公开(公告)号：JPH1183464A

公开(公告)日：1999-03-26

申请号：JP16069198

申请日：1998-06-09

Applicant: BASF AG

Inventor： SCHROF WOLFGANG DR ,  RUNGE FRANK DR ,  KLINGLER JUERGEN DR

IPC: G01B11/28 ,  G01N13/00 ,  G01N13/02

Abstract: PROBLEM TO BE SOLVED: To observe dynamic interface development by generating droplet flow containing a first liquid phase, moving the droplets in a specified track, and measuring the coverage of the interface coated with at least one of molecular species at a plurality of points in the track in non-contact manner. SOLUTION: A dropletor 1 generates and releases uniform droplets 2 at regular intervals. The liquid drops 2 move along a droplet trajectory shown by an arrow 3. A laser 4 radiates laser beam to the droplets in the track through a semisilvered mirror 5 and a lens 6. The light rays reflected by the droplets 2, especially the surface of the molecules, enter a detector 7 through the lens 6 and the semi-transparent mirror 5. The detector 7 enables the droplets to move in the track in the direction shown by an arrow 8 to observe the droplets 2 having the coverage in different generation steps. The detection signals are analyzed by an analysis unit. By this method, the interfacial adsorption of a substance can quickly and continuously be measured in non-contact manner.

公开(公告)号：JPH11189664A

公开(公告)日：1999-07-13

申请号：JP27512098

申请日：1998-09-29

Applicant: BASF AG

Inventor： MEYER-ROSCHER BERND DR ,  SCHROF WOLFGANG DR ,  URBAN DIETER DR ,  GEISS PAUL LUDWIG ,  BROCKMANN WALTER

IPC: C08J3/28 ,  B05D3/06 ,  C08F2/46 ,  C08F220/30 ,  C08F220/58 ,  C08J7/00 ,  C09J7/00 ,  C09J133/00 ,  G03F7/20

Abstract: PROBLEM TO BE SOLVED: To adjust crosslinking so that an optimal combination of adhesive properties, peeling strength and shear strength can be obtained by exposing a radiation crosslinkable pressure-sensitive contact film to a radiation pattern formed of regions of different strength. SOLUTION: As a method for crosslinking a radiation crosslinkable pressure- sensitive contact film by exposing the radiation crosslinkable pressure-sensitive contact film to actinic rays of a regulated dose, the film surface is exposed to a regular or irregular radiation pattern formed of regions of different strengths to crosslink the pressure-sensitive contact film. The radiation pattern can be generated by converging radiation by an optical lens or a magnetic lens or by shading using shade regions by a mask or a stencil. As a crosslinkable compound, a copolymer of a benzophenone group-substituted (meth) acrylic acid derivative and an unsubstituted (meth)acrylate is particularly suitable.

公开(公告)号：JPH11152323A

公开(公告)日：1999-06-08

申请号：JP25579598

申请日：1998-09-09

Applicant: BASF AG

Inventor： MOEHWALD HELMUT DR ,  BELOV VLADIMIR DR ,  SCHROF WOLFGANG DR

IPC: C07D345/00 ,  C07D517/04 ,  C08G61/12 ,  C08G79/00

Abstract: PROBLEM TO BE SOLVED: To obtain a novel polyselenophene having a relatively high conductivity and good mechanical properties as well by reacting 2,5-dihaloselenophene or 2,5-ditriflate selenophene with a selenophene derivative which is substituted by bis(trialkyltin) groups on the carbon atoms adjacent to the selenium atom. SOLUTION: This is a polyselenophene comprising one or plural types of structural units of formulas I and/or II (wherein X and Y are each H, a 1-22C alkyl, a 1-22C alkoxyl, a 1-22C alkyloxyalkyl, a 1-22C acyl, a 1-22C thioacyl, a 1-22C thioacyloxy, a 5-8C cycloalkyl, a 6-18C aryl, a 5-8C heterocyclic group, NO2 , or NHR , R is H, a 1-22C alkyl, a 1-22C alkoxyl, a 1-22C alkyloxyalkyl, a 1-22C acyl, or a 1-22C thioacyl, and X and Y may be combined with each other to form a carbon-containing ring having a plurality of types of heteroatoms).

公开(公告)号：JPH11132950A

公开(公告)日：1999-05-21

申请号：JP19381298

申请日：1998-07-09

Applicant: BASF AG

Inventor： SCHROF WOLFGANG DR ,  ROSSMANITH PETER DR ,  MAECHTLE WALTER DR

IPC: G01N1/28 ,  G01N15/04 ,  G01N21/49

Abstract: PROBLEM TO BE SOLVED: To enable the simple and accurate identification of particles in a sample during centrifugation by irradiating the sample under the action of centrifugal force with laser light, evaluating the spectrum of an inelastic scattering light part of reflected scattering light, and measuring the characteristic amount of matter. SOLUTION: A sample characteristics displaying device is provided with a rotor 1 with a rotating shaft 2, and cells 3 and 4 with empty chambers to hold samples are provided for the grooves of the rotor 1. A laser light source 5 irradiates the cell 4, and a detecting device 6 identifies and stores the spectrum of reflected scattering light from the sample 4. The other light source 9 irradiates the cell 3 via notch filter 10. A detecting device 11 analyzes the spectrum of reflected scattering light passed through the notch filter 10. The laser light source 5, the detecting device 6, the light source 9, and the detecting device 11 can be synchronously moved radially along arrows 7a and 12a and vertically along arrows 7b and 12b. The detecting devices 6 and 11 transmit numerical values to an evaluating device 8.

公开(公告)号：JPH10182707A

公开(公告)日：1998-07-07

申请号：JP35581397

申请日：1997-12-24

Applicant: BASF AG ,  MAX PLANCK GESELLSCHAFT

Inventor： RAGER TIMO ,  MEYER WOLFGANG DR ,  WEGNER GERHARD ,  MATHAUER KLEMENS DR ,  MAECHTLE WALTER DR ,  SCHROF WOLFGANG DR

IPC: C08J3/07 ,  C08F2/22 ,  C08F2/44 ,  C08F10/02 ,  C08F12/08 ,  C08F14/04 ,  C08F18/08 ,  C08F20/10 ,  C08F36/06 ,  C08F210/02 ,  C08F297/02

Abstract: PROBLEM TO BE SOLVED: To produce an aqueous polymer dispersion having reproducibility without requiring a use of a seed dispersion by performing an emulsion polymerization in the presence of a water-soluble neutral acid and an amphipathic material existing in a frozen form of a micelle state under a polymerization condition. SOLUTION: The objective polymer dispersion is obtained by using an aqueous phase in a polymerization vessel including 10 mol/L water-soluble neutral salt (sodium chloride, etc.) before and/or during the polymerization reaction and adding an amphipathic material existing in a frozen form of a micelle state in the polymerization condition when polymerizing a mono unsaturated monomer (e.g. 70-100wt.% acrylic or methacrylic ester of a 1-12C alkyl and/or styrene) by a free radical aqueous polymerization method. The amphipathic material is an oligomer block polymer of a linear composition containing a water-soluble oligomer block derived from the monomer A (styrenesulfonic acid, etc.) and a hydrophobic oligomer block derived from the monomer B (styrene, etc.) having

公开(公告)号：JPH1048678A

公开(公告)日：1998-02-20

申请号：JP5080297

申请日：1997-03-06

Applicant: BASF AG

Inventor： SCHROF WOLFGANG DR ,  MOEHWALD HELMUT DR ,  BELOV VLADIMIR DR ,  MAYER ELMA ,  EDOBUARUTO KOIREN

IPC: G02F1/35 ,  C07D333/18 ,  C07D495/04 ,  C08G61/12 ,  C08G75/00 ,  C08G79/12 ,  G02F1/355 ,  G02F1/361

Abstract: PROBLEM TO BE SOLVED: To obtain an optically stable thiophene compd. or its compsn. showing high nonlinearity and having fast relaxing time by incorporating a specified polythiophene. SOLUTION: The material contains at least one kind of polythiophene having structural units expressed by formula I and formula II. In formulae I and II, X, Y are straight-chain or branched-chains alkyl groups having 1 to 22 carbon atoms or straight-chain of branched-chain alkoxyl groups having 1 to 22 carbon atoms, or X and Y with atoms bonded to these may form a cyclic structure containing carbon atoms. The cyclic structure contains not only carbon atoms but nitrogen (N) heteroatoms, oxygen (O) heteroatoms, sulfur (S) heteroatoms or (P) phosphorus heteroatoms or two or more kinds of these heteroatoms. Moreover, the cyclic structure may have substltuents Z on the position of carbon atoms, nitrogen atoms or phosphorus atoms, and each Z independently represents the same groups as defined as X and Y.

公开(公告)号：JP2004005412A

公开(公告)日：2004-01-08

申请号：JP2003020751

申请日：2003-01-29

Applicant: BASF AG

Inventor： SCHROF WOLFGANG DR ,  LORENZ THOMAS ,  LEHMANN STEPHAN ,  HADELER JOACHIM ,  IDEN RUDIGER ,  BANDARA UPALI

IPC: H04N7/18 ,  G05B23/02 ,  G06F7/00 ,  G06F15/00 ,  G06F19/00 ,  G08B25/00 ,  G08B25/08 ,  H04M11/00

Abstract: PROBLEM TO BE SOLVED: To provide a remote research system providing a possibility of remote research. SOLUTION: The remote research system comprises a central laboratory site for carrying out chemical research tests, a laboratory robot for carrying out the chemical research tests, a central processing unit (CPU), a workstation 10 linked to the central processing unit for controlling the laboratory robot, a camera detecting actions of the laboratory robot when a chemical research test is being carried out and linked to the central processing unit via the workstation, and a workstation 20 for a remote user linked to the central processing unit 12 via a computer network 22 to allow remote user access to the chemical research test carried out in the central laboratory site. Execution states of the test are sent to the workstation 20 for the remote user by the camera via the central processing unit 12 and the computer network 22. COPYRIGHT: (C)2004,JPO

公开(公告)号：JP2001059838A

公开(公告)日：2001-03-06

申请号：JP2000202300

申请日：2000-07-04

Applicant: BASF AG

Inventor： SCHUCH HORST ,  SCHROF WOLFGANG DR

IPC: G01N30/02 ,  G01N30/00 ,  G01N30/46 ,  G01N30/62

Abstract: PROBLEM TO BE SOLVED: To quickly acquire accurate information in regard to liquid flow by using the liquid flow supplied from a pump for a plurality of separation channels and a changeover device. SOLUTION: Carrier liquid is supplied to each separation channel 2 by a pump 1, a flow control valve is provided in the inlet 4 of each separation channel 4, and the carrier liquid is introduced and passed to each separation channel 2 by same pressure. The whole separation channel 2 is made same structure, made the same flow condition in regard to the carrier liquid, and an analytical result is directly comparable. A sample is introduced from each inlet 4 by a changeover valve. A traverse flow is supplied to a flowmeter 6 through a multi- directional valve 5 and an outlet pipe, flow resistance is provided in the outlet pipe, and is the same pressure drop of the flowmeter 6. After the sample passing through the separation channel 2 corresponding thereto together with the axial flow of the carrier liquid passes through one separation channel 2 respectively, it is supplied to the other analyzer or a measuring device through the other multi-directional valve 7. A detector and the individual separation channel 2 are connected by the multi-directional valve 7 at a constant cycle.

公开(公告)号：JPH11160745A

公开(公告)日：1999-06-18

申请号：JP25641198

申请日：1998-09-10

Applicant: BASF AG

Inventor： MOEHWALD HELMUT DR ,  BELOV VLADIMIR DR ,  SCHROF WOLFGANG DR

IPC: G02F1/35 ,  C07F19/00 ,  C08G61/12 ,  C08J5/18 ,  C08L65/00 ,  G02F1/355 ,  G02F1/361

Abstract: PROBLEM TO BE SOLVED: To obtain an optically stable selenophene compd. which may be produced and processed to a thin film form by a simple process, has an excellent nonlinear characteristic and has a rapid relaxation time and optically high quality by using a nonlinear optical material contg. specific polyselenophene. SOLUTION: This nonlinear optical material contains the polyselenophene having the structural units of formula I or formula II or >=1 kind of the formula I or the formula II. In the forms, X and Y may be same or different and respectively independently denote hydrogen (in this case only either of X and Y is hydrogen), straight or branched 1-22C alkyl group, straight or branched 1-22C alkoxy group, etc. Or X and Y and the atom to which these are bonded may cojointly form a carbon-contg. ring having nitrogen (N), oxygen (O), sulfur (S) or phosphorus (P) hetero atom in addition to a carbon atom or >=2 kinds of these hetero atoms.

公开(公告)号：JPH1096698A

公开(公告)日：1998-04-14

申请号：JP20305097

申请日：1997-07-29

Applicant: BASF AG

Inventor： SCHROF WOLFGANG DR ,  KLINGLER JUERGEN DR ,  HORN DIETER DR

IPC: G01N21/65 ,  G01J3/28 ,  G01J3/44 ,  G01J3/457 ,  G01N15/02

Abstract: PROBLEM TO BE SOLVED: To provide a method with good selectivity for measuring a diffusion parameter of particles, e.g. a diffusion speed, a diffusion coefficient, local concentration, size and the flow behavior of particles, which eliminates marking to particles to be observed. SOLUTION: An excitation light of a light source, particularly a laser is directed to a sample 10, and a Raman scattering light from the observed capacity sample is collected and guided to a spectrometer, particularly a grating spectrograph 6. The light is developed to spectral lines. A luminance of at least one spectral line is measured at least ten times for every second by a photodetector 8, particularly a photoelectric multiplier or a photodiode. Based on the measured luminance value of the spectral line, a diffusion parameter, concentration, size or the flow behavior of particles in the sample corresponding to the spectral line is calculated by analyzing a change in luminance value, particularly a self correlation or a frequency.