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公开(公告)号:DE3174907D1
公开(公告)日:1986-08-14
申请号:DE3174907
申请日:1981-01-08
Applicant: BASF AG
Inventor: HORN PETER DR , HESSE ANTON DR , WEYLAND PETER DR , STRAEHLE WOLFGANG DR , MARX MATTHIAS DR
IPC: C08G18/00 , C08G18/02 , C08G18/28 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/56 , C08G18/60 , C08G18/64 , C08G18/65 , C08G18/66
Abstract: This invention relates to a process for preparing cellular polymers having urethane groups, isocyanurate groups, or both. The cellular polymers are prepared by reacting an organic polyisocyanate with certain polymer dispersions in the presence of a blowing agent. The polymer dispersions comprise (a) as a continuous phase, a polyol having a functionality of 2 to 8 and a hydroxyl number of 150 to 700; and (b) as a dispersed phase, an organic compound having (a) at least one Zerewitinoff active hydrogen atom, (b) a melting point of 30 DEG C. to 260 DEG C., and (c) a molecular weight of 178 to 100,000.
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公开(公告)号:AT146196T
公开(公告)日:1996-12-15
申请号:AT92115800
申请日:1992-09-16
Applicant: BASF AG
Inventor: GROLL PETER DR , STRAEHLE WOLFGANG DR , MUELLER HERBERT DR
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公开(公告)号:DE3638488A1
公开(公告)日:1988-05-19
申请号:DE3638488
申请日:1986-11-11
Applicant: BASF AG
Inventor: STREU JOACHIM DR , STRAEHLE WOLFGANG DR , RAMLOW GERHARD DR
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公开(公告)号:DE3614188A1
公开(公告)日:1987-10-29
申请号:DE3614188
申请日:1986-04-26
Applicant: BASF AG
Inventor: WERNER FRANK DR , STRAEHLE WOLFGANG DR , SCHUETT UWE
IPC: A43B13/04 , A43B13/12 , C08G18/66 , A43B9/16 , A43D65/00 , B32B5/20 , B32B27/40 , C08G18/14 , C08G18/32 , C08G18/65
Abstract: The invention relates to a two-layer shoe sole comprising i) an outsole of high-density polyurethane-polyurea elastomers and ii) a throughsole or comfort sole of low density produced by the one-shot process with the aid of the high-pressure method (RIM) by reacting a) organic polyisocyanates, b) relatively high-molecular-weight polyols, c) chain extenders and/or crosslinking agents, in the presence of d) catalysts, e) blowing agents and optionally f) auxiliaries and/or additives, where the formative component (c) for the production of the outsole (i) comprises primary aromatic polyamines, preferably alkyl-substituted phenylenediamines, containing at least one bonded alkyl radical in the ortho-position to each amino group, at least one of the alkyl radicals comprising more than 3 carbon atoms.
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公开(公告)号:DE3274115D1
公开(公告)日:1986-12-11
申请号:DE3274115
申请日:1982-06-25
Applicant: BASF AG
Inventor: NISSEN DIETMAR DR , STRAEHLE WOLFGANG DR , MARX MATTHIAS DR
Abstract: A process for the preparation of optionally cellular and non-cellular polyurethane elastomers, preferably by reaction injection molding, organic polyisocyanates, polyether polyols based on polyoxyalkylene polyether polyols with terminal hydroxyethylene groups and an ethoxylation degree of 1 to 13, having a content of primary hydroxyl groups at the corresponding degree of ethoxylation as the value of curve A to 100 percent with curve A describing the dependency of the primary hydroxyl group content upon the degree of ethoxylation are reacted with chain extenders and/or cross-linking agents in the presence of catalysts as well as optionally blowing agents, auxiliaries and additives.
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26.
公开(公告)号:AT20672T
公开(公告)日:1986-07-15
申请号:AT81100067
申请日:1981-01-08
Applicant: BASF AG
Inventor: HORN PETER DR , HESSE ANTON DR , WEYLAND PETER DR , STRAEHLE WOLFGANG DR , MARX MATTHIAS DR
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公开(公告)号:AT16177T
公开(公告)日:1985-11-15
申请号:AT82111822
申请日:1982-12-20
Applicant: BASF AG
Inventor: MARX MATTHIAS DR , STRAEHLE WOLFGANG DR
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公开(公告)号:DE3316592A1
公开(公告)日:1984-11-08
申请号:DE3316592
申请日:1983-05-06
Applicant: BASF AG
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公开(公告)号:DE3315382A1
公开(公告)日:1984-10-31
申请号:DE3315382
申请日:1983-04-28
Applicant: BASF AG
Inventor: STRAEHLE WOLFGANG DR , BUETHE INGOLF DR , MARX MATTHIAS DR
IPC: C07C69/80 , C08G18/42 , C08G18/48 , C08G65/26 , C08G65/32 , C08G18/14 , C08G18/18 , C08G18/20 , C08G18/66
Abstract: 1. A process for preparing an elastic, compact or cellular polyurethane by reacting a) an organic polyisocyanate with b) an organic polyhydroxy compound in the presence of c) a catalyst and optionally d) a chain extending or crosslinking agent, e) a blowing agent, f) an assistand and/or an additive, wherein polyhydroxy compound b) comprises to an extent not less than 30% by weight, based on total component b), a di-, tri- or tetrafunctional polyether polyester polyol having a hydroxyl number of from 10 to 200 and having been prepared by esterification of i) a di-, tri- or tetrafunctional polyetherol having a hydroxyl number of from 15 to 250 with a carboxylic anhydride in the presence of N-methylimidazole and/or triethylenediamine as a catalyst to give a carboxylic monoester and subsequent ii) alkoxylation of the carboxylic monoester with an alkylene oxide in the presence of a mixture of N-methylimidazole and/or triethylenediamine and triphenylphosphine and/or a thiodialkylene glycol as a catalyst, the amount of catalyst being from 0.05 to 2.0 parts by weight, based on 100 parts by weight of the mixture of polyol and carboxylic anhydride or on 100 parts by weight of carboxylic monoester.
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公开(公告)号:DE3315381A1
公开(公告)日:1984-10-31
申请号:DE3315381
申请日:1983-04-28
Applicant: BASF AG
Inventor: STRAEHLE WOLFGANG DR , MARX MATTHIAS DR
Abstract: In order to prepare polyester or polyetherpolyester polyols, polyols, preferably di- to hexafunctional polyether polyols having hydroxyl numbers from 15 to 250 are esterified with at least one carboxylic acid anhydride, preferably phthalic acid anhydride, in the presence of N-methylimidazole, triethylenediamine, and/or triphenylphosphine as catalysts to form a carboxylic acid half-ester, and said half-ester is then oxyalkylated with at least one alkylene oxide, preferably ethylene oxide, in the presence of N-methylimidazole, triethylenediamine, triphenylphosphine, thiodialkylene glycol, employing a mixture of at least two of the compounds cited as catalysts.
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