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    BENZYLIDENE PYRAZOLONES, PRODUCTION AND USE THEREOF
    22.
    发明申请
    BENZYLIDENE PYRAZOLONES, PRODUCTION AND USE THEREOF 审中-公开
    BENZYLIDENPYRAZOLONE，生产和使用

    公开(公告)号：WO9926930A2

    公开(公告)日：1999-06-03

    申请号：PCT/EP9807099

    申请日：1998-11-06

    Applicant: BASF AG ,  RHEINHEIMER JOACHIM ,  WITSCHEL MATTHIAS ,  ENGEL STEFAN ,  BAUMANN ERNST ,  DEYN WOLFGANG VON ,  HILL REGINA LUISE ,  MAYER GUIDO ,  MISSLITZ ULF ,  WAGNER OLIVER ,  OTTEN MARTINA ,  WESTPHALEN KARL OTTO ,  WALTER HELMUT

    Inventor： RHEINHEIMER JOACHIM ,  WITSCHEL MATTHIAS ,  ENGEL STEFAN ,  BAUMANN ERNST ,  VON DEYN WOLFGANG ,  HILL REGINA LUISE ,  MAYER GUIDO ,  MISSLITZ ULF ,  WAGNER OLIVER ,  OTTEN MARTINA ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT

    IPC: A01N43/56 ,  A01N43/78 ,  A01N43/80 ,  C07D231/16 ,  C07D231/20 ,  C07D401/10 ,  C07D403/10 ,  C07D405/10 ,  C07D409/10 ,  C07D413/06 ,  C07D413/10 ,  C07D417/10 ,  C07D231/18

    CPC classification number: C07D413/06 ,  A01N43/56 ,  A01N43/78 ,  A01N43/80 ,  C07D231/16 ,  C07D231/20

    Abstract: The invention relates to benzylidene pyrazolones of formula (I), wherein the substituents and index n have the following meanings: R = optionally substituted C1-C6 alkyl; R = optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, halogen, nitro, cyano; R = hydrogen, halogen, nitro, cyano, a group NR R , OCOR , NR COR ,CO2R , -COSR , -CONR R , C1-C4-alkoxyiminoalkyl, C1-C6 alkoxycarbonyl, optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, optionally substituted C1-C6 alkylthio, optionally substituted C2-C6 alkenyl, optionally substituted phenyl, optionally substituted phenoxy, an optionally substituted 5- or 6-membered saturated or unsaturated heterocycle which can contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulphur atoms as ring members; R = C1-C6 alkyl, C1-C4 halogen alkyl; or R and R = an optionally substituted saturated or unsaturated 2- or 3-membered bridge which can contain one sulphur atom which can be oxidized into sulfoxide or sulfone, R = hydrogen or optionally substituted C1-C6 alkyl; R = hydrogen, C1-C6 alkyl or C1-C4 halogenalkyl; n = 0, 1 or 2; X = hydrogen, chlorine or bromine. The compounds to which claim is laid are available in both a trans and a cis form or can be a mixture of these isomers.

    Abstract translation: 式（I）的Benzylidenpyrazolone其中取代基和指数n具有以下含义：R t <1>是未取代的或取代的。 C1-C6烷基; [R <2>是未取代的或取代的。 C1-C6烷基，未取代或取代的。 C1-C6烷氧基，卤素，硝基，氰基; [R <3>是氢，卤素，硝基，氰基，基团NR <5> - [R <6>，OCOR <5>，NR <5> COR <6>，CO 2 <5>，-COSR <5>，-CONR <5> - [R <6>，C1-C4-alkoxyiminoalkyl，C1-C6烷基羰基，未取代的或取代的。 C1-C6烷基，未取代或取代的。 C1-C6烷氧基，未取代的或取代的。 C1-C6烷硫基，未取代或取代的。 C2-C6链烯基，未取代的或取代的。 C2-C6炔基，未取代的或取代的。 苯基，未取代的或取代的。 苯氧基，未取代的或取代的。 5-或6-元饱和或可含有至多4个氮原子和/或至多2个氧或硫原子作为环成员的不饱和的杂环; [R <4> C1-C6-烷基，C1-C4卤代烷基; 或R <3>，R <4>为可以含有可被氧化为亚砜或砜硫原子的任选取代的饱和或不饱和2-或3-元桥; [R <5>为氢或未取代或取代的。 C1-C6烷基; [R <6>是未取代的或取代的。 C1-C6烷基; [R <7>是氢，C1-C6烷基或C1-C4卤代烷基; n为0.1或2; X是氢，氯或溴; 其中要求保护的化合物在跨及在所述顺式 - 形式两者呈现，或者可以是这些异构体的混合物。

    SUBSTITUTED 3-BENZYLPYRAZOLES AND THEIR USE AS HERBICIDES AND FOR LOWERING THE SUGAR CONTENT IN BLOOD
    23.
    发明申请
    SUBSTITUTED 3-BENZYLPYRAZOLES AND THEIR USE AS HERBICIDES AND FOR LOWERING THE SUGAR CONTENT IN BLOOD 审中-公开
    取代的3- benzylpyrazoles及其作为除草剂和降低血糖浓度

    公开(公告)号：WO9820000A2

    公开(公告)日：1998-05-14

    申请号：PCT/EP9706057

    申请日：1997-11-03

    Applicant: BASF AG ,  ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SHAEFER PETER ,  WESTPHALEN KARL OTTO ,  MISSLITZ ULF ,  WALTER HELMUT ,  REINHARD ROBERT ,  JONES ROBERT BRIAN

    Inventor： ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SHAEFER PETER ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT ,  REINHARD ROBERT ,  JONES ROBERT BRIAN

    IPC: A01N43/56 ,  A61K31/415 ,  A61K31/4152 ,  A61K31/4155 ,  A61K31/454 ,  A61K31/5377 ,  A61P3/10 ,  C07D231/20 ,  C07D401/10 ,  C07D401/12 ,  C07D403/10 ,  C07D403/12 ,  C07D405/12

    CPC classification number: C07D401/10 ,  C07D231/20 ,  C07D401/12 ,  C07D403/10 ,  C07D403/12 ,  C07D405/12

    Abstract: The invention relates to substituted 3-benzylpyrazoles of formula (I), their precursors of formulas (IIa), (IIb), (IIc), their byproducts of formula (III) as well as their salts, wherein R stands for H, C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkyl thio, C1-C4 halogen alkyl thio, C1-C4 alkyl sulfinyl, C1-C4 halogen alkyl sulfinyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for H, CN, NO2, halogen, C1-C4 alkyl, C1-C4 halogen alkyl; X -X stands for chemical bond, optionally substituted methylene-, ethylene-, ethene-1,2-diyl or oxymethylene or thiamethylene chain linked through the heteroatom to the phenyl ring; R -R stands for H, CN, NO2, halogen -O-Y -R , -O-CO-Y -R , -N(Y -R ) (Y -R ), -N(Y -R )-SO2-Y -R , -N(SO2-Y -R ) (SO2-Y -R ), -N(Y -R )-CO-Y -R , -N(Y -R ) (O-Y -R ), -S-Y -R , -SO-Y -R , -SO2-Y -R , -SO2-O-Y -R , -SO2-N(Y -R ) (Y -R ), -CO-Y -R , -C(=NOR )-Y -R , -C(=NOR )-O-Y -R , -C(=NOR )-CO-O-Y -R , -CO-O-Y -R , -CO-S-Y -R , -CO-N(Y -R ) (Y -R ), -CO-N(Y -R ) (O-Y -R ); R stands C1-C4 alkyl, C1-C4 halogen alkyl. The invention further relates to the use of (I) as herbicide, for the desiccation/defoliation of plants, and of (I), (IIa), (IIb), (IIc) and (III) for lowering the sugar content in blood.

    Abstract translation: 式的取代的3- benzylpyrazoles（I），它们在Formuln（IIA），（IIB），（IIC）的前体，和式（III）中，副产物和它们的盐，其中R <1> = H，C1-C4烷基 ，C1-C4卤代烷基，C1-C4烷基磺酰基，C1-C4卤代烷基磺酰基; [R <2> = C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C1-C4卤代烷硫基，C1-C4烷基亚磺酰基，C1-C4 卤代烷，C1-C4烷基磺酰基，C1-C4卤代烷基磺酰基; [R <3> = H，CN，NO 2，卤素，C1-C4烷基，C1-C4卤代烷基; X <1> - X <5> =化学键，任选取代的亚甲基，亚乙基，乙烯-1,2-二基，或通过结合到苯环或甲醛蒂亚姆乙烯链中的杂原子; [R <4> - R的<8> = H，CN，NO 2，卤素，-OY <1> -R <9> -O-CO-Y <1> -R <9> -N（Y <1 > -R <9>）（Y <2> -R <10>）， - N（Y <1> -R <9>） - SO2-Y <2> -R <10>，-N（SO 2 Y'> -R <9>）（SO 2-Y <2> -R <10>）， - N（Y <1> -R <9>） - CO-Y <2> -R <10>， -N（Y <1> -R <9>）（OY <2> -R <10>），-SY <1> -R <9>，-SO-Y <1> -R <9>， - SO2-Y <1> -R <9>，-SO 2 OY <1> -R <9>，-SO2-N（Y <1> -R <9>）（Y <2> -R <10> ）， - CO-Y <1> -R <9>，-C（= NOR <11>） - Y'> -R <9>，-C（= NOR <11>） - OY <1> - [R <9>，-C（= NOR <11>） - CO-OY <1> -R <9> -CO-OY <1> -R <9> -CO-SY <1> -R < 9>，-CO-N（Y <1> -R <9>）（Y <2> -R <10>），-CO-N（Y <1> [R <9>）（OY <2> - [R <10>）; [R <12> = C1-C4烷基，C1-C4卤代烷基; 使用：（Ⅰ）作为除草剂：用于植物干燥/落叶; （I），（IIA），（IIB），（IIC）和（III）用于降低血糖含量。

    3-(4,5-DIHYDROISOXAZOLE-5-YL)BENZOYLPYRAZOLE
    26.
    发明专利
    3-(4,5-DIHYDROISOXAZOLE-5-YL)BENZOYLPYRAZOLE 未知

    公开(公告)号：CA2394848C

    公开(公告)日：2010-04-27

    申请号：CA2394848

    申请日：2000-12-19

    Applicant: BASF AG

    Inventor： BAUMANN ERNST ,  VON DEYN WOLFGANG ,  KUDIS STEFFEN ,  LANGEMANN KLAUS ,  MAYER GUIDO ,  MISSLITZ ULF ,  NEIDLEIN ULF ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  WITSCHEL MATTHIAS

    IPC: C07D261/04 ,  C07D413/10 ,  A01N43/80 ,  C07D231/00 ,  C07D261/00 ,  C07D409/14 ,  C07D413/00 ,  C07D413/12 ,  C07D413/14

    Abstract: The invention relates to 3-(4,5-dihydroisoxazole-5-yl)benzoylpyrazole of the formula (I) and agriculturally useful salts thereof: (see formula I) wherein R1, R2 represent hydrogen, nitro, halogen, cyano, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl or halogenalkylsulfonyl; R3 represents hydrogen, halogen or alkyl; R4 represents hydrogen or alkyl; R5, R6 represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, wherein the latter six groups can be substituted; R7 represents halogen, cyano, hydroxy, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl, amino, alkylamino, dialkylamino, dialkoxymethyl, hydroxyiminoalkyl, alkoxyiminoalkyl or optionally substituted carbonyl; R11 represents optionally substituted pyrazole that is bound in the 4 position and that carries a hydroxy group or a derivative thereof in the 5 position. The invention also relates to methods and intermediate products for preparing the 3-(4,5-dihydroisoxazole-5-yl)benzoylpyrazole, to agents containing them and the use of said derivatives or agents containing them for combating undesired plants.

    3-(4,5-DIHYDROISOXAZOLE-5-YL)BENZOYLPYRAZOLES
    30.
    发明专利
    3-(4,5-DIHYDROISOXAZOLE-5-YL)BENZOYLPYRAZOLES 未知

    公开(公告)号：BG65374B1

    公开(公告)日：2008-04-30

    申请号：BG10678402

    申请日：2002-06-06

    Applicant: BASF AG

    Inventor： BAUMANN ERNST ,  VON DEYN WOLFGANG ,  KUDIS STEFFEN ,  LANGEMANN KLAUS ,  MAYER GUIDO ,  MISSLITZ ULF ,  NEIDLEIN ULF ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  WITSCHEL MATTHIAS

    IPC: C07D261/04 ,  C07D413/00 ,  A01N43/80 ,  C07D409/14 ,  C07D413/10 ,  C07D413/12 ,  C07D413/14

    Abstract: The invention relates to 3-(4,5-dihydroisoxalole-5-yl)benzoylpyrazole of the formula therein the variables have the following meanings: R1, R2 represent hydrogen, nitro, halogen, cyano, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogen alkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl or halogenalkylsulfonyl; hydrogen, R3 represents halogen or alkyl; R4 represents hydrogen or alkyl; R5, R6 represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, wherein the latter six groups can be substituted; R7 represents halogen, cyano, hydroxy, alkyl, halogenalkyl, alkoxy, halogenalkoxyalkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl, amino, alkylamino, dialkylamino, dialkoxymethyl, hydroxyiminoalkyl, alkoxyiminoalkyl or optionally substituted carbonyl; R11 represents optionally substituted pyrazole that is bound in the 4 position and carries a hydroxy group or a derivative thereof in the 5 position. The invention also relates to the agriculturally useful salts thereof, to methods and to intermediate products for preparing the 3-(4,5-dihydroisoxalole-5-yl)benzoylpyrazole, to agents containing them and to the use of said derivatives or the agents containing them for combatting undesired plants.

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