公开(公告)号：JP2003064299A

公开(公告)日：2003-03-05

申请号：JP2002160045

申请日：2002-05-31

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： SCHLARB BERNHARD ,  DERSCH ROLF ,  CHRISTIE DAVID ,  WEINGART FRANZ

IPC: C08J3/20 ,  C08F2/22 ,  C08F210/04 ,  C08F212/06 ,  C08F216/20 ,  C08F220/18 ,  C08F222/12 ,  C08L33/02 ,  C09B67/20 ,  C09D5/02 ,  C09D123/02 ,  C09D125/00 ,  C09D129/10 ,  C09D133/08 ,  C09D133/18 ,  C09D135/00 ,  C09D157/04 ,  D21H19/58

CPC classification number: D21H19/58 ,  C08L33/02 ,  C09D133/08 ,  C08L2666/04 ,  C08L2666/54

Abstract: PROBLEM TO BE SOLVED: To provide a solvent free coloring composition having extremely good abrasion resistance under wet condition and scrub washing resistance in wet condition even at high pigment volume concentration (PVC) of more than 75%. SOLUTION: The coloring composition containing a binder (I), a pigment (II), a pigment dispersant (III), optionally an inorganic filler (IV) and an auxiliary (V), but not a solvent is provided, wherein the main component of the binder (I) is a copolymer which is produced in an aqueous emulsion using a free radical by monomer mixtures consisting of a monomer (a) having a glass transition temperature of less than 20 deg.C when forming homopolymer, a monomer (b) having a glass transition temperature of more than 50 deg.C when forming homopolymer, an acidic monomer (c), and another monomer (d).

Abstract translation: 要解决的问题：即使在高于75％的高颜料体积浓度（PVC）的情况下，在湿润条件下提供具有极好耐磨性和耐擦洗洗涤性的无溶剂着色组合物。 解决方案：提供含有粘合剂（I），颜料（II），颜料分散剂（III），任选的无机填料（IV）和辅助剂（V）而不是溶剂的着色组合物，其中主要组分 粘合剂（I）的共聚物是在形成均聚物时，由具有玻璃化转变温度低于20℃的单体（a）的单体混合物使用自由基在水性乳液中制备的共聚物，单体（b ），当形成均聚物，酸性单体（c）和另一单体（d）时，玻璃化转变温度大于50℃。

公开(公告)号：JP2002179865A

公开(公告)日：2002-06-26

申请号：JP2001321022

申请日：2001-10-18

Applicant: BASF AG

Inventor： CHRISTIE DAVID ,  PAKUSCH JOACHIM DR ,  WISTUBA ECKEHARDT ,  SEIBERT HORST ,  FICKEISEN PETER

IPC: C08L25/10 ,  C08F236/10 ,  C08K5/00 ,  C09J109/02 ,  C09J109/06 ,  C09J113/00 ,  C09J125/10 ,  C09J133/20

Abstract: PROBLEM TO BE SOLVED: To obtain an adhesive composition having excellent levels of technical characteristics for application such as peel strength, shear strength, wet adhesive strength, dry adhesive strength and heat resistance. SOLUTION: This aqueous composition comprises 1-60 mass % of a polymer (A) composed of (a) 10-50 mass % of a

公开(公告)号：WO0144327A3

公开(公告)日：2001-12-27

申请号：PCT/EP0012848

申请日：2000-12-15

Applicant: BASF AG ,  RAETHER ROMAN BENEDIKT ,  MODERY BERND ,  BRAUN FRANK ,  BRINKMANN RENGEL SUSANNE ,  CHRISTIE DAVID ,  HAREMZA SYLKE

Inventor： RAETHER ROMAN BENEDIKT ,  MODERY BERND ,  BRAUN FRANK ,  BRINKMANN-RENGEL SUSANNE ,  CHRISTIE DAVID ,  HAREMZA SYLKE

IPC: C08F12/32

CPC classification number: C08F12/32

Abstract: The invention relates to a method for producing a conversion product (A), which comprises the following steps: (i) reacting, under radical conditions, a reaction mixture containing at least one radically convertible monomer (a) in the presence of at least one radical initiator and one compound of formula (I), wherein R1 to R4, independent of one another, represent hydrogen, a non-substituted or substituted alkyl radical, cycloalkyl radical, aralkyl radical, a non-substituted or substituted aromatic hydrocarbon radical with the provision that at least two of the radicals R1 to R4 represent a non-substituted or substituted aromatic hydrocarbon radical, or the radicals R and R or R and R , in pairs, represent a substituted or non-substituted aromatic hydrocarbon radical with 6 to 18 C atoms and a functional group which, in conjunction with the C-C double bond in general formula (I), comprises a multiple bond between a C atom and a heteroatom, whereby during the reaction, the reaction mixture consists of 10 or less wt. % water.

Abstract translation: 一种用于制备反应产物（A），其包括以下步骤（i）反应，自由基的条件下处理的反应混合物，其包含至少一种可自由基反应的单体（a）在至少一种自由基引发剂的配方的存在和化合物（I）（I ）表示：其中R1至R4各自独立地是氢，在每种情况下未被取代或被取代的烷基，环烷基，芳烷基，未取代的或取代的芳族烃基，前提条件是至少两个基团R 1至R 4的芳族的是未取代或取代的 烃基，或基团R <1>和R <2>或R <3>和R <4>碳原子数为6〜18的取代或未取代的芳香族烃和能够缀合的官能团对 在通式（I）的多CC双键 具有achbindung碳原子和一个杂原子是，其中间存在于反应混合物中10重量％或更少的水在反应过程中。

公开(公告)号：WO0174908A2

公开(公告)日：2001-10-11

申请号：PCT/EP0103787

申请日：2001-04-03

Applicant: BASF AG ,  CHRISTIE DAVID ,  HAREMZA SYLKE ,  BRINKMANN RENGEL SUSANNE ,  RAETHER ROMAN BENEDIKT

Inventor： CHRISTIE DAVID ,  HAREMZA SYLKE ,  BRINKMANN-RENGEL SUSANNE ,  RAETHER ROMAN BENEDIKT

IPC: C08F2/00 ,  C08F2/38 ,  C08F220/18 ,  C08F293/00

CPC classification number: C08F2/38 ,  C08F293/005 ,  C08F2220/1825 ,  C08F2438/02 ,  C08F212/08

Abstract: The invention relates to a method for producing polymers. According to said method, at least one first ethylenically unsaturated monomer is subjected to a radically induced polymerization in the presence of stable free radicals or sources of stable free radicals and a compound containing at least a free sulphanyl group, to obtain a polymer, whereby the molar ratio of the compound containing a free sulphanyl group to the stable free radicals ranges between 0.05 and 1.1. The rate of polymerization is significantly increased by the compound containing a free sulphanyl group.

Abstract translation: 公开了一种用于聚合物的制备方法，其特征在于，在稳定的自由基或来源的存在下，在至少一个第一烯属不饱和单体稳定自由基并且具有自由基聚合中的至少一个游离硫醇基进行，得到聚合物，其中的摩尔比的化合物 具有游离硫醇基团，以稳定的自由基化合物是在〜1.1的范围0.05。 聚合反应速率是通过具有游离硫醇基连接显著gestcigert。

公开(公告)号：CA2355252C

公开(公告)日：2008-03-04

申请号：CA2355252

申请日：1999-12-16

Applicant: BASF AG ,  BASF COATINGS AG

Inventor： CHRISTIE DAVID ,  BENDIX MAXIMILIAN ,  PAULUS WOLFGANG ,  BREMSER WOLFGANG ,  RAETHER ROMAN BENEDIKT ,  STRICKMANN FRANK

IPC: C08F2/44 ,  C08F212/32 ,  C08F2/16 ,  C08F2/38 ,  C08F220/10 ,  C08F220/12 ,  C08F220/18 ,  C08F257/00 ,  C08F293/00

Abstract: A method for producing a reaction product (A) comprising the following step (i): (iv) a reaction mixture comprising at least one radically reactable monomer (a) is reacted in radical conditions in the presence of at least one radical initiator and a compound of formula (I), wherein R1-R4 represent independently from each other hydrogen, a respectively unsubstituted or substituted alkyl radical, a cycloalkyl radical, an aralkyl radical, an unsubstituted or substituted aromatic hydrocarbon radical, under the proviso that at least two from R1-R4 represent an unsubstituted or substituted aromatic hydrocarbon radical.

公开(公告)号：AT270311T

公开(公告)日：2004-07-15

申请号：AT00931063

申请日：2000-04-18

Applicant: BASF AG

Inventor： BRINKMANN-RENGEL SUZANNE ,  NIESSNER NORBERT ,  SUTORIS HEINZ FRIEDRICH ,  MC KEE GRAHAM EDMUND ,  KNOLL KONRAD ,  CHRISTIE DAVID

IPC: C08F293/00 ,  C08F297/04 ,  C08L53/02 ,  C09D153/02

公开(公告)号：AT261996T

公开(公告)日：2004-04-15

申请号：AT00985177

申请日：2000-12-15

Applicant: BASF AG

Inventor： RAETHER ROMAN BENEDIKT ,  MODERY BERND ,  BRAUN FRANK ,  BRINKMANN-RENGEL SUSANNE ,  CHRISTIE DAVID ,  HAREMZA SYLKE

IPC: C08F12/32

公开(公告)号：DE10126717A1

公开(公告)日：2002-12-05

申请号：DE10126717

申请日：2001-05-31

Applicant: BASF AG

Inventor： SCHLARB BERNHARD ,  DERSCH ROLF ,  CHRISTIE DAVID ,  WEINGART FRANZ

IPC: C08J3/20 ,  C08F2/22 ,  C08F210/04 ,  C08F212/06 ,  C08F216/20 ,  C08F220/18 ,  C08F222/12 ,  C08L33/02 ,  C09B67/20 ,  C09D5/02 ,  C09D123/02 ,  C09D125/00 ,  C09D129/10 ,  C09D133/08 ,  C09D133/18 ,  C09D135/00 ,  C09D157/04 ,  D21H19/58 ,  C09D17/00 ,  C08K3/34 ,  D21H21/28

Abstract: Solvent-free, pigment-containing compositions contain a binder based on an aqueous copolymer dispersion obtained by radical emulsion polymerization of a mixture containing 0.05-15 wt.% of itaconic acid, anhydride or salt as acidic comonomer, a pigment, a pigment distributor of DIN 53402 acid number below 600, optionally an inorganic filler, and conventional additives. Solvent-free, pigment-containing compositions contain: (A) binder based on an aqueous copolymer dispersion obtained by radical emulsion polymerization of a mixture comprising by wt.: (i) a monomer whose homopolymer has a Tg below 20 degrees C (45-69.95%); (ii) a monomer whose homopolymer has a Tg above 50 degrees C (30-54.95%); (iii) itaconic acid, anhydride or salt (0.05-1.5%); and (iv) one or more comonomers (0-2%); (B) a pigment; (C) a pigment distributor of DIN 53402 acid number below 600; (D) optionally an inorganic filler; and (E) conventional additives.

公开(公告)号：PL349515A1

公开(公告)日：2002-07-29

申请号：PL34951599

申请日：1999-12-16

Applicant: BASF COATINGS AG ,  BASF AG

Inventor： BREMSER WOLFGANG ,  STRICKMANN FRANK ,  BENDIX MAXIMILIAN ,  PAULUS WOLFGANG ,  RAETHER ROMAN BENEDIKT ,  CHRISTIE DAVID

IPC: C08F2/44 ,  C08F2/38 ,  C08F212/32 ,  C08F220/10 ,  C08F220/18 ,  C08F257/00 ,  C08F293/00

Abstract: A process for preparing a reaction product (A), comprising the following stage (i):(i) reacting under free-radical conditions a reaction mixture comprising at least one free-radically reactable monomer (a) in the presence of at least one free-radical initiator and of a compound (I) of the formula: in which R1 to R4 each independently of one another are hydrogen, a substituted or unsubstituted alkyl radical, cycloalkyl radical or arakyl radical, or an unsubstituted or a substituted aromatic hydrocarbon radical, with the proviso that at least two of R1 to R4 are an unsubstituted or a substituted aromatic hydrocarbon radical in aqueous phase.

公开(公告)号：DE10027860A1

公开(公告)日：2001-12-13

申请号：DE10027860

申请日：2000-06-06

Applicant: BASF AG

Inventor： MC KEE GRAHAM EDMUND ,  BENDIX MAXIMILIAN ,  BARGHOORN PETER ,  CHRISTIE DAVID

IPC: C08F2/18 ,  C08F283/00 ,  C08G18/08 ,  C08G18/62 ,  C08G18/70 ,  C08G18/80 ,  C09D133/00 ,  C09D135/06 ,  C09D175/04 ,  C08F220/18 ,  C08F220/26 ,  C08F220/34 ,  C08J5/02 ,  C09D5/02

Abstract: Micro-suspension polymers are obtained by dispersing a mixture of radically-polymerizable monomers with isocyanate-reactive groups, monomers without such groups, diphenyl-ethene or -ethane and blocked polyisocyanate in water in presence of protective colloid and then polymerizing in presence of a radical initiator. A method for the production of micro-suspension polymers involves: (1) dispersion of a mixture of (A1) 0.1-60 wt.% radically-polymerizable monomer(s) with isocyanate-reactive functional group(s), (A2) 40-99.9 wt% radically-polymerizable comonomer(s) without NCO-reactive groups, (A3) 0-20 wt.% 1,1-diphenylethene or 1,1-diphenylethane and (A4) 0.1-100 wt.% blocked polyisocyanate(s) in water in presence of a protective colloid, to give a dispersion with an average particle diameter (d50) of 0.08-100 microns, followed by (2) polymerisation of the droplets to a conversion of at least 50 wt.% in presence of 0.1-20 wt.% radical initiator(s) (amounts based on the total wt. of A1 and A2, taken as 100 wt.%). Independent claims are also included for: (a) micro-suspension polymers (I) or dispersions, made by this method; (b) fibres, molded products, film or varnish obtained from (I) or their dispersions; (c) a method for varnishing or coating substrates by coating with a dispersion of (I), drying and heating to above 80 deg C.