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    Non linear optical (NLO) materials for making films or foils
    22.
    发明专利
    Non linear optical (NLO) materials for making films or foils 未知

    公开(公告)号：DE19709185A1

    公开(公告)日：1997-10-30

    申请号：DE19709185

    申请日：1997-03-06

    Applicant: BASF AG

    Inventor： SCHROF WOLFGANG DR ,  MOEHWALD HELMUT DR ,  BELOV VLADIMIR DR ,  MAYER ELMA ,  KEUREN EDWARD VAN DR

    IPC: G02F1/35 ,  C07D333/18 ,  C07D495/04 ,  C08G61/12 ,  C08G75/00 ,  C08G79/12 ,  G02F1/355 ,  G02F1/361 ,  C07D495/00

    Abstract: Non-linear optical (NLO) materials - comprise one or more polythiophenes (P) containing repeat units of formula (I) and (II) :X, Y = 1-22C alkyl, 1-22C alkoxy, 1-22C alkyloxyalkyl, 1-22C acyl(oxy), 1-22C thioacyl(oxy), 5-8C cycloalkyl, 6-18C aryl or 5-8C heterocycle, any of which may be substituted with one or more 1-22C alkyl, 1-22C alkoxy, 1-22C alkyloxyalkyl or 1-22C (thio)acyl ; NO2 or NHR ; or X and Y may form a ring containing at least one N, O, S and/or P heteroatom, in which at least one of the ring atoms may be substituted with a group Z ; R = H, 1-22C alkyl, 1-22C alkoxy, 1-22C alkyloxyalkyl or 1-22C (thio)acyl ; Z = X or two Z groups can combine to form a group of formula (III)-(VI) ; and A = C, N or P, or a combination of at least two of these atoms, with the provision that any C atom is bonded to a H atom or substituted in the same way as X. Also claimed are (i) non-linear optical materials comprising a formulation (Q) of at least one polymer (P) and at least one other polymer and (ii) non-linear optical materials containing (P) or comprising (Q).

    Use of compositions based on substituted polyethylenes as nonlinear-optical materials
    25.
    发明专利
    Use of compositions based on substituted polyethylenes as nonlinear-optical materials 未知

    公开(公告)号：DE4333657A1

    公开(公告)日：1995-04-06

    申请号：DE4333657

    申请日：1993-10-02

    Applicant: BASF AG

    Inventor： WUENSCH JOSEF DR ,  HAAS KARL-HEINZ DR ,  ESSER ANTON DR ,  SCHROF WOLFGANG DR

    IPC: G02F1/35 ,  C08F8/00 ,  C08J5/18 ,  C08L39/00 ,  C08L41/00 ,  C08L101/00 ,  C08L101/02 ,  G02F1/355 ,  G02F1/361 ,  B29C71/02 ,  C08L29/04 ,  C08L31/02 ,  C08L39/04

    Abstract: The use of compositions obtainable from a mixture containing A) polyethylenes containing recurring units of the formula I in which R is a radical of the formula R and R and R to R , independently of one another, may be identical or different and are selected from the group consisting of hydrogen, halogen, -NO2, -CN, C1- to C50-alkyl, C1- to C50-alkoxy, C3- to C50-cycloalkyl, C3- to C50-cycloalkoxy, C6- to C18-aryl, C6- to C18-aryloxy and C4- to C18-heteroaryl radicals, where the abovementioned radicals may in each case have one or more substituents, and where the alkyl, alkoxy, cycloalkyl and cycloalkoxy radicals may each contain one or more double bonds, and each of the abovementioned radicals may be interrupted by one or more heteroatoms or groups containing heteroatoms, and R and R , independently of one another, may be identical or different and are selected from the group consisting of C1- to C50-alkyl and C3- to C50-cycloalkyl radicals, and R is selected from the group consisting of C1- to C50-alkyl and C6- to C18-aryl radicals, and X is a halogen, and M is a divalent or trivalent metal, and n is an integer from 5 to 10 , and p is 2 or 3, and B) at least one polymer other than A, by cleaving off radicals R and in each case an alpha -proton from the polyethylene A, as nonlinear-optical materials.

    27.
    发明专利
    未知

    公开(公告)号：ES2176838T3

    公开(公告)日：2002-12-01

    申请号：ES98103369

    申请日：1998-02-26

    Applicant: BASF AG

    Inventor： MEYER-ROSCHER BERND DR ,  SCHROF WOLFGANG DR

    IPC: G01N21/64 ,  G01N21/65

    Abstract: Spectroscopic determination of the degree of cross-linking at different depths in cured pressure-sensitive adhesive layers of cross-linkable oligomeric or polymeric compounds (I) and radiation-sensitive photo-initiators (II) is carried out by confocal Raman or fluorescence spectroscopy. Also claimed is the apparatus used.

    30.
    发明专利
    未知

    公开(公告)号：DE4228852A1

    公开(公告)日：1994-03-03

    申请号：DE4228852

    申请日：1992-08-29

    Applicant: BASF AG

    Inventor： NAARMANN HERBERT DR ,  SCHROF WOLFGANG DR

    IPC: C08F4/72 ,  B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  B01J31/22 ,  C08F4/06 ,  C08F4/42 ,  C08F4/60 ,  C08F4/642 ,  C08F4/643 ,  C08F138/00 ,  G02F1/361 ,  G01N21/62

    Abstract: Polyacetylenes obtainable by the reaction of (A) acetylenes of general formula (I) in which R is hydrogen, C1 to C10 alkyl in which the alkyl radical may be substituted by fluorine and/or chlorine, C1 to C10 alkoxy, C5 to C7 cycloalkyl, F, Cl, CN, -CONH2, -COOH, heteroaryl with 4 to 5 carbon atoms, C1 to C10 alkyl phenyl, phenyl in which the phenyl radical may be substituted by -NO2, fluorine or chlorine, with (B) a catalyst obtainable by the two-stage reaction of (B1) metal-C1 to C10 alcoholates, in which the metal is selected from the fourth to eighth group of the periodic system, with (B2) metal-C1 to C10 alkyls in which the metal is aluminium, magnesium or thallium, or metal acetyl acetonates or metal- pi complexes in which the metals are selected from the fourth to eighth group of the periodic system, the temperature in a first reaction stage being in the range from 20 to 50 DEG C and in a second reaction stage in the range of some 80 to 170 DEG C.

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