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公开(公告)号：DE102008042061A1
公开(公告)日：2010-03-18
申请号：DE102008042061
申请日：2008-09-12
Applicant: BASF SE
Inventor： RAICHLE ANDREAS , HORSTMANN CATHARINA , ROSOWSKI FRANK , MUELLER-ENGEL KLAUS JOACHIM , PETZOLDT JOCHEN , CREMER ULRICH
Abstract: A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [BiaZ1bOx]p[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy]1, in which a finely divided oxide BiaZ1bOx and, formed from element sources, a finely divided mixture of stoichiometry BicMo12FedZ2eZ3fZ4gZ5hZ6i are mixed in a ratio of p:1, this mixture is used to form shaped bodies and these are treated thermally, where 0
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公开(公告)号：DE102007010422A1
公开(公告)日：2008-09-04
申请号：DE102007010422
申请日：2007-03-01
Applicant: BASF SE
Inventor： CREMER ULRICH , RAICHLE ANDREAS , ROSOWSKI FRANK , HAMMON ULRICH , MUELLER-ENGEL KLAUS JOACHIM
IPC: B01J23/28 , B01J35/10 , C07C57/055
Abstract: Preparation of a catalyst consisting of a carrier body and a catalytic active mass, which is applied on the surface of the carrier body, comprises attaching one of the active mass to the surface of the carrier body with the help of a binding agent, where the active mass is a finely divided mixture of: at least an element of molybdenum and vanadium containing finely divided multielement oxides; and at least a finely divided substance comprising oxide of molybdenum or its compound, which forms its oxide under the effect of increased temperature and molecular oxygen. An independent claim is included for a catalyst, obtained by the above process.
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公开(公告)号：MY158839A
公开(公告)日：2016-11-15
申请号：MYPI2011000802
申请日：2009-09-01
Applicant: BASF SE
Inventor： RAICHLE ANDREAS , HORSTMANN CATHARINA , ROSOWSKI FRANK , MÜLLER-ENGEL KLAUS JOACHIM , BORCHERT HOLGER , COX GERHARD , CREMER ULRICH
IPC: B01J23/888 , B01J35/02 , C07C45/35 , C07C51/25
Abstract: THE INVENTION RELATES TO A METHOD FOR PRODUCING GEOMETRIC CATALYST MOULDED BODIES (K), THE ACTIVE MASS THEREOF BEING A MULTI-ELEMENT OXIDE IN THE STOICHIOMETRY [Bᵢ₁WbOx]a [M0₂Z¹cZ²dFeeZᶟfZ⁴gZ⁵hOy]l. SAID METHOD CONSISTS OF FORMING A FINE PARTICLE OXIDE BilWbOxHAVING A GRAIN SIZE (FORMULA I) AND, FROM ELEMENT SOURCES, A FINE PARTICLE INTIMATE MIXTURE IN THE STOICHIOMETRY M0l₂Z¹cZ²dFeeZᶟfZ⁴gZ⁵h HAVING THE GRAIN SIZE (FORMULA II) AND SAID MIXTURE IS MIXED ACCORDING TO THE RATIO A: 1, FORMING MOULDED BODIES WITH THE MIXTURE WHICH ARE THEN THERMALLY TREATED. FORMULA (III) IS ≥ 820. (FIGURE 1)
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公开(公告)号：MY158287A
公开(公告)日：2016-09-30
申请号：MYPI20082496
申请日：2008-07-04
Applicant: BASF SE
Inventor： DIETERLE MARTIN , CREMER ULRICH , MÜLLER-ENGEL KLAUS-JOACHIM
IPC: C07C51/16 , C07C51/235
Abstract: 66 PROCESS FOR LONG-TERM OPERATION OF A HETEROGENEOUSLY CATALYZED PARTIAL GAS PHASE OXIDATION OF AN ORGANIC STARTING COMPOUND 5 ABSTRACT A PROCESS FOR THE LONG-TERM OPERATION OF A HETEROGENEOUSLY CATALYZED PARTIAL GAS PHASE OXIDATION OF AN ORGANIC STARTING COMPOUND, IN WHICH THE REACTION GAS INPUT MIXTURE IS PARTIALLY OXIDIZED OVER A FIXED CATALYST BED WHICH IS ACCOMMODATED IN TWO SUCCESSIVE 1 0 TEMPERATURE ZONES A, B WHOSE TEMPERATURE IS CHANGED WITH INCREASING OPERATING TIME SUCH THAT THE INITIALLY LOWER TEMPERATURE INCREASES AND THE DIFFERENCE BETWEEN THE TWO TEMPERATURES DECREASES.
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公开(公告)号：BRPI0812874A2
公开(公告)日：2014-12-09
申请号：BRPI0812874
申请日：2008-06-12
Applicant: BASF SE
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Patent Agency Ranking
公开(公告)号：BRPI0812290A2
公开(公告)日：2014-11-25
申请号：BRPI0812290
申请日：2008-05-30
Applicant: BASF SE
Inventor： SCHLIEPHAKE VOLKER , BOTT KLAUS , BECHER ROLF-DIETER , MUELLER-ENGEL KLAUS JOACHIM , PETZOLDT JOCHEN , CREMER ULRICH , RAICHLE ANDREAS
IPC: B01J8/06
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公开(公告)号：DE502006004343D1
公开(公告)日：2009-09-03
申请号：DE502006004343
申请日：2006-12-21
Applicant: BASF SE
Inventor： CREMER ULRICH , WEGERLE ULRIKE , LAQUA GERHARD , HAMMON ULRICH , MUELLER-ENGEL KLAUS JOACHIM
Abstract: Heterogeneously catalyzed gas phase partial oxidation of organic compound with oxygen over fixed catalyst bed involves: recovering quality of the fixed catalyst bed by not replacing entire fixed catalyst bed but only its portion by a replacement fixed catalyst bed part; when increasing operating time is accompanied by increasing reduction in quality of the fixed catalyst bed, such that volume-specific activity of the replacement fixed catalyst bed part is lower than volume-specific activity of replaced fixed catalyst bed part in its freshly installed state. Method for heterogeneously catalyzed gas phase partial oxidation of at least one organic starting compound with molecular oxygen over a fixed catalyst bed freshly installed into a reaction chamber, involving conducting a reaction gas mixture comprising the at least one organic starting compound and the molecular oxygen through the fixed catalyst bed, for partial oxidation; and removing the heat of reaction by indirect heat exchange with a fluid heat carrier conducted outside the reaction chamber, involves: recovering the quality of the fixed catalyst bed by not replacing the entire fixed catalyst bed but only its portion by a replacement fixed catalyst bed part; when increasing operating time is accompanied by an increasing reduction in the quality of the fixed catalyst bed, such that the volume-specific activity of the replacement fixed catalyst bed part is lower than the volume-specific activity of the replaced fixed catalyst bed part in its freshly installed state.
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公开(公告)号：DE102007028332A1
公开(公告)日：2008-12-18
申请号：DE102007028332
申请日：2007-06-15
Applicant: BASF SE
Inventor： RAICHLE ANDREAS , BORCHERT HOLGER , MUELLER-ENGEL KLAUS-JOACHIM , WILMER HAGEN , DOBNER CORNELIA , CREMER ULRICH
Abstract: A process for charging a reactor with a fixed catalyst bed which comprises at least one annular shaped support catalyst body K, in which, before the charging, fragments formed in the preparation of the shaped catalyst bodies K are removed by screening.
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公开(公告)号：DE102007025869A1
公开(公告)日：2008-07-03
申请号：DE102007025869
申请日：2007-06-01
Applicant: BASF SE
Inventor： SCHLIEPHAKE VOLKER , BOTT KLAUS , BECHER ROLF-DIETER , MUELLER-ENGEL KLAUS JOACHIM , PETZOLDT JOCHEN , CREMER ULRICH , RAICHLE ANDREAS
IPC: B01J8/06
Abstract: Following a prior reaction in the tube bundle reactor, and between extraction and re-charging, the solid layer of molybdenum oxide or and/or molybdenum oxide hydrates deposited on the insides of the reactor tubes, is brushed away. Cylindrical, especially spirally-configured tube brushes are used. The coating is brushed away immediately on its formation. The preceding process is one of heterogeneous catalysis promoting partial gas phase oxidation. Examples of prior reactions carried out, include conversion of: propylene to acrolein and/or acrylic acid, acrolein to acrylic acid, iso-butene to methacrolein and/or methacrylic acid, methacrolein to methacrylic acid, propane to acrolein and/or acrylic acid, iso-butane to methacrolein and/or methacrylic acid, propylene to acrylonitrile, propane to acrylonitrile, isobutene to methacrylonitrile, isobutane to methacrylonitrile, C 4-hydrocarbon(s) to maleic acid anhydride or methanol to formaldehyde. The after-care or servicing described, complements use of a multi-element, formed oxide catalyst, containing molybdenum oxide in its active mass. The product gas contains steam.
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公开(公告)号：BR112012013208A2
公开(公告)日：2016-03-01
申请号：BR112012013208
申请日：2010-12-03
Applicant: BASF SE
Inventor： GITTER MARKUS , HUBER SABINE , CREMER ULRICH
IPC: C07C45/00 , C07C47/06 , C07C51/235 , C07C53/08
Abstract: processo para a preparação de ácido acético. a invenção expõe um método para a produção de acetaldeído e/ou ácido acético, de acordo com cujo método, um fluxo gasoso, contendo oxigênio molecular, etanol e pelo menos uma impureza, selecionada a partir de compostos de enxofre, é colocado em contato, em alta temperatura, com um catalisador de oxidação resistente a enxofre. o etanol é, de um modo preferido, obtido a partir de uma biomassa. o referido catalisador de oxidação resistente a enxofre compreende, por exemplo, o óxido de vanádio e pelo menos um óxido de zircônio, titânio e alumínio. em uma modalidade, o fluxo gasoso é convertido, no catalisador de oxidação resistente a enxofre, a uma primeira mistura de oxidação, o acetaldeído sendo o produto de oxidação predominante, e a referida primeira mistura de oxidação sendo convertida em um outro calatalisador de oxidação, a uma segunda mistura de oxidação, ácido acético sendo o produto de oxidação predominante. o referido outro catalisador de oxidação compreende, por exemplo, um óxido multimetálico contendo, pelo menos, molibdênio e vanádio.
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