公开(公告)号：AU746352B2

公开(公告)日：2002-04-18

申请号：AU5360998

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：PH11997058671B1

公开(公告)日：2000-12-04

申请号：PH11997058671

申请日：1997-11-28

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：MX9905080A

公开(公告)日：2000-04-30

申请号：MX9905080

申请日：1999-05-31

Applicant: CLOROX CO

Inventor： DELINE JAMES E ,  ZIELSKE ALFRED G ,  SUDBURY BARRY A ,  SMITH WILLIAM L ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  ALVAREZ VINCENT E ,  FOLAND LAFAYETTE D

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：CA2273089A1

公开(公告)日：1998-06-04

申请号：CA2273089

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： DELINE JAMES E ,  ZIELSKE ALFRED G ,  SUDBURY BARRY A ,  SMITH WILLIAM L ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  ALVAREZ VINCENT E ,  FOLAND LAFAYETTE D

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34 ,  C11D7/38

Abstract: The invention comprises heterocyclic cationic activators with the structure of Formula (I) that are capable of forming a peroxyimidic acid with a source of active oxygen in aqueous solution or being in a peroxyimidic form wherein A, R1, R2, R3, Y, and Z are as defined in the disclosure. The activators of Formula (I) are admixed with another compound selected from anionic species either capable of forming a peracid with a source of active oxygen in aqueous solution, or being in a peracid form, or a non-ionic polarizable activator and suitable counterion.

公开(公告)号：CA1240231A

公开(公告)日：1988-08-09

申请号：CA536542

申请日：1987-05-06

Applicant: CLOROX CO

Inventor： KAUFMANN EDWARD J ,  SUDBURY BARRY A

IPC: C11D17/04

Abstract: Conventional polyvinyl alcohol envelopes will not readily dissolve in wash water which has a significant borate concentration and a pH frequently encountered in wash liquors. Herein, such films are rendered sufficiently soluble in such solutions. In the preferred embodiment this is done by utilizing a polyvinyl alcohol film having an acid having an acid dissociation constant of 10-9M or larger or a polyvinyl alcohol film containing mixtures thereof with a polyvinyl alcohol having a number average molecular weight below about 50,000.

公开(公告)号：CA1230795A

公开(公告)日：1987-12-29

申请号：CA414399

申请日：1982-10-28

Applicant: CLOROX CO

Inventor： KAUFMANN EDWARD J ,  SUDBURY BARRY A

IPC: C08L29/00 ,  C08J5/18 ,  C08J11/00 ,  C08K5/05 ,  C08L29/04 ,  C08L33/00 ,  C08L33/02 ,  C11D3/37 ,  C11D17/04

Abstract: Borate Solution Soluble Polyvinyl Alcohol Films Conventional polyvinyl alcohol envelopes will not readily dissolve in wash water which has a significant borate concentration and a pH frequently encountered in wash liquors. Herein, such films are rendered sufficiently soluble in such solutions. In the preferred embodiment this is done by utilizing a polyvinyl alcohol film wherein at least a portion of the polyvinyl alcohol has a number average molecular weight below about 50,000, or a polyvinyl alcohol film containing a polyhydroxy compound having a binding constant with borate of at least about 800M-2, or utilizing a polyvinyl alcohol film having an acid having an acid dissociation constant of 10-9M or larger; or a polyvinyl alcohol film containing mixtures thereof.