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公开(公告)号：AU2003250195A1
公开(公告)日：2004-03-19
申请号：AU2003250195
申请日：2003-07-30
Applicant: BASF AG
Inventor： STROEZEL MANFRED , BECKER JENS , BERNING WILFRIED , GENGER THOMAS , OOST CARSTEN , SNOECK JOOST-WILLEM
IPC: B01J10/00 , B01J19/00 , C07B61/00 , C07C27/12 , C07C29/50 , C07C35/08 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C49/403 , C07C51/215 , C07C51/25 , C07C51/265 , C07C407/00 , C07C409/14 , C07C409/16 , C07C51/16
Abstract: A process for oxidizing a starting material with an oxidizing agent to obtain a product, which comprises carrying out the oxidation in a reaction apparatus which has a bottom region at the lower end, a top region at the upper end and a reaction zone between the top region and the bottom region, maintaining the reaction mixture in the boiling state in the reaction zone, and introducing oxidizing agent into the reaction zone in at least two substreams.
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公开(公告)号：DE10240816A1
公开(公告)日：2004-03-11
申请号：DE10240816
申请日：2002-08-30
Applicant: BASF AG
Inventor： GENGER THOMAS , OOST CARSTEN , SNOECK JOOST-WILLEM , STROEZEL MANFRED , BECKER JENS , BERNING WILFRIED
IPC: B01J10/00 , B01J19/00 , C07B61/00 , C07C27/12 , C07C29/50 , C07C35/08 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C49/403 , C07C51/215 , C07C51/25 , C07C51/265 , C07C407/00 , C07C409/14 , C07C409/16 , C07B33/00
Abstract: A process for oxidizing a starting material with an oxidizing agent to obtain a product, which comprises carrying out the oxidation in a reaction apparatus which has a bottom region at the lower end, a top region at the upper end and a reaction zone between the top region and the bottom region, maintaining the reaction mixture in the boiling state in the reaction zone, and introducing oxidizing agent into the reaction zone in at least two substreams.
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公开(公告)号：ES2198106T3
公开(公告)日：2004-01-16
申请号：ES99122634
申请日：1999-11-13
Applicant: BASF AG
Inventor： OOST CARSTEN DR , STROEZEL MANFRED , ETZRODT HEINZ DR , WELLER DIETMAR DR , KAIBEL GERD DR , JAEDICKE HAGEN DR
Abstract: Preparation of unsaturated methyl ketones(I), from an unsaturated alcohol(II) and alkyl acetoacetate(III) in the presence of an organo-aluminum catalyst(IV) comprises: (a) supplying (II) and (IV) to a reactor with a distillation column, (b) making temperature to be 170-250 degrees C under elevated pressure, (c) dosing the mixture with (III) and (d) maintaining a constant (III) content of 0.1-10 wt.% during the reaction. Preparation of unsaturated ketones of formula (I) involves reaction of an unsaturated alcohol of formula (II) with an alkyl acetoacetate of formula (III), in presence of 0.1-5 mol. % (based on (II)) of an organo-aluminum compound catalyst (IV), with elimination and distillative separation of the alcohol R3OH formed in the reaction, in a reactor system provided with a distillation column. Reaction is carried out by: (a) supplying (I (which boils at less than 140 degrees C), without a solvent, and (IV) to the reaction vessel, (b) adjusting the temperature to a value as constant as possible in the range 170-250 degrees C under elevated pressure, (c) dosing the mixture with (III) and (d) maintaining a (III) content as constant as possible in the range 0.1-10 wt. % during the reaction. Dotted line = optional bond; R1 = Me or Et; R2, R3 = 1-4C alkyl.
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公开(公告)号：DE59710290D1
公开(公告)日：2003-07-24
申请号：DE59710290
申请日：1997-03-24
Applicant: BASF AG
Inventor： KAIBEL DR , BROECKER DR , STROEZEL MANFRED
IPC: B01F5/06 , B01J8/00 , B01J8/06 , B01J8/18 , B01J8/20 , B01J8/22 , B01J8/34 , B01J19/24 , C07C45/62
Abstract: In carrying out reactions in a reactor containing a liquid phase in which a catalyst is suspended, and where a gaseous phase may be present, the liquid and gas phases pass, at least partly, through a device having openings or passages whose hydraulic diameter is 0.5-20 (1-3) mm. Also claimed is the reactor including a device having openings or passages in it built so that liquid or gas flow through it during the reaction.
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公开(公告)号：AT238263T
公开(公告)日：2003-05-15
申请号：AT99122634
申请日：1999-11-13
Applicant: BASF AG
Inventor： OOST CARSTEN DR , STROEZEL MANFRED , ETZRODT HEINZ DR , WELLER DIETMAR DR , KAIBEL GERD DR , JAEDICKE HAGEN DR
Abstract: Preparation of unsaturated methyl ketones(I), from an unsaturated alcohol(II) and alkyl acetoacetate(III) in the presence of an organo-aluminum catalyst(IV) comprises: (a) supplying (II) and (IV) to a reactor with a distillation column, (b) making temperature to be 170-250 degrees C under elevated pressure, (c) dosing the mixture with (III) and (d) maintaining a constant (III) content of 0.1-10 wt.% during the reaction. Preparation of unsaturated ketones of formula (I) involves reaction of an unsaturated alcohol of formula (II) with an alkyl acetoacetate of formula (III), in presence of 0.1-5 mol. % (based on (II)) of an organo-aluminum compound catalyst (IV), with elimination and distillative separation of the alcohol R3OH formed in the reaction, in a reactor system provided with a distillation column. Reaction is carried out by: (a) supplying (I (which boils at less than 140 degrees C), without a solvent, and (IV) to the reaction vessel, (b) adjusting the temperature to a value as constant as possible in the range 170-250 degrees C under elevated pressure, (c) dosing the mixture with (III) and (d) maintaining a (III) content as constant as possible in the range 0.1-10 wt. % during the reaction. Dotted line = optional bond; R1 = Me or Et; R2, R3 = 1-4C alkyl.
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Patent Agency Ranking
公开(公告)号：ES2186267T3
公开(公告)日：2003-05-01
申请号：ES99105126
申请日：1999-03-26
Applicant: BASF AG
Inventor： BROCKER FRANZ JOSEF DR , KAIBEL GERD DR , AQUILA WERNER DR , FUCHS HARTWIG , WEGNER GUNTER DR , STROEZEL MANFRED
IPC: B01J23/44 , B01J8/20 , B01J8/22 , B01J19/24 , B01J23/46 , C07B61/00 , C07C45/62 , C07C47/21 , C07C49/04
Abstract: Production of saturated carbonyl compounds (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds (II) is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. Production of saturated carbonyl compounds of formula R1-CH(R2)-CH(R3)-C(R4)=O (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds of formula R1-C(R2)=C(R3)-C(R4)=O (II) in the presence of a particulate palladium and/or rhodium catalyst and a base is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. R1 = H or an organic group; R2-R4 = H or 1-4C alkyl.
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公开(公告)号：PT947493E
公开(公告)日：2003-03-31
申请号：PT99105126
申请日：1999-03-26
Applicant: BASF AG
Inventor： STROEZEL MANFRED , KAIBEL GERD , AQUILA WERNER , BROCKER FRANZ JOSEF , FUCHS HARTWIG , WEGNER GUNTER
IPC: B01J23/44 , B01J8/20 , B01J8/22 , B01J19/24 , B01J23/46 , C07B61/00 , C07C45/62 , C07C47/21 , C07C49/04
Abstract: Production of saturated carbonyl compounds (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds (II) is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. Production of saturated carbonyl compounds of formula R1-CH(R2)-CH(R3)-C(R4)=O (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds of formula R1-C(R2)=C(R3)-C(R4)=O (II) in the presence of a particulate palladium and/or rhodium catalyst and a base is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. R1 = H or an organic group; R2-R4 = H or 1-4C alkyl.
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公开(公告)号：ES2183469T3
公开(公告)日：2003-03-16
申请号：ES99122636
申请日：1999-11-13
Applicant: BASF AG
Inventor： OOST CARSTEN , STROEZEL MANFRED , ETZRODT HEINZ , WELLER DIETMAR , RHEUDE UDO , KAIBEL GERD
IPC: B01J31/14 , C07B61/00 , C07C45/67 , C07C45/74 , C07C49/203
Abstract: Preparation of unsaturated ketones by reaction of the corresponding alpha , beta -unsaturated alcohol with an alkyl acetoacetate compound in the presence an organo-aluminum catalyst at constant temperature, with separation and continuous removal of CO2 and alcohol formed. Preparation of unsaturated ketones of formula (I) by reaction of the corresponding alpha , beta -unsaturated alcohol of formula (II) with an alkyl acetoacetate compound of formula (III) in the presence of 0.1-5 mole% (based on (III)) of an organo-aluminum catalyst with separation and continuous distillative removal of CO2 and alcohol of formula R3OH formed during reaction, in a reactor containing a fractionation column, where: (A) (II) is added to the reaction mixture together with the organic catalyst without additional solvent and (III) is then added to this mixture; (B) the reaction temperature is kept constant between 175-220 degrees C; (C) the content of (III) is kept at a constant level between 0.1-10 wt.% during the reaction. R1, R3 = 1-4C alkyl; R2 = 4-30C aliphatic, cycloaliphatic or cycloaliphatic-aliphatic; a, b = optional additional bonds.
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公开(公告)号：DE59708164D1
公开(公告)日：2002-10-17
申请号：DE59708164
申请日：1997-04-22
Applicant: BASF AG
Inventor： KAIBEL DR , STROEZEL MANFRED , RHEUDE DR
Abstract: A partitioned column for separating a multi-component mixture into three or more fractions comprises at least one removable partition wall. Also claimed is a process for separating a multi-component mixture into three or more fractions using the above column.
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公开(公告)号：AT224348T
公开(公告)日：2002-10-15
申请号：AT98119215
申请日：1998-10-12
Applicant: BASF AG
Inventor： OOST CARSTEN DR , STROEZEL MANFRED , ETZRODT HEINZ DR , BOCKSTIEGEL BERNHARD DR , JAEDICKE HAGEN DR , WELLER DIETMAR DR , LAUPICHLER LOTHAR DR , REIMER KLAUS
Abstract: Preparation of gamma , delta -unsaturated ketones (I) by modified Carroll reaction is catalysed by a stable liquid aluminum acetoacetate compound or mixture of such compounds. Some such catalyst mixtures are new. Preparation of gamma , delta -unsaturated ketones of formula (I) involves modified Carroll reaction of an allyl alcohol of formula (II) with diketene or an alkyl acetoacetate of formula (III) in presence of an aluminum catalyst. R1 = H or 1-20C, saturated or unsaturated, branched hydrocarbyl; R2 = 1-5C alkyl. The novelty is that the catalyst consists of an aluminum compound (or aluminum compound mixture) which is a stable liquid at room temperature and contains at least one alkyl acetoacetate-forming group and 1 or 2 alkoxy groups or exclusively alkyl acetoacetate forming groups which are esterified sec. butanol or isobutanol or with at least two different alkanols. Independent claims are included for: (1) new mixtures of aluminum tris-acetoacetates of formula (V) which are liquid at room temperature; and (2) the preparation of mixtures as in (1). R3 = 1-5C alkyl, preferably Me or Et; R4 = 3-10C alkyl, preferably CHMe2, CH(Me)Et, CMe3 or CH(Me)-C3H7; R5 = 1-10C alkyl, preferably Me, Et, CHMe2, CH(Me)Et or CH(Me)-C3H7; provided that R3-R5 are not all the same. A further Independent claim relates to the continuous preparation of compounds (V) (or their mixtures), having the narrower proviso that R3-R5 can only be the same if they are -CH(Me)Et or -CH2CHMe2, which are liquid at room temperature. The process involves continuously reacting 1 mole of aluminum alcoholate of formula (VI) with 3-10 moles of (III), or with at least 3 moles of a mixture of 2 or 3 different compounds (III), optionally dissolved in an inert solvent. Reaction is at 100-250 (preferably 150-200) degrees C and 1-100 (preferably 1-10) bars with a dwell time of 5-120 (preferably 15-45) minutes, the pressure and temperature being such that no gas phase is formed in the reaction vessel. R6 = 2-10C alkyl, preferably -CH2CHMe2, -CH(Me)Et or -CH(Me)C3H7; provided that R2 and R6 can only be the same if they are -CH(Me)Et or -CH2CHMe2.
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