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公开(公告)号:ZA9710682B
公开(公告)日:1998-07-17
申请号:ZA9710682
申请日:1997-11-27
Applicant: CLOROX CO
Inventor: ALVAREZ VINCENT E , DELINE JAMES E , FOLAND LAFAYETTE D , KAARET THOMAS W , PETRIN MICHAEL J , SMITH WILLIAM L , SUDBURY BARRY A , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C11D , C07D
Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.
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公开(公告)号:MX9905080A
公开(公告)日:2000-04-30
申请号:MX9905080
申请日:1999-05-31
Applicant: CLOROX CO
Inventor: DELINE JAMES E , ZIELSKE ALFRED G , SUDBURY BARRY A , SMITH WILLIAM L , KAARET THOMAS W , PETRIN MICHAEL J , ALVAREZ VINCENT E , FOLAND LAFAYETTE D
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06
Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.
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公开(公告)号:CA2273089A1
公开(公告)日:1998-06-04
申请号:CA2273089
申请日:1997-11-18
Applicant: CLOROX CO
Inventor: DELINE JAMES E , ZIELSKE ALFRED G , SUDBURY BARRY A , SMITH WILLIAM L , KAARET THOMAS W , PETRIN MICHAEL J , ALVAREZ VINCENT E , FOLAND LAFAYETTE D
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C01B3/00 , C07D265/12 , C07D211/26 , C07D211/34 , C11D7/38
Abstract: The invention comprises heterocyclic cationic activators with the structure of Formula (I) that are capable of forming a peroxyimidic acid with a source of active oxygen in aqueous solution or being in a peroxyimidic form wherein A, R1, R2, R3, Y, and Z are as defined in the disclosure. The activators of Formula (I) are admixed with another compound selected from anionic species either capable of forming a peracid with a source of active oxygen in aqueous solution, or being in a peracid form, or a non-ionic polarizable activator and suitable counterion.
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公开(公告)号:MX217641B
公开(公告)日:2003-11-18
申请号:MX9905080
申请日:1999-05-31
Applicant: CLOROX CO
Inventor: DELINE JAMES E , ZIELSKE ALFRED G , SUDBURY BARRY A , SMITH WILLIAM L , KAARET THOMAS W , PETRIN MICHAEL J , ALVAREZ VINCENT E , FOLAND LAFAYETTE D
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06
Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.
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公开(公告)号:CA1112814A
公开(公告)日:1981-11-24
申请号:CA319866
申请日:1979-01-18
Applicant: CLOROX CO
Inventor: ALVAREZ VINCENT E , MADDOX LODRIC L
Abstract: An aqueous bleaching composition having a pH from about 11 to 14, comprising an alkali metal hypochlorite, an alkali metal orthophosphate buffer, and an alkali metal pyrophosphate builder. The buffer increases the stability of the hypochlorite formulation to be comparable to a nonbuilt composition of equal hypochlorite content despite the solution's increased ionic strength. The builder significantly aids in soil removal during laundering operations.
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公开(公告)号:DE2904954A1
公开(公告)日:1979-08-16
申请号:DE2904954
申请日:1979-02-02
Applicant: CLOROX CO
Inventor: ALVAREZ VINCENT E , MADDOX LODRIC L
Abstract: An aqueous bleaching composition having a pH from about 11 to 14, comprising an alkali metal hypochlorite, an alkali metal orthophosphate buffer, and an alkali metal pyrophosphate builder. The buffer increases the stability of the hypochlorite formulation to be comparable to a non-built composition of equal hypochlorite content despite the solution's increased ionic strength. The builder significantly aids in soil removal during laundering operations.
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公开(公告)号:AU750138B2
公开(公告)日:2002-07-11
申请号:AU5686998
申请日:1997-11-18
Applicant: CLOROX CO
Inventor: ALVAREZ VINCENT E , ARBOGAST JAMES W , DELINE JAMES E , FOLAND LAFAYETTE D , KAARET THOMAS W , KLOTTER KEVIN A , PETRIN MICHAEL J , SMITH WILLIAM L , ZIELSKE ALFRED G , MITCHELL JAMES D
IPC: C07D295/14 , C01B13/02 , C07D295/02 , C07D295/15 , C11D1/62 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/00 , D06L3/02 , H04B7/06 , C01B3/00 , C11D7/38 , C07D265/12 , C07D211/26 , C07D211/34
Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butyl morpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is contacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.
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公开(公告)号:CO5031309A1
公开(公告)日:2001-04-27
申请号:CO97069849
申请日:1997-11-28
Applicant: CLOROX CO
Inventor: ALVAREZ VINCENT E , DELINE JAMES E , LAFAYETTE D FOLAND , KAARET THOMAS W , PETRIN MICHAEL J , SMITH WILLIAM M , SUDBURY BARRY A , ZIELSKE ALFRED G
IPC: C07D295/14 , C07C255/03 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06
Abstract: Una composición útil en procesos blanqueadores, quecomprende:una especie catiónica heterocíclica que sea capaz ya sea de formar un ácido peroximidico con una fuente de oxígeno activo en una solución acuosa o encontrándose en una forma peroximídica; y una especie aniónica que sea capaz ya sea de formar un perácido con una fuente de oxígeno activa en una solución acuosa o encontrándose en forma perácida o en un activador no iónico polarizable y un contraíon apropiado.La composición de la reivindicación 1 en donde la especie catiónica heterocíclica es capaz de formar un ácido peroximidico que incluye un compuesto con la estructura de la fórmula I en donde A es un anillo saturado formado por una pluralidad de átomos adicionales al átomo N1 , el anillo saturado de átomos incluyendo por lo menos un átomo de carbón y por lo menos un átomo de O, S y N, el sustituyente R1 unido al átomo N1 , de la estructura de la fórmula I incluyendo, ya sea, (a) un alquil C1-24 o un alquil alcoxilado en donde el alcoxi es un C2-4 , (b) un cicloalquil C2-24 , (c) un alcaril C7-24 , (d) un alcoxi repetitivo o no repetitivo o un alcohol alcoxilado, en donde la unidad alcoxi es C2-4 , o (e) -CR2 R3 C N en donde R2 y R3 son cada uno H, un alquil C1-24 , un cicloalquil o un alcaril, o un alcoxi repetitivo o no repetitivo o un alcohol alcoxilado en donde unidades alcoxi son C2-4 , Z se encuentra entre el rango de 0 a 10 y en donde Y es un contraión.
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公开(公告)号:CA2273086A1
公开(公告)日:1998-06-04
申请号:CA2273086
申请日:1997-11-18
Applicant: CLOROX CO
Inventor: ALVAREZ VINCENT E , ARBOGAST JAMES W , PETRIN MICHAEL J , ZIELSKE ALFRED G , SMITH WILLIAM L , MITCHELL JAMES D , DELINE JAMES E , KAARET THOMAS W , KLOTTER KEVIN A , FOLAND LAFAYETTE D
IPC: C07D295/14 , C01B13/02 , C07D295/02 , C07D295/15 , C11D1/62 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/00 , D06L3/02 , H04B7/06 , C01B3/00 , C07D265/12 , C07D211/26 , C07D211/34 , C11D7/38
Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butylmorpholinium acetonitrile, Nhexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is coctacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.
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公开(公告)号:AU662004B2
公开(公告)日:1995-08-17
申请号:AU2107292
申请日:1992-08-14
Applicant: CLOROX CO
Inventor: MITCHELL JAMES D , ALVAREZ VINCENT E , CARTY DANIEL T , LATHAM JAMES R
Abstract: The invention provides a cleaning agent and method for removing stains from fabrics comprising a combination of dense gas, a source of hydrogen peroxide and an organic bleach activator therefor.
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