公开(公告)号：DE10353745A1

公开(公告)日：2005-06-23

申请号：DE10353745

申请日：2003-11-17

Applicant: BASF AG

Inventor： SCHAEDLER VOLKER ,  EHRENSTEIN MORITZ ,  DU FRESNE VON HOHENESCHE CEDRI

IPC: C08J9/28 ,  C08J9/20

公开(公告)号：CA2461948A1

公开(公告)日：2003-04-10

申请号：CA2461948

申请日：2002-09-30

Applicant: BASF AG

Inventor： KROENER HUBERTUS ,  SCHAEDLER VOLKER ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  MANDERS LAMBERTUS

IPC: C08F2/38 ,  C08F212/08 ,  C08F220/04 ,  C08F220/44 ,  C08F236/06 ,  C08F236/10 ,  C09D5/02 ,  C09D109/06 ,  C09D109/08 ,  C09D125/10 ,  D21H19/58 ,  C08F291/00 ,  D21H17/35

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by means of radical aqueous emulsion polymerisation of a monomer mixture M containing styrene, butadiene, and optionally up to 30 wt. %, in relation to 100 wt. % of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene. The reaction is carried out in a polymerisation vessel according to a monomer supply method, in the presence of a regulator system comprising, in relation to 100 wt. % of monomers, between 0.02 and 0.5 wt. % of at least one hydrocarbon KW having between 6 and 20 C atoms and being selected from compounds forming a pentadienyl radical or a 1 - phenylallyl radical by means of abstraction of a hydrocarbon atom, an .alpha .- methylstyrene dimer, and between 0.3 and 2 wt. % of an organic compound S wi th at least one SH group. The inventive method is characterised in that at leas t 30 %, preferably at least 50 %, especially at least 80 %, and ideally the entire amount (or more than 95 %) of the hydrocarbon KW is present in the polymerisation vessel.

公开(公告)号：DE50001336D1

公开(公告)日：2003-04-03

申请号：DE50001336

申请日：2000-05-26

Applicant: BASF AG

Inventor： DERSCH ROLF ,  MAAS HEIKO ,  SCHAEDLER VOLKER

IPC: C08F2/22 ,  C08C19/02 ,  C08F8/00 ,  C08F8/04 ,  C08F236/04 ,  C09D1/04 ,  C09D5/00 ,  C09D109/00

Abstract: The present invention relates to a process for hydrogenating ethylenically unsaturated double bonds in polymers P by reacting an aqueous dispersion of at least one polymer P with hydrogen in the presence of at least one hydrogenation catalyst comprising at least one transition metal selected from rhodium and/or ruthenium and at least one nonionic phosphorus compound capable of forming a coordinative compound with the transition metal, which comprises incorporating the hydrogenation catalyst into the aqueous dispersion of the polymer P without adding a solvent. The present invention also relates to the aqueous dispersions of the hydrogenated polymers P obtainable by this process and to coating compositions comprising such dispersions.

公开(公告)号：AT233281T

公开(公告)日：2003-03-15

申请号：AT00936816

申请日：2000-05-26

Applicant: BASF AG

Inventor： DERSCH ROLF ,  MAAS HEIKO ,  SCHAEDLER VOLKER

IPC: C08F2/22 ,  C08C19/02 ,  C08F8/00 ,  C08F8/04 ,  C08F236/04 ,  C09D1/04 ,  C09D5/00 ,  C09D109/00

Abstract: The present invention relates to a process for hydrogenating ethylenically unsaturated double bonds in polymers P by reacting an aqueous dispersion of at least one polymer P with hydrogen in the presence of at least one hydrogenation catalyst comprising at least one transition metal selected from rhodium and/or ruthenium and at least one nonionic phosphorus compound capable of forming a coordinative compound with the transition metal, which comprises incorporating the hydrogenation catalyst into the aqueous dispersion of the polymer P without adding a solvent. The present invention also relates to the aqueous dispersions of the hydrogenated polymers P obtainable by this process and to coating compositions comprising such dispersions.

公开(公告)号：DE10135380A1

公开(公告)日：2003-02-06

申请号：DE10135380

申请日：2001-07-25

Applicant: BASF AG

Inventor： DISTLER DIETER ,  SCHAEDLER VOLKER ,  LEMAN TITUS ,  STEINMACHER THOMAS

IPC: D21H19/36 ,  D21H19/58 ,  D21H19/60 ,  D21H25/14 ,  D21H19/56

Abstract: Paper-coating mass (A) comprising at least one inorganic pigment (I) and as binder, an aqueous polymer dispersion (B). (B) is prepared by emulsion polymerization of ethylenically unsaturated monomers and (A) forms a gel at above 35 deg C, i.e. between 35 and 60 deg C its viscosity is at least double its value at 30 deg C. Independent claims are also included for the following: (1) Preparation of coated paper by applying (A) to crude paper; and (2) Coated paper prepared using (A) or by method (1).

公开(公告)号：DE10103065A1

公开(公告)日：2002-07-25

申请号：DE10103065

申请日：2001-01-24

Applicant: BASF AG

Inventor： SCHAEDLER VOLKER ,  SEYFFER HERMANN ,  MAAS HEIKO ,  KELLER ANDREAS

IPC: C09D115/00 ,  D21H19/18 ,  D21H19/20 ,  D21H19/22 ,  D21H27/10 ,  C09D5/02 ,  C09D125/10 ,  C09D191/06 ,  D21H19/58

Abstract: The use of aqueous polymer dispersions containing hydrogenated styrene-butadiene copolymer(s) (CP) for the production of barrier coatings on paper, pasteboard or cardboard. Independent claims are also included for (1) a method for coating paper, pasteboard or cardboard by applying aqueous dispersions of CP, optionally with a wax dispersed in the aqueous phase and optionally with conventional additives and fillers, and then drying at elevated temperature; (2) packaging material made of paper, pasteboard or cardboard with a barrier coating based on CP; and (3) aqueous preparations of CP as described in (a) above.

公开(公告)号：DE10015262A1

公开(公告)日：2001-10-04

申请号：DE10015262

申请日：2000-03-28

Applicant: BASF AG

Inventor： SCHAEDLER VOLKER ,  CHRISTIE DAVID ,  ETTL ROLAND

IPC: D21H19/56 ,  D21H19/58 ,  C08F212/00 ,  C08F214/00 ,  C08F216/12 ,  C08F218/04 ,  C08F220/18 ,  C08F220/42

Abstract: A paper coating composition (I) contains a copolymer binding agent prepared by radical polymerization of ethylenically unsaturated compounds such that the polymer has at least one copolymerizable ethylenically unsaturated group, a number average mol. wt. of 500-50,000 g/mol and at least one carboxylic acid group. Independent claims are included for: (i) paper coated with composition (I); and (ii) printed coated paper.

公开(公告)号：CA2461947C

公开(公告)日：2011-05-24

申请号：CA2461947

申请日：2002-09-30

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F2/22 ,  C08F212/08 ,  C08F2/38 ,  C08F212/00 ,  C08F236/00 ,  C08F236/06 ,  C08F236/10 ,  C08F291/00

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by the radical aqueous emulsion-polymerisation of a monomer mixture M, containing: between 40 and 80 wt. % styrene as monomer M1; between 20 and 60 wt. % butadiene as monomer M2 and between 0 and 40 wt. %, (in relation to l00 wt. % monomers), of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene, according to a monomer feed process in the presence of between 0.05 and 0.5 wt. %, (in relation to l00 wt. % monomers), of at least one hydrocarbon KW comprising between 6 and 20 C atoms, selected from compounds, which form a pentadienyl or a 1-phenylallyl radical during the abstraction of a hydrogen atom, or from .alpha.-methylstyrene dimers. Said method is characterised in that at least 30 % of the hydrocarbon KW is already present in the polymerisation vessel and the residual quantity of the hydrocarbon KW is fed to the polymerisation reaction during the course of the latter.

公开(公告)号：DE102005059303A1

公开(公告)日：2007-06-21

申请号：DE102005059303

申请日：2005-12-09

Applicant: BASF AG

Inventor： SCHAEDLER VOLKER ,  RAMAN VIJAY IMMANUEL ,  DU FRESNE CEDRIC VON HOHENESCH

IPC: C08J9/14 ,  C08J9/18 ,  C08J9/22 ,  E04B1/74

Abstract: A nanoporous polymer foam having an average pore diameter in the range of from 10 nm to 1000 nm, obtainable by means of a process comprising the following stages: a) providing a solution of a polycondensation reactive resin in an organic solvent, b) mixing the solution with a curing catalyst for the polycondensation reactive resin and curing the reactive components to form a gel, and c) removing the organic solvent, and the use thereof for thermal insulation purposes.

公开(公告)号：DE50207217D1

公开(公告)日：2006-07-27

申请号：DE50207217

申请日：2002-09-30

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F212/08 ,  C08F2/38 ,  C08F220/04 ,  C08F220/44 ,  C08F236/06 ,  C08F236/10 ,  C08F291/00 ,  C09D5/02 ,  C09D109/06 ,  C09D109/08 ,  C09D125/10 ,  D21H17/35 ,  D21H19/58

Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprising styrene, butadiene, and if desired up to 30% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene; in a polymerization vessel by a monomer feed technique in the presence of a regulator system containing, based on 100% by weight of monomers, from 0.02 to 0.5% by weight of at least one hydrocarbon HC having from 6 to 20 carbon atoms, selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or 1-phenylallyl radical, and alpha-methylstyrene dimer, and from 0.3 to 2% by weight of an organic compound S containing at least one SH group wherein at least 30%, preferably at least 50%, in particular at least 80%, and with particular preference the entirety (or >95%) of hydrocarbon HC is included in the initial charge to the polymerization vessel.