O or S; n = not defined; R1 = 1-4C haloalkyl; R2 = H, halo or 1-3C alkyl; R3-R5 = H, CN, thiocyanato, halo, 1-4C haloalkyl, 1-4C haloalkoxy, 1-4C haloalkylthio, 1-4C alkyl or 1-4C alkoxy; R6, R7 = 1-4C alkyl, NH2, 1-4C alkylamino or di(1-4C alkyl)amino, or R6 and R7 together form =O; R8 may be in position alpha or beta and R3 is in the other position; R8 = (1) H, halo, amino, 1-4C alkylsulphonylamino or di(1-4C alkyl)amino; (2) 1-6C alkoxy, 1-6C alkylthio, 3-6C cycloalkoxy, 3-6C cycloalkylthio, 2-6C alkenyloxy, 5-7C cycloalkenyloxy, 2-6C alkenylthio, 2-6C alkynyloxy, 2-6C alkynylthio, (1-6C alkyl)carbonyloxy, (1-6C alkyl)carbonylthio, (1-6C alkoxy)carbonyloxy, (2-6C alkenyl)carbonyloxy, (2-6C alkenyl)carbonylthio, (2-6C alkynyl)carbonyloxy, (2-6C alkynyl)carbonylthio, 1-6C alkylsulphonyloxy or 1-6C alkylsulphonyl, where the last 18 groups may contain 1-4 substituents; (3) CT-R11, C(R11)(Y1R12)(Y2R13), C(R11)=C(R14)CN, C(R11)=C(R14)CO-R15, CH(R11)-CH(R14)CO-R15, C(R11)=C(R14)-CH2-CO-R15, C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, C(R11)=C(R14)-CH2-CH(R18)CO-R15, CO-OR19, CO-SR19, CO-N(R19)-OR20, C?=C-CO-NH-OR20, C?=C-CO-N(R19)-OR20, , C?=C-CS-NH-OR20, C?=C-CS-N(R19)-OR20, C(R11)=C(R14)-CO-NH-OR20, C(R11)=C(R14)-CO-N(R19)-OR20, C(R11)=C(R14)-CS-NH-OR20, C(R11)=C(R14)-CS-N(R19)-OR20, C(R11)=C(R14)-C(R21)=N-OR20, C(R21)=N-OR20, C?=C-C(R21)=N-OR20, C(Y1R12)(Y2R13)-OR19, C(Y1R12)(Y2R13)-SR19, C(Y1R12)(Y2R13)-N(R23)(R24), N(R23)(R24), CO-N(R23)(R24), or groups of formula (i), (ii), -C?=C-(i), -C?=C-(ii), -C(R11)=C(R14)-(i) or -C(R11)=C(R14 )-(ii); Y1, Y2 = S or O; theta = 1-3C alkylene optionally substituted by 1-6C alkyl; R11 = H, CN, 1-6C alkyl, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 3-6C cycloalkyl, 1-6C alkoxy-(1-6C alkyl) or (1-6C alkoxy)carbonyl; R12, R13 = 1-6C alkyl, 1-6C haloalkyl, 3-6C alkenyl, 3-6C alkynyl or 1-6C alkoxy-(1-6C alkyl) or R12 and R13 together form a 2-4 membered carbon chain which is optionally substituted and can contain non-adjacent O, S or N atoms instead of C atoms or be condensed or form a spiro attachment with a 3-7 membered ring; R14 = H, CN, halo, 1-6C alkyl, 1-6C haloalkyl, 1-6C alkoxy, (1-6C alkyl)carbonyl or (1-6C alkoxy)carbonyl; R15 = H, OR22, SR22, 1-6C alkyl (optionally substituted by one or two 1-6C alkoxy groups), 2-6C alkenyl, 2-6C alkynyl, 1-6C haloalkyl, 3-6C cycloalkyl, 1-6C alkylthio-(1-6C alkyl), 1-6C alkyliminooxy, N(R23)(R24) or optionally substituted phenyl; R22 has the same meanings as R19; R16 = H, CN, halo, 1-6C alkyl, 3-6C alkenyl, 3-6C alkynyl, 1-6C alkoxy-(1-6C alkyl), (1-6C alkyl)carbonyl, (1-6C alkoxy)carbonyl, N(R25)(R26) or optionally substituted phenyl; R25, R26 have the same meanings as R23 and R24; R17 = H, halo, CN, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl, (1-6C alkyl)carbonyl or (1-6C alkoxy)carbonyl; R18 = H, CN, 1-6C alkyl or (1-6C alkoxy)carbonyl; R19 = H, 1-6C alkyl, 1-6C haloalkyl, 2-6C alkenyl or 2-6C alkynyl (where the latter four groups are optionally substituted), (1-6C alkyl)carbonyl, (1-6C haloalkyl)carbonyl, (1-6C alkoxy)carbonyl, 1-6C alkylaminocarbonyl, di-(1-6C alkyl)aminocarbonyl, 1-6C alkoxyimino-(1-6C alkyl), 3-6C cycloalkyl, phenyl or phenyl-(1-6C alkyl), where the phenyl ring is optionally substituted; R20 = H, 1-6C alkyl, 1-6C haloalkyl, 3-6C cycloalkyl, 3-6C alkenyl, 3-6C alkynyl, hydroxy-(1-6C alkyl), 1-6C alkoxy-(1-6C alkyl), 1-6C alkylthio-(1-6C alkyl), cyano-(1-6C alkyl), (1-6C alkyl)carbonyl-(1-6C alkyl), (1-6C alkoxy)carbonyl-(1-6C alkyl), (1-6C alkoxy)carbonyl-(2-6C alkenyl), (1-6C alkyl)carbonyloxy-(1-6C alkyl) or phenyl-(1-6C alkyl), where the phenyl ring may contain 1-3 substituents; R

公开(公告)号：DE19633751A1

公开(公告)日：1998-02-26

申请号：DE19633751

申请日：1996-08-22

Applicant: BASF AG

Inventor： SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  RACK MICHAEL DR ,  ZAGAR CYRILL DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR

IPC: A01N43/76 ,  A01N43/84 ,  C07D213/61 ,  C07D213/70 ,  C07D413/04 ,  C07D417/04 ,  A01N43/48 ,  A01N43/72 ,  C07D213/89 ,  C07D401/04

Abstract: Substituted 2-arylpyridine of formula (I) and salts thereof. In said formula (I), R = SH, SO2OH, SO2C1, SO2NH2, C1-C6-Alkylthio, C1-C6-Alkyl sulfinyl, C1-C6-alkylsulfonyl, C1-C6-alkylamino-sulfonyl, Di(C1-C6-alkyl)aminosulfonyl; R , R = H, halogen; R = H, C1-C6-alkyl, C1-C6-halogenalkyl, cyano-C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkoxy-C1-C6-alkyl, C1-C4-halogen-alkoxy-C1-C4-alkyl, C1-C6-alkylthio-C1-C6-alkyl, C1-C6 alkyl sulfinyl-C1-C6-alkyl, C1-C6-alkylsulfonyl-C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C6-alkoxycarbonyl-C1-C6-alkyl, C1-C3-alkoxy-C1-C3-alkoxycarbonyl-C1-C6-alkyl, C2-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C6-alkyl, C3-C7-cycloalkyloxy-C1-C6-alkyl, C3-C7-cycloalkylthio-C1-C6-alkyl, C3-C8-alkenyl, C3-C8-alkinyl, C3-C8-halogenalkenyl, C3-C8-halogenalkinyl, C1-C6-alkoxy-C3-C8-alkenyl, C1-C6-alkoxy-C3-C8-alkinyl, C1-C6-alkylcarbonyl, C1-C6-alkylsulfonyl, C3-C6-alkenyloxy, C3-C6-alkinyloxy or eventually substituted benzyl; X = -O-, -S-, -NH-, -N(CH3)-, -CH2-; Y = chemical bond, -CO-, C(R ,R ); R ,R = H, NO2, CN, OCH3, SCH3, halogen, C1-C4-alkyl, C1-C4-halogenalkyl, C1-C4-alkoxycarbonyl, C2-C6-alkenyl, C3-C6-alkinyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl. Application as herbicide; for plant desiccation/defoliation.

公开(公告)号：DE19613548A1

公开(公告)日：1997-10-09

申请号：DE19613548

申请日：1996-04-04

Applicant: BASF AG

Inventor： HEISTRACHER ELISABETH DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

IPC: A01N43/56 ,  C07D231/56 ,  A01N37/00

Abstract: 3-Chloro-tetrahydroindazolyl-phenylpropionic acid derivatives of formula (I) and their salts are new. R1, R5 = H or 1-6C alkyl; R2 = H or halo; R3 = CN, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy; R4 = halo; R6 = OR7, SR7, NR8R9 or N(R8)OR10; R7 = H, 1-6C alkyl (optionally substituted by halo, CN, 1-6C alkoxy, 1-6C alkylthio, 1-6C alkoxy-carbonyl, 1-6C alkylamino-carbonyl, di-1-6C alkylamino-carbonyl or 1-6C alkoxyimino), 2-6C alkyl (disubstituted by 1-6C alkoxy or 1-6C alkylthio), 3-6C alkenyl, 3-6C haloalkenyl, 3-6C alkynyl, 3-6C cycloalkyl, Ph' or CH2Ph'; Ph' = phenyl (optionally mono-, di- or tri- substituted by CN, NO2, halo, 1-6C alkoxy-carbonyl, 1-6C alkyl, 1-6C alkoxy, 1-6C alkylthio, 1-6C haloalkyl, 1-6C haloalkoxy or 1-6C haloalkylthio; R8-R10 = as R7, 1-6C alkyl-carbonyl or 1-6C haloalkyl-carbonyl; or R8+R9 = 4-6 membered hydrocarbon chain with 1 non-terminal CH2 optionally replaced by O or 1-4C alkylimino.

公开(公告)号：DE19605766A1

公开(公告)日：1997-08-21

申请号：DE19605766

申请日：1996-02-16

Applicant: BASF AG

Inventor： ZAGAR CYRILL DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

IPC: A01N57/08 ,  A01N57/24 ,  C07F9/58 ,  C07F9/6558 ,  A01N43/40

Abstract: The invention concerns substituted 2-phenylpyridines of formula (I) and their salts, in which X = a bond, 1,2-ethinediyl, an optionally substituted methylene-, 1,2-ethanediyl- or 1,3-propylene bridge, optionally substituted methyleneoxymethylene, methylenethiamethylene, ethene-1,2-diyl, optionally substituted oxymethylene, thiamethylene, oxyethylene or thiaethylene bonded to the phenyl ring via the heteroatom; Y = -O-, -S-; -Z = -O-, -S-, -N(R )-; Z = -O2-, -S-, -N(R )-; R , R , R , R = H, C1-C6-alkyl, C1-C6-alkyl halide, hydroxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4alkoxy-C1-C4alkyl, C1-C4alkoxy halide-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkoxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di-(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthiohalide-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4alkinylthio-C1-C4-alkyl, C1-C4-alkylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphinylhalide-C1-C4-alkyl, C3-C4-alkenylsulphinyl-C1-C4-alkyl, C3-C4-alkinylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphonyl-C1-C4-alkyl, C1-C4-alkylsulphonyl halide-C1-C4-alkyl, C3-C4-alkenylsulphonyl-C1-C4-alkyl, C3-C4-alkinylsulphonyl-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-alkenyl halide, cyano-C3-C6-alkenyl, C3-C6-alkinyl, C3-C6-alkinyl halide, cyano-C3-C6-alkinyl, hydroxycarbonyl-C1-C4-alkyl, (C1-C4-alkoxy)-carbonyl-C1-C4-alkyl, (C1-C4-alkylthio)carbonyl-C1-C4-alkyl, amino-carbonyl-C1-C4-alkyl, (C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di-(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-members heterocyclyl or heterocyclyl-C1-C4-alkyl, wherein all the heterocycles can contain a (thio)carbonyl ring member, or R + R and/or R + R and/or R + R together in each case are an optionally substituted 1,2-ethanediyl-, 1,3-propylene-, tetramethylene-, pentamethylene- or ethyleneoxyethylene chain; or R + R together are optionally substituted 1,2-phenylene; R = CN, halogen, C1-C4-alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or C1-C4 halkoxy halide; R , R are H, halogen; R is halogen, C1-C4 alkyl halide; and n = 0,1. The invention further concerns the use of these substances as herbicides and for desiccating/defoliating plants.

公开(公告)号：DE19542520A1

公开(公告)日：1997-05-22

申请号：DE19542520

申请日：1995-11-15

Applicant: BASF AG

Inventor： ZAGAR CYRILL DR ,  HARREUS ALBRECHT DR ,  BUSSCHE-HUENNEFELD CHRISTOPH D ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  MENKE OLAF DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

IPC: A01N43/56 ,  C07D231/18 ,  C07D231/20

Abstract: The invention relates to substituted 1-methyl-3-phenylpyrazoles (I) and the agriculturally useful acid addition salts thereof, in which R is C1-C4 alkylhalide or C1-C4 alkylthiohalide; R is halogen; R is F or Cl; R is CN, C1-C4 fluoroalkyl, C2-C4 fluoroalkenyl or -C(R ) (X-R ) (Y-R ); R is H or C1-C4 alkyl; X and Y are -O- or -S-; R , R is C1-C4 alkyl, C1-C4 alkylhalide, C3-4 alkenyl, C3-C4 alkenylhalide or C3-C4 alkinyl. It also relates to the use thereof as herbicides and for the desiccation or defoliation of plants.

公开(公告)号：DE19528943A1

公开(公告)日：1997-02-13

申请号：DE19528943

申请日：1995-08-07

Applicant: BASF AG

Inventor： SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  MENKE OLAF DR ,  ZAGAR CYRILL DR ,  RACK MICHAEL DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISLITZ ULF DR

IPC: A01N43/40 ,  C07D213/61 ,  C07D405/12 ,  C07D409/12 ,  A01N43/34

Abstract: Substituted 2-phenylpyridines have the formula (I), in which n equals 0, 1; R stands for halogen, C1-C6 alkyl halide; R , R stand for H, halogen; R stand for CN, halogen; X, Y stand for -O-, -S-; R , R stand for H, C1-C4 alkyl or form together an 1,2-ethylene, 1,3-propylene, 1,4-tetramethylene or 1,5-pentamethylene chain; R stands for C1-C6 alkyl halide, C3-C6 alkenyl halide, C2-C6-alkenyloxy-C1-C4-alkyl, C2-C6-alkenyloxy-C1-C4-alkoxy-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-alkenyloxy-C1-C4-alkoxy-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-alkadienyl, C3-C6-alkinyl, C3-C6-cycloalkyl, C5-C6-cycloalkenyl, 3-oxetanyl, 3-thietanyl, phenyl, phenyl-C1-C4-alkyl or 5/6-membered heteroaryl with 1 to 3 heteroatoms selected from the group that consists of 2 oxygen atoms, two sulphur atoms and 3 nitrogen atoms, whereas each phenyl ring and heteroaromatic compound may be unsubstituted or bear 1 to 3 substituents halogen, NO2, CN, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-alkoxycarbonyl; or R and R form together an 1,2-ethylene or 1,3-propylene chain that may bear one or two C1-C4 alkyl substituents. These compounds are useful as herbicides, as plant siccative/defoliating agents.