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    BIMETAL-EXCHANGED ZEOLITE BETA FROM ORGANOTEMPLATE-FREE SYNTHESIS AND USE THEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOX
    22.
    发明申请
    BIMETAL-EXCHANGED ZEOLITE BETA FROM ORGANOTEMPLATE-FREE SYNTHESIS AND USE THEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOX 审中-公开
    无机合成的双官能交换沸石和在选择性催化还原NOX中的用途

    公开(公告)号：WO2015101930A1

    公开(公告)日：2015-07-09

    申请号：PCT/IB2014/067413

    申请日：2014-12-30

    Applicant: BASF SE ,  TOKYO INSTITUTE OF TECHNOLOGY ,  BASF (CHINA) COMPANY LIMITED

    Inventor： FEYEN, Mathias ,  MAURER, Stefan ,  MÜLLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  XIAO, Feng-Shou ,  TOSHIYUKI, Yokoi ,  YILMAZ, Bilge

    IPC: C01B39/00 ,  B01J29/00

    CPC classification number: B01D53/9418 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/502 ,  B01J29/7615 ,  B01J37/0203 ,  B01J37/04 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/34 ,  C01B39/026 ,  C01B39/46

    Abstract: The present invention relates to a process for the production of a zeolitic material having a BEA-type framework structure comprising YO 2 and X2O 3 , wherein said process comprises the steps of (1)preparing a mixture comprising one or more sources for YO 2 and one or more sources for X 2 O 3 ; (2)crystallizing the mixture obtained in step (1); (3)subjecting the zeolitic material having a BEA-type framework structure obtained in step (2) to an ion-exchange procedure with Cu; and (4) subjecting the Cu ion-exchanged zeolitic material obtained in step (3) to an ion-exchange procedure with Fe; wherein Y is a tetravalent element, and X is a trivalent element, wherein the mixture provided in step (1) and crystallized in step (2) further comprises seed crystals comprising one or more zeolitic materials having a BEA-type framework structure, and wherein the mixture provided in step (1) and crystallized in step (2) does not contain an organotemplate as a structure-directing agent, as well as to the zeolitic material having a BEA framework structure per se, and to its use, in particular in a method for the treatment of NO x by selective catalytic reduction (SCR).

    Abstract translation: 本发明涉及生产具有包含YO 2和X 2 O 3的BEA型骨架结构的沸石材料的方法，其中所述方法包括以下步骤：（1）制备包含一种或多种YO 2和一种或多种源的混合物 X2O3的来源; （2）使步骤（1）中获得的混合物结晶; （3）将具有步骤（2）中获得的BEA型骨架结构的沸石材料与Cu进行离子交换程序; 和（4）使步骤（3）中获得的Cu离子交换的沸石材料与Fe的离子交换程序; 其中Y是四价元素，X是三价元素，其中在步骤（1）中提供并在步骤（2）中结晶的混合物还包含包含一种或多种具有BEA型骨架结构的沸石材料的晶种，其中 步骤（1）中提供并在步骤（2）中结晶的混合物不含作为结构导向剂的有机模板，以及本身具有BEA骨架结构的沸石材料，特别是其用途 通过选择性催化还原（SCR）处理NOx的方法。

    POWDER OR GRANULATE FOR A ZEOLITIC MATERIAL AND PROCESS FOR ITS PRODUCTION
    24.
    发明申请
    POWDER OR GRANULATE FOR A ZEOLITIC MATERIAL AND PROCESS FOR ITS PRODUCTION 审中-公开
    粉末或粉碎用于其生物材料及其生产工艺

    公开(公告)号：WO2015059175A1

    公开(公告)日：2015-04-30

    申请号：PCT/EP2014/072614

    申请日：2014-10-22

    Applicant: BASF SE

    Inventor： FEYEN, Mathias ,  SCHAACK,, Bernd-bastian ,  MÜLLER, Ulrich ,  HEIDEMANN, Thomas

    IPC: B01J29/40 ,  B01J37/00

    CPC classification number: B01J37/0045 ,  B01J29/40

    Abstract: A process for the production of a powder or granulate, comprising (I) providing a zeolitic material; (II) suspending the zeolitic material provided in step (I) in a solvent system; (III) mixing the suspension obtained in step (II) with one or more binders; (IV) drying the suspension obtained in step (III); and (V) calcining of the dried material obtained in step (IV); wherein the zeolitic material provided in step (I) has an MFI-type framework structure comprising YO 2 and optionally comprising X 2 O 3 , wherein Y is a tetravalent element, and X is a trivalent element, said material having an X-ray diffraction pattern comprising at least the following reflections: (I) wherein 100% relates to the intensity of the maximum peak in the X-ray powder diffraction pattern, as well as to a powder or granulate per se and to its use.

    Abstract translation: 一种制备粉末或颗粒的方法，包括（I）提供沸石材料; （II）将在步骤（I）中提供的沸石材料悬浮在溶剂体系中; （III）将步骤（II）中获得的悬浮液与一种或多种粘合剂混合; （IV）干燥步骤（III）中获得的悬浮液; 和（V）煅烧步骤（IV）中获得的干燥材料; 其中步骤（I）中提供的沸石材料具有包含YO 2和任选地包含X 2 O 3的MFI型框架结构，其中Y是四价元素，X是三价元素，所述材料具有至少包含X射线衍射图 以下反射：（I）其中100％涉及X射线粉末衍射图中的最大峰的强度，以及粉末或颗粒本身及其用途。

    PROCESS FOR THE PREPARATION OF BUTADIENE
    26.
    发明申请
    PROCESS FOR THE PREPARATION OF BUTADIENE 审中-公开
    制备丁二烯的方法

    公开(公告)号：WO2014198901A1

    公开(公告)日：2014-12-18

    申请号：PCT/EP2014/062391

    申请日：2014-06-13

    Applicant: BASF SE

    Inventor： SPANNHOFF, Kirsten ,  PARVULESCU, Andrei-Nicolae ,  LANGE DE OLIVEIRA, Armin ,  MARX, Stefan ,  FEYEN, Mathias ,  MÜLLER, Ulrich ,  SCHWAB, Ekkehard

    IPC: B01J29/89 ,  B01J37/00 ,  C07C1/20 ,  C07C11/167

    CPC classification number: C07C1/20 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/37 ,  B01J2229/62 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01P2006/12 ,  C07C1/2076 ,  C07C2529/70 ,  C07C2529/78 ,  C07C2529/86 ,  C07C2529/89 ,  C07C11/167

    Abstract: The present invention relates to a gas-phase process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 comprising ethanol with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene, wherein the catalyst comprises a zeolitic material having a framework structure comprising YO 2 , Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, as well as to a zeolitic material having a framework structure comprising YO 2 , Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, wherein the zeolitic material displays a specific X-ray powder diffraction pattern, and to its use.

    Abstract translation: 本发明涉及用于制备丁二烯的气相方法，其包括（i）提供包含乙醇的气流G-1; （ii）使包含乙醇的气流G-1与催化剂接触，从而获得包含丁二烯的气流G-2，其中所述催化剂包含具有包含YO 2，Y代表一种或多种四价元素的骨架结构的沸石材料， 其中包含在骨架结构中的Y的至少一部分被一种或多种元素X同晶取代，以及具有包含Y 2 O，Y代表一种或多种四价元素的骨架结构的沸石材料，其中至少一部分 包含在骨架结构中的Y由一种或多种元素X同晶取代，其中沸石材料显示特定的X射线粉末衍射图案及其用途。

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