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公开(公告)号:AU690752B2
公开(公告)日:1998-04-30
申请号:AU3746495
申请日:1995-10-17
Applicant: BASF AG
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公开(公告)号:DK0758344T3
公开(公告)日:1998-03-02
申请号:DK95912254
申请日:1995-03-20
Applicant: BASF AG
Inventor: NILZ CLAUDIA , KROENER MICHAEL , WINTER MANFRED , STANGE ANDREAS , SCHUHMACHER RUDOLF
Abstract: PCT No. PCT/EP95/01030 Sec. 371 Date Sep. 30, 1996 Sec. 102(e) Date Sep. 30, 1996 PCT Filed Mar. 20, 1995 PCT Pub. No. WO95/26989 PCT Pub. Date Oct. 12, 1995Solutions of polymers containing vinylamine units, which solutions have a long shelf life, are prepared by hydrolyzing polymers containing N-vinylcarboxamide units with acids in an aqueous medium and removing the carboxylic acids eliminated from the polymers as esters from the aqueous polymer solution after the hydrolysis by adding at least stoichiometric amounts of at least one C1-C6-alcohol and distilling off the esters from the reaction mixture, and said aqueous solutions are used as dry and wet strength agents in papermaking.
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公开(公告)号:FI97405C
公开(公告)日:1996-12-10
申请号:FI931642
申请日:1993-04-13
Applicant: BASF AG
Inventor: KROENER MICHAEL , NILZ CLAUDIA , SENDHOFF NORBERT , STANGE ANDREAS , DE CLERCQ ARNOLD , RIEBELING ULRICH
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公开(公告)号:FI963778A
公开(公告)日:1996-11-22
申请号:FI963778
申请日:1996-09-23
Applicant: BASF AG
Inventor: HARTMANN HEINRICH , DENZINGER WALTER , NILZ CLAUDIA
IPC: C05G3/00 , C08F263/00 , C08F265/00 , C08F271/00 , C09B67/00 , C09B67/46 , C09D17/00 , C09K17/20 , C09K23/00 , C09K23/52 , C11D3/37 , D21H17/34 , C08F
Abstract: PCT No. PCT/EP95/00912 Sec. 371 Date Oct. 24, 1996 Sec. 102(e) Date Oct. 24, 1996 PCT Filed Mar. 3, 1995 PCT Pub. No. WO95/25759 PCT Pub. Date Sep. 28, 1995Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least 5% by weight of units of the formulae (I) (II) where R1 and R2 are each H or C1-C6-alkyl, monoethylenically unsaturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5% strength by weight aqueous solution at 25 DEG C. and pH 7), are prepared by polymerization of monoethylenically unsaturated monomers in the presence of polymers which in each case contain at least 5% by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as dispersants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.
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公开(公告)号:DE59104096D1
公开(公告)日:1995-02-09
申请号:DE59104096
申请日:1991-10-04
Applicant: BASF AG
Inventor: KROENER MICHAEL , NILZ CLAUDIA , SENDHOFF NORBERT , STANGE ANDREAS , DE CLERCQ ARNOLD , RIEBELING ULRICH
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公开(公告)号:CA2157175A1
公开(公告)日:1995-01-26
申请号:CA2157175
申请日:1994-06-27
Applicant: BASF AG
Inventor: DENZINGER WALTER , HARTMANN HEINRICH , KROENER MICHAEL , NILZ CLAUDIA
Abstract: The invention concerns a method for the elimination of impurities containing cyanide groups from polymers containing acyclic N-vinyl carboxylic acid amide units and/or vinylamine units by treating the polymer with at least one oxidising agent (a) under the action of light and/or (b) in the presence of heavy-metal ions.
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公开(公告)号:CA2143747A1
公开(公告)日:1994-04-14
申请号:CA2143747
申请日:1993-09-23
Applicant: BASF AG
Inventor: NILZ CLAUDIA , SENDHOFF NORBERT , BREITSCHAFT WALTER , ZILLIG MANFRED , LORENCAK PRIMOZ
Abstract: a process for dyeing paper in connection with paper manufacture by adding watersoluble anionic dyes and cationic polymers which contain vinylamine units to the paper pulp as fixing agents and removing water from the paper pulp with the formation of dyed paper is described.
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28.
公开(公告)号:NZ240196A
公开(公告)日:1993-10-26
申请号:NZ24019691
申请日:1991-10-11
Applicant: BASF AG
Inventor: KROENER MICHAEL , NILZ CLAUDIA , SENDHOFF NORBERT , STANGE ANDREAS , DE CLERCQ ARNOLD , REIBELING ULRICH
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公开(公告)号:CA2217295C
公开(公告)日:2006-10-03
申请号:CA2217295
申请日:1996-04-20
Applicant: BASF AG
Inventor: MONCH DIETMAR , SCHUHMACHER RUDOLF , STANGE ANDREAS , DENZINGER WALTER , RUBENACKER MARTIN , LORENCAK PRIMOZ , NILZ CLAUDIA
IPC: C08B31/12 , C08F283/06 , C08F8/12 , C08F283/00 , C09B67/46 , C09D17/00 , D21H17/53 , D21H19/20 , D21H21/10 , D21H21/16 , D21H21/18
Abstract: Graft polymers are obtainable by free radical polymerization of (A) monomers or monomer mixtures comprising (a) from 10 to 100% by weight of N-vinylcarboxamides of the formula (see formula I), where R1 and R2 are each H or C1-C6-alkyl, (b) from 0 to 90% by weight of other monoethylenically unsaturated monomers copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least two ethylenically unsaturated, nonconjugated double bonds in the molecule in the presence of (B) polymers which contain at least 3 units of a C2-C4-alkylene oxide, and/or polytetrahydrofurans, in a weight ratio (A) : (B) of (95 to 10) : (5 to 90) , and, if required, subsequent elimination of some or all of the groups (see formula II) from the polymerized monomers (a) of the graft polymer with formation of units of the formula (see formula III) The graft polymers can be used as dry and wet strength agents, as fixing agents fear interfering substances and fillers, as retention aids and drainage aids in the production of paper and as promoters in the diketene sizing of paper, board and cardboard, as dispersants for pigments, as starch cationizing agents and as assistants in the production of tissue papers.
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公开(公告)号:CA2203931C
公开(公告)日:2006-02-21
申请号:CA2203931
申请日:1995-10-17
Applicant: BASF AG
Inventor: REUTHER WOLFGANG , HARTMANN HEINRICH , MEIXNER HUBERT , NILZ CLAUDIA , DENZINGER WALTER , NIESSNER MANFRED , LINHART FRIEDRICH , SCHUHMACHER RUDOLF , STANGE ANDREAS
Abstract: Starch is cationically modified by reacting starch with polymers which contain amino and/or ammonium groups in an aqueous medium at from 115 to 180.degree.C under superatmospheric pressure in the absence of oxidizing agents, polymerization initiators and alkali, by a process in which the reaction is carried out in a manner such that a reduction in molecular weight occurs in not more than 10% by weight of the starch, and the reaction products thus obtainable are used as dry strength agents for paper.
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