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公开(公告)号:AT33849T
公开(公告)日:1988-05-15
申请号:AT84100852
申请日:1984-01-27
Applicant: BASF AG
Inventor: DERSCH ROLF DR , LOCH WERNER DR , MATTHAEI LOTHAR , SCHULTZE WOLFGANG , WISTUBA ECKEHARDT DR
IPC: C04B24/26 , C04B26/06 , C04B41/46 , C04B41/63 , C04B41/65 , C09D133/04 , C09D133/06 , C09K3/00 , C09D3/80
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公开(公告)号:DE3502944A1
公开(公告)日:1986-07-31
申请号:DE3502944
申请日:1985-01-30
Applicant: BASF AG
Inventor: KOSSMANN HERIBERT , MATTHAEI LOTHAR , LEY GREGOR DR , WISTUBA ECKEHARDT DR , WULGARIS SAVAS DR
IPC: C09D5/00 , C09D5/02 , C09D15/00 , C09D125/00 , C09D125/04 , C09D125/14 , C09D127/04 , C09D133/02 , C09D133/04 , C09D133/06 , C09D135/00 , C09D157/00 , C09D3/74 , C09D5/14 , C09D7/12 , B27K3/34 , B27K3/50
Abstract: Binders for aqueous primers for wood paints contain (A) from 50 to 95% by weight, based on the weight of the primer, of an aqueous dispersion of a vinyl polymer having a particle size of from 0.03 to 0.5 mu m and a minimum film-forming temperature of from 0 DEG to 50 DEG C., the said dispersion being stable to polyvalent ions, and (B) from 5 to 50% by weight, based on the weight of the primer, of a water-soluble polymeric zinc amine complex of a copolymer which has a K value of from 8 to 40 and consists of (a) from 20 to 60% by weight, based on the weight of the copolymer, of an alpha , beta -monoethylenically unsaturated mono- and/or dicarboxylic acid of 3 to 5 carbon atoms and (b) from 40 to 80% by weight, based on the weight of the copolymer, of styrene and/or one or more alkyl (meth)acrylates, where alkyl is of 1 to 8 carbon atoms, the copolymer being reacted with from 2 to 6 moles, based on the carboxyl groups of the copolymer, of ammonia and from 0.8 to 1.2 equivalents of a zinc compound per carboxyl group of the copolymer.
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公开(公告)号:DE3437920A1
公开(公告)日:1986-04-17
申请号:DE3437920
申请日:1984-10-17
Applicant: BASF AG
Inventor: MATTHAEI LOTHAR , KERCKOW ALBRECHT DR , PETERS KARL-CLEMENS DR , WISTUBA ECKEHARDT DR
IPC: C08F2/24 , C08F218/04 , C08F220/12 , C08F220/06
Abstract: This invention relates to a process for the preparation of aqueous vinyl propionate tert-butyl acrylate copolymer dispersions which are suitable, in particular, as binders for paints and plasters, by emulsion polymerisation in which the monomers are fed to the polymerisation mixture, after initiation of the polymerisation, in such a manner that vinyl propionate is only fed in after from 5 to 20 % of the other monomers have polymerised, the vinyl propionate being fed in together with the remainder of the other monomers in an amount which increases with time.
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公开(公告)号:DE3173237D1
公开(公告)日:1986-01-30
申请号:DE3173237
申请日:1981-06-03
Applicant: BASF AG
Inventor: DERSCH ROLF DR , LOCH WERNER DR , NEUBERT GERHARD DR , WISTUBA ECKEHARDT DR
IPC: C08F220/00 , C08F220/04 , C08F220/10 , C08F220/12 , C09D5/02 , C09D133/04
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公开(公告)号:DE3225875A1
公开(公告)日:1984-01-12
申请号:DE3225875
申请日:1982-07-10
Applicant: BASF AG
Inventor: HAMBRECHT JUERGEN DR , MUENCH VOLKER DR , BANKOWSKY HEINZ-HILMAR , MUELLER DIETRICH-WOLFGANG DR , WISTUBA ECKEHARDT DR
IPC: B41M7/00 , C08F212/08 , C08L25/14 , C08L91/06 , C09D125/08 , D21H19/12 , C08F8/44 , C08F214/04 , C08F220/04 , C08F220/44 , D21H1/40
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公开(公告)号:DK0773245T3
公开(公告)日:2001-02-19
申请号:DK96117484
申请日:1996-10-31
Applicant: BASF AG
Inventor: SCHMIDT-THUEMMES JUERGEN DR , WISTUBA ECKEHARDT DR , DRAGON ANDREE , ANSELMANN THOMAS
IPC: C08K3/28 , C08F2/22 , C08F212/00 , C08F212/06 , C08F212/08 , C08F236/10 , C08K3/00 , C08K5/17 , C08L25/00 , C08L25/02 , C09D5/00 , C09D109/06 , C09D109/08 , C09D125/00 , C09D125/02 , C09D125/10
Abstract: Aqueous polymer dispersions (I), containing a radical copolymer (CP) with an alkali metal ion content (GA) of not more than 0.5 wt.%, based on (A) 20-65 wt.% vinylaromatic monomer(s), (B) 35-80 wt.% comonomer(s) with two conjugated double bonds and (C) 0-10 wt.% other comonomers with at least one double bond. Also claimed are (i) aqueous polymer preparations containing (I) and finely divided pigment in amounts of up to 60 vol.% (IIA) or 20-45 vol.% (IIB); (ii) substrates coated with a film of (I) or (II), and (iii) a process for the production of (I) by radical- initiated aqueous emulsion polymerisation of the above comonomers, with the addition of ammonia and/or organic amine to increase the pH of the dispersion medium.
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公开(公告)号:AT199019T
公开(公告)日:2001-02-15
申请号:AT96117484
申请日:1996-10-31
Applicant: BASF AG
Inventor: SCHMIDT-THUEMMES JUERGEN DR , WISTUBA ECKEHARDT DR , DRAGON ANDREE , ANSELMANN THOMAS
IPC: C08K3/28 , C08F2/22 , C08F212/00 , C08F212/06 , C08F212/08 , C08F236/10 , C08K3/00 , C08K5/17 , C08L25/00 , C08L25/02 , C09D5/00 , C09D109/06 , C09D109/08 , C09D125/00 , C09D125/02 , C09D125/10
Abstract: Aqueous polymer dispersions (I), containing a radical copolymer (CP) with an alkali metal ion content (GA) of not more than 0.5 wt.%, based on (A) 20-65 wt.% vinylaromatic monomer(s), (B) 35-80 wt.% comonomer(s) with two conjugated double bonds and (C) 0-10 wt.% other comonomers with at least one double bond. Also claimed are (i) aqueous polymer preparations containing (I) and finely divided pigment in amounts of up to 60 vol.% (IIA) or 20-45 vol.% (IIB); (ii) substrates coated with a film of (I) or (II), and (iii) a process for the production of (I) by radical- initiated aqueous emulsion polymerisation of the above comonomers, with the addition of ammonia and/or organic amine to increase the pH of the dispersion medium.
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公开(公告)号:DE19724915A1
公开(公告)日:1998-12-17
申请号:DE19724915
申请日:1997-06-12
Applicant: BASF AG
Inventor: ZHAO CHENG-LE DR , ROSER JOACHIM DR , WISTUBA ECKEHARDT DR , MATHAUER KLEMENS DR , SCHULER BERNHARD DR
IPC: C08F2/22 , C08F4/30 , C08F4/34 , C08F265/06 , C08F291/00 , C09D151/00 , C09J151/00 , C04B26/06 , C08F220/18 , C08J3/03 , C08J3/12 , C09D133/06 , C09D151/06 , C09J133/04 , D06M15/263 , D21H17/37
Abstract: Production of aqueous polymer dispersions (I) comprises radical-initiated aqueous emulsion polymerisation of ethylenic monomers to give a dispersion of polymer (A) followed by radical polymerisation of other monomers in one or more subsequent stages (i) in the presence of polymer (A), with the following features: (a) polymer (A) has a Tg of Tg1, (b) the monomers polymerised in stages (i) are such that the isolated statistical (co)polymerisation of these monomers gives a polymer (i) with a Tg which approaches a limiting value of Tgi with increasing molecular weight, (c) for each Tg1 the difference Tgi - Tg1 = at least 10 deg C, (d) the amount of monomers polymerised in polymer (A) is 85-99.9 wt.% of the total amount (TM) polymerised in the entire process, (e) the total amount of monomers polymerised in all stages (i) is 0.1-15 wt.% of TM, (f) in each stage (i), the addition of monomer is carried out so that monomer conversion (polymerisation) (Ui) does not exceed 50 mol% of the amount already in the reactor at any time up to the end of addition, and (g) apart from monomers with two conjugated double bonds, the total amount of monomer used for the production of polymer (A) includes not more than 5 wt.% monomers with more than one unsaturated group. Also claimed are (1) dispersions (I) obtained by this process, (2) polymer powder obtained by spray drying (I), (3) polymers obtained by this process and (4) aqueous dispersions containing such polymers.
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公开(公告)号:ES2105377T3
公开(公告)日:1997-10-16
申请号:ES94103350
申请日:1994-03-05
Applicant: BASF AG
Inventor: FRICKE HANS-JOACHIM , HAEBERLE KARL DR , MAEMPEL LOTHAR DR , PEIKERT FRITZ , WISTUBA ECKEHARDT DR
IPC: C08G18/08 , C09J175/00 , C09J175/04
Abstract: The use of aqueous dispersions containing a polyurethane having a content of urea groups of less than 0.6 % by weight, based on the polyurethane, as adhesives.
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公开(公告)号:ES2087587T3
公开(公告)日:1996-07-16
申请号:ES93102290
申请日:1993-02-13
Applicant: BASF AG
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