公开(公告)号：BR9105578A

公开(公告)日：1992-09-01

申请号：BR9105578

申请日：1991-12-23

Applicant: STANDARD OIL CO OHIO

Inventor： LYNCH CHARLES STAFFORD ,  GLAESER LINDA CLAIRE ,  BRAZDIL JAMES FRANK ,  TOFT MARK ANTHONY

IPC: B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/34 ,  B01J23/843 ,  B01J23/847 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C253/24 ,  C07C255/08

Abstract: Disclosed is a process for making an activated antimony and vanadium-containing catalyst in oxide form having an atomic ratio of Sb:V in the range from 0.8-4, which comprises calcining such an oxidic vanadium and antimony-containing composition at a temperature of over 750 DEG C, and thereafter contacting said calcined catalyst with a hydroxy compound in liquid form selected from (1) cyclohexanol, (2) cyclopentanol, (3) a monohydroxy, acyclic hydrocarbon having 1-8 C atoms, and (4) a dihydroxy, acyclic hydrocarbon having 2-4 carbon atoms, and separating as a liquid said compound from said catalyst insofar as it is present beyond the amount wetting said catalyst, and thereafter drying said catalyst.

公开(公告)号：DE68902042D1

公开(公告)日：1992-08-13

申请号：DE68902042

申请日：1989-10-26

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  GLAESER LINDA CLAIRE ,  TOFT MARK ANTHONY

IPC: B01J23/22 ,  B01J27/08 ,  B01J35/08 ,  B01J37/04 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：BR8905787A

公开(公告)日：1990-06-12

申请号：BR8905787

申请日：1989-11-14

Applicant: STANDARD OIL CO OHIO

Inventor： TOFT MARK ANTHONY ,  BRAZDIL JAMES FRANK ,  GLAESER LINDA CLARE

IPC: B01J23/22 ,  B01J27/08 ,  B01J35/08 ,  B01J37/04 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08 ,  B01J37/02 ,  B01J23/16

公开(公告)号：SG76602A1

公开(公告)日：2000-11-21

申请号：SG1999001526

申请日：1999-03-03

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK JR ,  TOFT MARK ANTHONY

IPC: B01J23/00 ,  B01J23/28 ,  B01J23/88 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08

Abstract: A process of manufacturing acrylonitrile or methacrylonitrile by the catalytic reaction in the vapor phase of a paraffin selected from propane and isobutane with molecular oxygen and ammonia by catalytic contact of the reactants in a reaction zone with a catalyst, the feed composition having a mole ratio of the paraffin to ammonia in the range of from about 2.5 to 16 and a mole ratio of paraffin to oxygen in the range of from about 1.0 to 10, wherein said catalyst has the elements in the proportions indicated by the empirical formula: VSbmAaMobDdOx where A is one or more of Ti, Sn, Fe, Cr and Ga; D is one or more of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Nb, Zr, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B and Mn; m equals 0.8 to 4; a equals 0.01 to 2; 0

公开(公告)号：IN183836B

公开(公告)日：2000-04-29

申请号：IN783DE1992

申请日：1992-09-02

Applicant: STANDARD OIL CO

Inventor： TOFT MARK ANTHONY ,  BRAZDIL JAMES FRANK ,  GLAESER LINDA CLAIRE

IPC: B01J29/00

公开(公告)号：BR9901709A

公开(公告)日：2000-01-11

申请号：BR9901709

申请日：1999-03-24

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK JR ,  TOFT MARK ANTHONY

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/28 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08

Abstract: A process of manufacturing acrylonitrile or methacrylonitrile by the catalytic reaction in the vapor phase of a paraffin selected from propane and isobutane with molecular oxygen and ammonia by catalytic contact of the reactants in a reaction zone with a catalyst, the feed composition having a mole ratio of the paraffin to ammonia in the range of from about 2.5 to 16 and a mole ratio of paraffin to oxygen in the range of from about 1.0 to 10, wherein said catalyst has the elements in the proportions indicated by the empirical formula: VSbmAaMobDdOx where A is one or more of Ti, Sn, Fe, Cr and Ga; D is one or more of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Nb, Zr, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B and Mn; m equals 0.8 to 4; a equals 0.01 to 2; 0

公开(公告)号：DE3879253D1

公开(公告)日：1993-04-22

申请号：DE3879253

申请日：1988-04-14

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  TOFT MARK ANTHONY ,  GLAESER LINDA CLAIRE

IPC: B01J27/199 ,  B01J23/16 ,  B01J23/22 ,  B01J23/30 ,  B01J23/84 ,  B01J23/85 ,  B01J23/88 ,  B01J23/89 ,  B01J27/057 ,  B01J27/14 ,  B01J27/198 ,  B01J37/04 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C253/24 ,  C07C255/08

Abstract: Disclosed is ammoxidation of C3 to C5 acyclic alkanes with NH3 and O2 using (1) a mole ratio of paraffin:NH3 in the range from 2 to 16 and a mole ratio of alkane:O2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalyst compositions useful in the process are also disclosed.

公开(公告)号：ES2178350T3

公开(公告)日：2002-12-16

申请号：ES99302315

申请日：1999-03-25

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  TOFT MARK ANTHONY

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/28 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08

Abstract: A process of manufacturing acrylonitrile or methacrylonitrile by the catalytic reaction in the vapor phase of a paraffin selected from propane and isobutane with molecular oxygen and ammonia by catalytic contact of the reactants in a reaction zone with a catalyst, the feed composition having a mole ratio of the paraffin to ammonia in the range of from about 2.5 to 16 and a mole ratio of paraffin to oxygen in the range of from about 1.0 to 10, wherein said catalyst has the elements in the proportions indicated by the empirical formula: VSbmAaMobDdOx where A is one or more of Ti, Sn, Fe, Cr and Ga; D is one or more of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Nb, Zr, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B and Mn; m equals 0.8 to 4; a equals 0.01 to 2; 0

公开(公告)号：RO116273B1

公开(公告)日：2000-12-29

申请号：RO9900313

申请日：1999-03-23

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JR JAMES FRANK ,  TOFT MARK ANTHONY

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/28 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08

Abstract: The invention relates to a process for preparing acrylonitrile or methacrylonitrile by means of the catalytic reaction in a vapour phase of a paraffin hydrocarbon, chosen from propane and isobutane, with molecular oxygen and ammonia in a molar ratio paraffin hydrocarbon to ammonia of 2.5 to 16 and a molar ratio paraffin hydrocarbon to oxygen of 1.0 to 10, the catalyst composition corresponding to the following empirical formula : VSBmAaMobDdOx where A is an element selected from among Ti, Sn, Fe, Cr, or Ga; D represents one or more elements selected from among Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Nb, Zr, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B and Mn ; m is equal to 0.8 up to 4.0 ; a is equal to 0.01 up to 2.0 ; b is greater than 0 and greater than 0.005 ; d is equal to 0 up to 2.0 ; x has a value determined by the oxidation condition of the present cations, the catalyst being thermally treated at a temperature of at least 780 C degrees .

公开(公告)号：TR199900709A2

公开(公告)日：1999-10-21

申请号：TR9900709

申请日：1999-03-26

Applicant: STANDARD OIL CO

Inventor： JR JAMES FRANK BRAZDIL ,  TOFT MARK ANTHONY

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/28 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08

Abstract: A process of manufacturing acrylonitrile or methacrylonitrile by the catalytic reaction in the vapor phase of a paraffin selected from propane and isobutane with molecular oxygen and ammonia by catalytic contact of the reactants in a reaction zone with a catalyst, the feed composition having a mole ratio of the paraffin to ammonia in the range of from about 2.5 to 16 and a mole ratio of paraffin to oxygen in the range of from about 1.0 to 10, wherein said catalyst has the elements in the proportions indicated by the empirical formula: VSbmAaMobDdOx where A is one or more of Ti, Sn, Fe, Cr and Ga; D is one or more of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Nb, Zr, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B and Mn; m equals 0.8 to 4; a equals 0.01 to 2; 0