PROCESS FOR PREPARING ANTHRANILAMIDE ESTERS AND DERIVATIVES
    23.
    发明申请
    PROCESS FOR PREPARING ANTHRANILAMIDE ESTERS AND DERIVATIVES 审中-公开
    制备茴香酰胺和衍生物的方法

    公开(公告)号:WO2015162260A1

    公开(公告)日:2015-10-29

    申请号:PCT/EP2015/058943

    申请日:2015-04-24

    Applicant: BASF SE

    CPC classification number: C07D401/04

    Abstract: The present invention relates to a process for preparing N-pyridylpyrazole carboxanilides carrying a sulfiminocarbonyl group in the ortho position with respect to the amide group, which are represented by formula (I), the process comprising reacting a N-pyridylpyrazole carbooxanilide precursor of formula (II) or (II*) with a sulfimine of formula (III) or a salt thereof. Moreover, the present invention relates to a process for preparing N-pyridylpyrazole carbooxanilide precursors of formula (II) by reacting a compound of formula (IV) with a compound of formula (V). Furthermore, the present invention relates to N-pyridylpyrazole carbooxanilide precursors of formulae (II.A'), (II*.A'), (II.A'') and (II*.A'').

    Abstract translation: 本发明涉及一种在式(I)表示的相对于酰胺基的邻位上制备载有亚硫酰亚氨基羰基的N-吡啶基吡唑羧酰苯胺的方法,该方法包括使式(I)的N-吡啶基吡唑羧酰苯胺前体 II)或(II *)与式(III)的亚磺酸或其盐反应。 此外,本发明涉及式(Ⅳ)化合物与式(Ⅴ)化合物反应制备式(Ⅳ)的N-吡啶基吡唑酰苯胺前体的方法。 此外,本发明涉及式(II.A'),(II * .A'),(II.A“)和(II * .A”)的N-吡啶基吡唑碳酰苯胺前体。

    PROCESS FOR PREPARING PYRIDYLPYRAZOLE COMPOUNDS AND DERIVATIVES THEREOF FROM PYRIDYLHYDRAZINE
    24.
    发明申请
    PROCESS FOR PREPARING PYRIDYLPYRAZOLE COMPOUNDS AND DERIVATIVES THEREOF FROM PYRIDYLHYDRAZINE 审中-公开
    吡啶并吡唑化合物的制备方法及其衍生物及其衍生物

    公开(公告)号:WO2014202599A1

    公开(公告)日:2014-12-24

    申请号:PCT/EP2014/062709

    申请日:2014-06-17

    Applicant: BASF SE

    CPC classification number: C07D401/04 Y02P20/582

    Abstract: The present invention relates to a process for preparing pyndylpyrazole compounds of the formula (I) starting from pyridylhydrazine of formula (II) The present invention relates also to processes comprising further preceding and/or subsequent reaction steps, leading to anthranilamide pesticides or to precursors for them.

    Abstract translation: 本发明涉及从式(II)的吡啶基肼制备式(I)的吡啶基吡啶化合物的方法。本发明还涉及包含进一步的前述和/或后续反应步骤的方法,其导致邻氨基苯甲酰胺农药或前体 他们。

    PRODUCTION OF PYRIPYROPENES FROM DRY BIOMASS
    25.
    发明申请
    PRODUCTION OF PYRIPYROPENES FROM DRY BIOMASS 审中-公开
    从干生物量生产吡啶酮

    公开(公告)号:WO2014155214A1

    公开(公告)日:2014-10-02

    申请号:PCT/IB2014/059381

    申请日:2014-03-03

    CPC classification number: C07D493/04 A01N43/40 C12P17/181

    Abstract: The invention pertains to processes to produce dry biomass of pyripyropene producer organisms, processes to obtain pyripyropenes from such dry biomass, as well as to processes to produce compounds of Formula (III) and/or Formula (IV) and/or Formula (V) from the pyripyropenes obtained from the dry biomass. The invention does further pertain to the dry biomass itself, as well as processes using said dry biomass to obtain pyripyropenes for the production of compounds of Formula (III) and/or Formula (IV) and/or Formula (V), including processes using said dry biomass to obtain pyripyropenes or compounds of Formula III and/or Formula (IV) and/or Formula (V) in order to produce pest control compositions, in particular insecticides, comprising such compounds.

    Abstract translation: 本发明涉及产生拟南芥生产生物体的干生物质的方法,从这种干生物质获得拟南芥的方法,以及产生式(Ⅲ)和/或式(Ⅳ)和/或式(Ⅴ)化合物的方法, 来自干生物质获得的吡柔比星。 本发明进一步涉及干生物质本身,以及使用所述干生物质获得用于生产式(III)和/或式(IV)和/或式(V)的化合物的吡啶并苯的方法,包括使用 所述干燥生物质以获得拟南芥或式III化合物和/或式(Ⅳ)和/或式(Ⅴ)化合物,以便制备包含这些化合物的害虫控制组合物,特别是杀虫剂。

    VERFAHREN ZUR HERSTELLUNG VON 1,3,4-SUBSTITUIERTEN PYRAZOLVERBINDUNGEN

    公开(公告)号:WO2009135808A3

    公开(公告)日:2009-11-12

    申请号:PCT/EP2009/055328

    申请日:2009-05-04

    Abstract: Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von 1,3-substituierten Pyrazolverbindungen der Formel (I), worin X insbesondere für eine Gruppe CX 1 X 2 X 3 steht, worin X 1 , X 2 und X 3 unabhängig voneinander insbesondere für Wasserstoff, Fluor oder Chlor stehen, R 1 für C 1 -C 4 -Alkyl oder Cyclopropyl steht, und R 2 für Wasserstoff, CN oder eine Gruppe CO 2 R 2a steht, worin R 2a für insbesondere für C 1 -C 6 -Alkyl steht, umfassend die folgenden Schritte: i) Umsetzung eine Verbindung der Formel Il mit einem Hydrazon der Formel (III), wobei in Formel (Il) die Variablen X und R 2 die für Formel (I) angegebenen Bedeutungen aufweisen, Y für Sauerstoff, eine Gruppe NR y1 oder eine Gruppe [NR y2 R y3 ] + Z - steht, R 3 für OR 3a oder eine Gruppe NR 3b R 3c steht, und wobei in Formel (III) die Variable R 1 die für Formel (I) angegebenen Bedeutungen aufweist, R 4 und R 5 unabhängig voneinander für Wasserstoff, C 1 -C 6 -Alkyl, gegebenenfalls substituiertes Phenyl stehen, wobei wenigstens einer der Reste R 4 oder R 5 von Wasserstoff verschieden ist und wobei R 4 und R 5 gemeinsam mit dem Kohlenstoffatom, an das sie gebunden sind, auch für einen 5 bis 10-gliedrigen gesättigten Carbocyclus stehen können; Behandlung des dabei erhaltenen Reaktionsprodukts mit einer Säure in Gegenwart von Wasser.

    AZOLIN-2-YLAMINO COMPOUNDS FOR COMBATING ANIMAL PESTS
    28.
    发明申请
    AZOLIN-2-YLAMINO COMPOUNDS FOR COMBATING ANIMAL PESTS 审中-公开
    用于组合动物饲料的AZOLIN-2-YLAMINO化合物

    公开(公告)号:WO2009115491A1

    公开(公告)日:2009-09-24

    申请号:PCT/EP2009/053079

    申请日:2009-03-16

    Abstract: The present invention relates to azolin-2-ylamino compounds of formulae (I) and (II), wherein n is 0 to 3; Ar is phenyl; A is a radical of formulae A 1 or A 2 , wherein * indicates the point of attachment; X is S, O or N(R 10 ); R 7a-d are H, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylamino or C 3 -C 6 -cycloalkyl; R 8-10 are H, CN, NO 2 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, Ar 3 , -B-C(=O)R a , -B-C(=S)R a , -B-C(=NR f )R a , etc., wherein B is a single bond or C 1 -C 4 -alkanediyl; R 1 is H, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, phenyl or benzyl; R 2,3 are H, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, phenyl or benzyl; R 4 is H, halogen, CN, N 3 , NO 2 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, a heterocycle, Ar 5 , -C(=O)R a, -C(=S)R a , -C(=NR f )R a , etc.; or R 4 and R 5 together form a carbocycle or heterocycle; R 5,6 are H, halogen, CN, N 3 , NO 2 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, heterocycle, Ar 8 , -C(=O)R a , -C(=S)R a , -C(=NR f )R a , etc.; or R 5 and R 6 together form a carbocycle or heterocycle; R a-h are H, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, heterocycles or Ar 10 ; Ar 1 to 11 are phenyl, naphthyl or heteroaryl; and A' is a radical of formula A 3 , wherein W is halogen or OR 11 ; R 11 is H or -C(=O)-R i ; R i is H, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C3-C8-cycloalkyl, heterocycle or Ar 12 ; and Ar 12 is phenyl, naphthyl or heteroaryl; as well as to agricultural composition containing such compounds, the use of such compounds for controlling animal pests, seed, comprising such compounds, a method for controlling animal pests and a method for treating or protecting an animal from infestation or infection by parasites.

    Abstract translation: 本发明涉及式(I)和(II)的唑啉-2-基氨基化合物,其中n为0至3; Ar是苯基; A是式A1或A2的基团,其中*表示连接点; X是S,O或N(R10); R7a-d为H,卤素,C1-C6-烷基,C1-C6-烷氧基,C1-C6-烷基氨基或C3-C6-环烷基; R8-10是H,CN,NO2,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C8-环烷基,Ar3,-BC(= O)Ra,-BC(= S) Ra,-BC(= NRf)Ra等,其中B为单键或C1-C4-烷二基; R1是H,卤素,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C6-环烷基,苯基或苄基; R2,3是H,卤素,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C6-环烷基,苯基或苄基; R4是H,卤素,CN,N3,NO2,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C8-环烷基,杂环,Ar5,-C(= O) C(= S)Ra,-C(= NRf)Ra等; 或R4和R5一起形成碳环或杂环; R5,6是H,卤素,CN,N3,NO2,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C8-环烷基,杂环,Ar8,-C(= O) -C(= S)R a,-C(= NR f)R a等; 或R5和R6一起形成碳环或杂环; R h为H,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6炔基,C 3 -C 8 - 环烷基,杂环或Ar 10; Ar 1至11是苯基,萘基或杂芳基; 并且A'是式A3的基团,其中W是卤素或OR 11; R 11为H或-C(= O)-R i; R 1是H,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6炔基,C 3 -C 8环烷基,杂环或Ar 12; 和Ar 12是苯基,萘基或杂芳基; 以及含有这种化合物的农业组合物,这些化合物用于控制动物害虫,种子,包含这些化合物的用途,控制动物害虫的方法以及用于治疗或保护动物不受寄生虫感染或感染的方法。

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