公开(公告)号：KR820002027B1

公开(公告)日：1982-10-25

申请号：KR790001899

申请日：1979-06-11

Applicant: STANDARD OIL CO OHIO

Inventor： TALSMA H ,  BOND T ,  FELDMAN D

IPC: C08F291/00 ,  C08J3/00

Abstract: The color and impact strength of nitrile polymers, prepared by polymn. of an olefinically unsatd. nitrile with a monovinyl monomer in the presence of a rubber, were improved by heating the polymer to a plastic state in the absence of O and in presence of an inert gas. Thus, an acrylonitrile-rubber-vinyl compd. latex, coagulated and formed into strands was pelletized by screw extrusion in the presence of CO2. The product had Izod impact strength 2.57kg/cm2, yellowness index 28.

公开(公告)号：KR810001559B1

公开(公告)日：1981-10-27

申请号：KR780002991

申请日：1978-09-30

Applicant: STANDARD OIL CO OHIO

Inventor： HSIANG LI GEORGE SU ,  JORKASKY R JR

IPC: C08F291/00

Abstract: The title polymers are prepd. from maleic anhydride(I), a cyclic olefin, styrene(II), and a preformed rubber. Thus, a mixt. of I 25, II 40, Bz2O2 0.4 and MeCOEt 75 parts was added over 6 hr at 75oC to mixt. of SBR 15, II 10, β-pinene 25, and MeCOEt 25 parts and heated an addnl. hr at 70oC, giving a polymer with heat-distortion temp. 166oC, fluexural strength 8.41x103 psi, notched lzod impact strength 1.76 ftlb/in. notch, and tensile strength 5.06x103 psi.

公开(公告)号：KR810001558B1

公开(公告)日：1981-10-27

申请号：KR770001213

申请日：1977-05-24

Applicant: STANDARD OIL CO OHIO

Inventor： MILLER A ,  ZAGATA R ,  GRASSELLI R

IPC: C07C69/54

Abstract: Acrylates and methacrylates were obtained by oxidative esterufucation of propylene or isobutylene (I) in the presence of O and C2H4 or an alc., in a single fluidized bed reactor contg. oxidn. catalysts at 200-600≦̸C. A reactor was charged with 80% 50:50 mixt. of Ni2.5Co4.5Fe3BiPO.5/0.5Mo12Ox and SiO2 and 20% 62:38 mixt. of V3W1.2Mo12Ox and SiO2.Air-I-MeOH(10:1:2) was fed to the reactor at 355oC and 1 atm. and after contact time 5 s the product yield was methyl methacrylate 30.0, I 53.0, acrolein 1.0, and methacrolein 2.0 mol. percent with a trace of methacrylic acid.

公开(公告)号：KR810000396B1

公开(公告)日：1981-04-27

申请号：KR770001149

申请日：1977-05-14

Applicant: STANDARD OIL CO OHIO

Inventor： MAZEKE H ,  COFFEY G

IPC: C08F220/42

Abstract: Acid-activated mercaptans are used as chain transfer agents in the copolymn. of acrylonitrile(I), giving high conversions to polymers with high nitrile content and good processability. Thus, 75 parts I and 25 parts Me acrylate were added to compn. contg. Na dioctyl sulfosuccinate 0.85, poly (vinylpyrrolidone) 0.30, water 205, nitrile rubber(added as latex) 9, and H3PO4 0.067 parts. The polymn. mixt. was heated to 54≦̸C, treated with 0.06 parts K2S2O8 and 1.2 parts pentaerythritol tetrakis(3-mercaptopropionate) and polymd. 3.5h, giving a polymer with av. mol. wt. 126,885 and Brabender torgue at 230≦̸ and 35 rpm 2/20m-g after 10 min

公开(公告)号：KR800000740B1

公开(公告)日：1980-08-02

申请号：KR800002487

申请日：1980-06-24

Applicant: STANDARD OIL CO OHIO

Inventor： TERRILL D ,  SHAW W ,  DOLHY S ,  MILBEYER E

IPC: B01J27/14

公开(公告)号：KR800000424B1

公开(公告)日：1980-05-26

申请号：KR750001572

申请日：1975-07-19

Applicant: STANDARD OIL CO OHIO

Inventor： HARDMAN H ,  GRASSELLI R ,  SURESH D

IPC: B01J21/02

Abstract: Oxidation catalyst, useful for oxidation reaction such as oxidation of olefine, dehydrogenation and oxidation of methyl substituted aromatic compd., was prepd. by composing in the compd.(I; X = Y,Xr,Ag,S,Ce,Th,Pr,Ru,Ga,Ta,La; A = alkali metal,Tl,or its mixture;D = Ni,Co,Mg,Ca,Sr,Zn,Cd,or its mixture; E = P,As,B,W,Sb or its mixture ; O

公开(公告)号：KR790001986B1

公开(公告)日：1979-12-30

申请号：KR750002252

申请日：1975-10-16

Applicant: STANDARD OIL CO OHIO

Inventor： LI G S ,  HENSLEY L W

IPC: C08F220/42

Abstract: Low creep. impact-resistant palymerizates of olefinic nitriles, useful as gas and vapor barriers, were prepd. by polymerizing an ester of an olefinically unsatd. acid (CH2 = CR1-COOR2; R1 = C1-4 alkyl group or halogen, R2 = C1-6 alkyl group) and indene in the presence of a rubber prepd. from a conjugated diene and an olefinically unsatd. nitrile (CH2 = CR-CN ; R4 = C1-4 lower alkyl or halogen group).

公开(公告)号：KR790001265B1

公开(公告)日：1979-09-20

申请号：KR740003996

申请日：1974-11-05

Applicant: STANDARD OIL CO OHIO

Inventor： SERGE ROMAN DOLHYI ,  ERNEST CARL MILBERGER

Abstract: Catalysts(I) for oxidn. of (meta)acrolein to (meta) acrylic acid at 200-500≦̸C with improved selectivity contain oxides or oxide complexes of Ce, W,V, Mo, and optionally, Fe, Co, Ni, Zr, Cu, Mg, Mn, Bi, Ti, Zr, Sn, P, transition, alkali, alk. earth, or lanthanide metals. I also was very useful for oxidn. of butadien to maleic anhydride and oxidn. esterification of usatd. aldehyde to corresponding unsatd. polyester.

公开(公告)号：KR790001048B1

公开(公告)日：1979-08-22

申请号：KR750002839

申请日：1975-12-26

Applicant: STANDARD OIL CO OHIO

Inventor： COFFEY G P ,  GEORGE SU-HSIANG LI

Abstract: Graft acrylonitrile-butadiene-indene polymer, having good impact resistance, low permeability to gases, and high softening temp., was prepd. by grafting acrylonitrile and indene on nitrile rubber. Thus, an aq. emulsion of acrylonitrile 70, indene 17.5 and rubber latex 15 parts was polymd. at 60≦̸C for 6hr using K2S2O8 as catalyst and limonene dimercaptane, and then the reaction mixt. was heated to 70≦̸C and K2S2O8 0.2, indene 12.5 and limonene dimercaptane 0.5 part were added over a period 5hr to give I.

公开(公告)号：KR790000826B1

公开(公告)日：1979-07-18

申请号：KR750001586

申请日：1975-07-21

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV D ,  HARDMAN H ,  GRASSELLI R K

Abstract: Unsatd. aldehydes and acids were obtained by oxidn. of olefins using the improved catalyst I (X = Ce, Th, Mn, Pr, Nb, Ge, Cr, Y, Zr, Ru, Ga, Sn, In, Cu, La, Ta, W or their mixt., A = alkali metal, Tl or their mixt, D = Ni, Co, Mg, Zn, Cd, Ca, Sr, or their mixt., E = P, As, B, S, Al, or their mixt. 0