公开(公告)号：DK0421238T3

公开(公告)日：1997-06-16

申请号：DK90118375

申请日：1990-09-25

Applicant: HOECHST AG

Inventor： HOENEL MICHAEL DR ,  WALZ GERD DR ,  ZIEGLER PETER DR ,  KUBILLUS UWE DR

IPC: C08G59/50 ,  C08L63/00 ,  C08L101/00 ,  C09D5/02 ,  C09D7/12 ,  C09D5/44 ,  C09D163/00 ,  C09D201/00

Abstract: The invention relates to the use of crosslinked polymer microparticles having an average particle size of at most 5 mu m and a glass transition temperature (Tg) of at least +30 DEG C. in aqueous paint preparations as filler and/or as partial substitute of white pigments, in particular of titanium dioxide. Among other things, the corresponding paints show increased spreading power, less tendency for sedimentation and reduced crater formation.

公开(公告)号：DE4324801A1

公开(公告)日：1995-01-26

申请号：DE4324801

申请日：1993-07-23

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  BRINDOEPKE GERHARD DR ,  DOESSEL KARL-FRIEDRICH DR

IPC: C08F4/28 ,  C08F4/34 ,  C08F20/10 ,  C08F20/26 ,  C08F212/08 ,  C08F220/04 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C09D5/00 ,  C09D5/03 ,  C09D133/00 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D175/04 ,  C08F222/02

Abstract: Copolymers comprising from 5 to 50 % by weight of one or more glycidyl esters of saturated aliphatic C4-C30-monocarboxylic acids containing a tertiary or quaternary alpha -carbon atom and from 95 to 5 % by weight of at least two olefinically unsaturated, copolymerisable monomers, of which at least one contains at least one carboxyl group. The copolymers are characterised by an OH number of from 50 to 250 mg of KOH/g, a solution viscosity of from 15 to 2000 mPa s (50 % strength solution at 23 DEG C), a mean molecular weight (weight average Mw) of less than 8600 g/mol and a nonuniformity of less than 3.4. The copolymers according to the invention are particularly suitable as binder components for high-solids coating compositions.

公开(公告)号：DE4000748A1

公开(公告)日：1991-07-18

申请号：DE4000748

申请日：1990-01-12

Applicant: HOECHST AG

Inventor： SCHWAB MICHAEL DR ,  KUBILLUS UWE DR

IPC: B05D7/14 ,  C08G18/00 ,  C08G18/08 ,  C08G18/10 ,  C08G18/12 ,  C09D5/00 ,  C09D5/02 ,  C09D175/04

Abstract: An aqueous coating composition for the manufacture of primers or of filler coatings, which contains at least one water-dispersible binder resin, as well as crosslinking agents and, if appropriate, customary additives, characterised in that the water-dispersible binder resin is at least partly a polyurethane resin which contains components which are derived from (A) polyisocyanates, (B) polyols having an average molecular weight Mn of at least 400, (C) if appropriate low molecular weight polyols, (D) compounds which contain at least two groups which are reactive with isocyanate groups and at least one group capable of anion formation, (E) polyols which carry no further groups reactive with isocyanate groups, where these components (E) are each located on the chain end of the polyurethane resin, if appropriate (F) compounds which are monofunctional or contain active hydrogen of differing reactivity and are different from (E), where these components (F) are also located on the chain end of the polyurethane resin and, if appropriate (G) compounds which are different from (B), (C), (D), (E) and (F) and contain at least two groups reactive with NCO groups. The filler coatings obtainable therefrom are distinguished, inter alia, by improved resistance to flying stones at low temperatures and by good intermediate layer adhesion, while corresponding primers show improved protection against corrosion.

公开(公告)号：DE3919028A1

公开(公告)日：1990-12-13

申请号：DE3919028

申请日：1989-06-10

Applicant: HOECHST AG

Inventor： ESSER KLAUS ,  DUERR HELMUT DR ,  PLATH DIETER DR ,  SCHOEN MANFRED DR ,  KUBILLUS UWE DR

IPC: C09D7/12 ,  C09D7/80 ,  C09D201/00 ,  C09D201/06

Abstract: Coating compsn. contains (A) a film-forming resin, (B) a cellulose ester, (C) solvent, (D) metal pigment and opt. (E) crosslinkers and (F) further lacquer additives and of the type esp. to give a multi-layer coating with a base layer and opt. a clear topcoat. (i) the cellulose ester (B) has an acetyl content of 2-30 (pref. 2-5) wt.%, a butyryl content of 17-53 (pref. 47-53) wt.% and an average mol.wt. of at least 25000, pref. 30000-60000; and (ii) this cellulose ester is introduced into the coating compsn. in the form of a pasty, thixotropic pre-mix (e.g. with the crosslinkers). The solids content of the compsn. is pref. 15-30 wt.%. The cellulose ester pre-mix pref. contains a diluent which swells the cellulose ester, esp. an aromatic or aliphatic hydrocarbon or a higher alcohol. alcohol.

公开(公告)号：DE3733182A1

公开(公告)日：1989-04-20

申请号：DE3733182

申请日：1987-10-01

Applicant: HOECHST AG

Inventor： KUBILLUS UWE DR ,  BRINDOEPKE GERHARD DR ,  PLUM HELMUT DR

IPC: C07C69/34 ,  C07C67/00 ,  C07C231/00 ,  C07C231/02 ,  C07C231/12 ,  C07C233/04 ,  C07C233/09 ,  C07C233/18 ,  C07C233/20 ,  C07C233/36 ,  C07C233/38 ,  C07C235/80 ,  C07C253/00 ,  C07C255/17 ,  C07C255/18 ,  C08G59/40 ,  C08G63/91 ,  C08J3/24 ,  C08K3/16 ,  C08K5/07 ,  C08K5/10 ,  C08K5/20 ,  C08K5/29 ,  C08K5/32 ,  C08L63/10 ,  C09D7/12 ,  C09D163/10

Abstract: A curing agent (A) containing active CH groups is characterised in that it contains at least two groups of the formula (I) or structural units of the formula (I') or (I") in which A is X and Y are identical or different and are CO2R , CN, NO2, CONH2, CONR H or CONR R , where the radicals R may be identical or different and are hydrocarbon radicals, preferably alkyl radicals having 1 to 12 carbon atoms, which may also be interrupted by oxygen or an N-alkyl radical, with the proviso that only one of the two radicals X and Y may be an NO2 group; A' is X' and Y' are identical or different and are Curable mixtures of (A) and a Michael acceptor (B) and optionally diluents and conventional additives cure rapidly even at low temperatures and are particularly suitable for surface-coating compositions.

公开(公告)号：DK0635523T3

公开(公告)日：1998-10-26

申请号：DK94111031

申请日：1994-07-15

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  BRINDOEPKE GERHARD DR ,  DOESSEL KARL-FRIEDRICH DR

IPC: C08F4/28 ,  C08F4/34 ,  C08F20/10 ,  C08F20/26 ,  C08F212/08 ,  C08F220/04 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C09D5/00 ,  C09D5/03 ,  C09D133/00 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D175/04

Abstract: Copolymers comprising from 5 to 50 % by weight of one or more glycidyl esters of saturated aliphatic C4-C30-monocarboxylic acids containing a tertiary or quaternary alpha -carbon atom and from 95 to 5 % by weight of at least two olefinically unsaturated, copolymerisable monomers, of which at least one contains at least one carboxyl group. The copolymers are characterised by an OH number of from 50 to 250 mg of KOH/g, a solution viscosity of from 15 to 2000 mPa s (50 % strength solution at 23 DEG C), a mean molecular weight (weight average Mw) of less than 8600 g/mol and a nonuniformity of less than 3.4. The copolymers according to the invention are particularly suitable as binder components for high-solids coating compositions.

公开(公告)号：AT169644T

公开(公告)日：1998-08-15

申请号：AT94111031

申请日：1994-07-15

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  BRINDOEPKE GERHARD DR ,  DOESSEL KARL-FRIEDRICH DR

IPC: C08F4/28 ,  C08F4/34 ,  C08F20/10 ,  C08F20/26 ,  C08F212/08 ,  C08F220/04 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C09D5/00 ,  C09D5/03 ,  C09D133/00 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D175/04

Abstract: Copolymers comprising from 5 to 50 % by weight of one or more glycidyl esters of saturated aliphatic C4-C30-monocarboxylic acids containing a tertiary or quaternary alpha -carbon atom and from 95 to 5 % by weight of at least two olefinically unsaturated, copolymerisable monomers, of which at least one contains at least one carboxyl group. The copolymers are characterised by an OH number of from 50 to 250 mg of KOH/g, a solution viscosity of from 15 to 2000 mPa s (50 % strength solution at 23 DEG C), a mean molecular weight (weight average Mw) of less than 8600 g/mol and a nonuniformity of less than 3.4. The copolymers according to the invention are particularly suitable as binder components for high-solids coating compositions.

公开(公告)号：DE59405136D1

公开(公告)日：1998-03-05

申请号：DE59405136

申请日：1994-03-28

Applicant: HOECHST AG

Inventor： SCHMIDT HOLGER DR ,  BRUECK TANJA REGINA ,  KUBILLUS UWE DR ,  OSWALD HARALD ,  SCHAUB PETRA ,  TRAVERS-HEMMER ANDREA

IPC: B05D3/02 ,  C08F8/44 ,  C08F12/00 ,  C08F20/10 ,  C08F212/06 ,  C08F220/04 ,  C08F220/06 ,  C08F220/18 ,  C08F220/28 ,  C08F220/32 ,  C08G59/02 ,  C08G59/32 ,  C08J3/07 ,  C08L61/28 ,  C09D5/00 ,  C09D125/00 ,  C09D125/02 ,  C09D125/14 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/10 ,  C09D133/14 ,  C09D161/20 ,  C09D161/28 ,  C09D163/00

Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg of KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization of a) from 5 to 40 parts by weight of at least one glycidyl ester of an aliphatic, saturated monocarboxylic acid which is branched in the alpha -position, b) from 0 to 30 parts by weight of at least one diester of an alpha , beta -olefinically unsaturated dicarboxylic acid, c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, where the molar amount of component c) is always greater than or equal to the molar amount of component b), d) from 0 to 60 parts by weight of an alkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, e) from 2 to 40 parts by weight of at least one alpha , beta -olefinically unsaturated carboxylic acid, where the molar amount of component e) is always greater than the molar amount of component a), f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, where the polymerisation is carried out in the presence or absence of solvents, optionally with addition of a water-dilutable solvent, neutralisation and dilution with water. These dispersions are suitable as water-dilutable binders for stoving (baking) varnishes or stoving solid-colour top coats.

公开(公告)号：DK0619329T3

公开(公告)日：1998-03-02

申请号：DK94104863

申请日：1994-03-28

Applicant: HOECHST AG

Inventor： KUBILLUS UWE DR ,  SCHMIDT HOLGER DR ,  BRUECK TANJA REGINA ,  OSWALD HARALD ,  SCHAUB PETRA ,  TRAVERS-HEMMER ANDREA

IPC: B05D3/02 ,  C08F8/44 ,  C08F12/00 ,  C08F20/10 ,  C08F212/06 ,  C08F220/04 ,  C08F220/06 ,  C08F220/18 ,  C08F220/28 ,  C08F220/32 ,  C08G59/02 ,  C08G59/32 ,  C08J3/07 ,  C08L61/28 ,  C09D5/00 ,  C09D125/00 ,  C09D125/02 ,  C09D125/14 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/10 ,  C09D133/14 ,  C09D161/20 ,  C09D161/28 ,  C09D163/00

Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg of KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization of a) from 5 to 40 parts by weight of at least one glycidyl ester of an aliphatic, saturated monocarboxylic acid which is branched in the alpha -position, b) from 0 to 30 parts by weight of at least one diester of an alpha , beta -olefinically unsaturated dicarboxylic acid, c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, where the molar amount of component c) is always greater than or equal to the molar amount of component b), d) from 0 to 60 parts by weight of an alkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, e) from 2 to 40 parts by weight of at least one alpha , beta -olefinically unsaturated carboxylic acid, where the molar amount of component e) is always greater than the molar amount of component a), f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, where the polymerisation is carried out in the presence or absence of solvents, optionally with addition of a water-dilutable solvent, neutralisation and dilution with water. These dispersions are suitable as water-dilutable binders for stoving (baking) varnishes or stoving solid-colour top coats.

公开(公告)号：AT162820T

公开(公告)日：1998-02-15

申请号：AT94104863

申请日：1994-03-28

Applicant: HOECHST AG

Inventor： SCHMIDT HOLGER DR ,  BRUECK TANJA REGINA ,  KUBILLUS UWE DR ,  OSWALD HARALD ,  SCHAUB PETRA ,  TRAVERS-HEMMER ANDREA

IPC: B05D3/02 ,  C08F8/44 ,  C08F12/00 ,  C08F20/10 ,  C08F212/06 ,  C08F220/04 ,  C08F220/06 ,  C08F220/18 ,  C08F220/28 ,  C08F220/32 ,  C08G59/02 ,  C08G59/32 ,  C08J3/07 ,  C08L61/28 ,  C09D5/00 ,  C09D125/00 ,  C09D125/02 ,  C09D125/14 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/10 ,  C09D133/14 ,  C09D161/20 ,  C09D161/28 ,  C09D163/00

Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg of KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization of a) from 5 to 40 parts by weight of at least one glycidyl ester of an aliphatic, saturated monocarboxylic acid which is branched in the alpha -position, b) from 0 to 30 parts by weight of at least one diester of an alpha , beta -olefinically unsaturated dicarboxylic acid, c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, where the molar amount of component c) is always greater than or equal to the molar amount of component b), d) from 0 to 60 parts by weight of an alkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, e) from 2 to 40 parts by weight of at least one alpha , beta -olefinically unsaturated carboxylic acid, where the molar amount of component e) is always greater than the molar amount of component a), f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an alpha , beta -olefinically unsaturated carboxylic acid, where the polymerisation is carried out in the presence or absence of solvents, optionally with addition of a water-dilutable solvent, neutralisation and dilution with water. These dispersions are suitable as water-dilutable binders for stoving (baking) varnishes or stoving solid-colour top coats.