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公开(公告)号:AT283877T
公开(公告)日:2004-12-15
申请号:AT98117893
申请日:1998-09-22
Applicant: BASF AG
Inventor: ROTERMUND UDO DR , HEINZ MARION , BIEDERMANN ANJA , HEMPEL RENATE E , WIEGMANN WERNER
IPC: C08J9/00 , C08G18/00 , C08G18/28 , C08G18/34 , C08G18/36 , C08G18/40 , C08G18/42 , C08G18/65 , C08G18/66 , C08G101/00 , C08J9/08 , C08J9/14 , C09K23/34
Abstract: Storage-stable emulsion, used in the manufacture of fine celled hard foamed materials, contains a polyester alcohol propellant of specified formula as emulsifier. Emulsion contains: (a) compounds containing hydrogen atoms reactive towards isocyanates; (b) a polyester alcohol propellant of formula (I) as emulsifier; and (c) usual polyurethane catalysts, auxiliary aids and/or additives. (b) is emulsified in components (b) and (c). m = 0-15; n = 0-1; o = 0-15; p = 0-1; q = 0-15; r = 0-1; s = 0-15; t = 0-1; u = 0-10; v = 0-15; x = 1-5; y = 1-4 or mixtures between 1-3 with r + n is not 0; R1 = aliphatic structure based on the structure of multivalent alcohols, preferably ethylene glycol, diethylene glycol, triethylene glycol 1,2-propylene glycol, and dipropylene glycol; 1,4-butane diol, 1,6-hexane diol, neopentyl glycol, 1,3-butane diol, trimethylol propane, trimethylol ethane, glycerin, pentaerythrite; R2 = polycarboxylic acid without COOH groups, e.g. adipic acid, terephthalic acid, or o-phthalic acid; and R3 = alcohol as in R1.
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公开(公告)号:DE10237914A1
公开(公告)日:2004-02-26
申请号:DE10237914
申请日:2002-08-14
Applicant: BASF AG
Inventor: DINSCH STEFAN , HEINZ MARION , WINKLER JUERGEN , ROTERMUND UDO , BIEDERMANN ANJA , KAMPF GUNNAR
Abstract: Process for preparation of polyetherols based on oligo- and/or polysaccharides as starter substances by catalyzed addition of alkylene oxides, where at least one solution or melt of costarter is used, the starter substance is taken up, and the starter mixture is alkoxylated in the melt is new. An Independent claim is included for a polyetherol based on oligo- or polysaccharide obtained as above.
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公开(公告)号:DE59808057D1
公开(公告)日:2003-05-28
申请号:DE59808057
申请日:1998-11-26
Applicant: BASF AG
Inventor: HEINZ MARION , HORN PETER DR , BIEDERMANN ANJA DR
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公开(公告)号:DE59901540D1
公开(公告)日:2002-07-04
申请号:DE59901540
申请日:1999-12-15
Applicant: BASF AG
Inventor: HEINZ MARION , BIEDERMANN DR , ROTERMUND DR , REICHELT MICHAEL , WIEGMANN WERNER
IPC: B29C44/00 , E04B1/80 , F16L59/065 , F25D23/06
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公开(公告)号:DE19742568A1
公开(公告)日:1999-04-01
申请号:DE19742568
申请日:1997-09-26
Applicant: BASF AG
Inventor: VOLKERT OTTO DR , ROTERMUND UDO DR , BIEDEMANN ANJA DR , HEINZ MARION
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公开(公告)号:DE19742011A1
公开(公告)日:1999-03-25
申请号:DE19742011
申请日:1997-09-24
Applicant: BASF AG
Inventor: ROTERMUND UDO DR , BIEDERMANN ANJA DR , HEMPEL RENATE , WIEGMANN WERNER , HEINZ MARION
IPC: C08J3/02 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/66 , C08G101/00 , C08J9/12 , C08J9/14 , C08L75/04 , C08L75/08 , C08G65/38
Abstract: Emulsions containing polyether alcohols are used in the production of hard foams based on isocyanates to improve the temperature stability of the foams. Storage-stable halogen-free emulsions used in the production of hard foams based on isocyanates contain: (a) compounds containing hydrogen atoms reactive towards isocyanate groups; (b) water; (c) halogen-free propellants; and optionally (d) usual auxiliary aids and/or additives. (a) is used in an amount of 0.2-80 wt.% and has a functionality of more than 1.5, and an OH number of 10-100 mg KOH/g. (c) consists of 3-10 C hydrocarbons. Independent claims are also included for: (1) the production of the hard foams described; (2) the foams, and (3) the use of the polyether alcohols described.
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公开(公告)号:CA2245009A1
公开(公告)日:1999-03-24
申请号:CA2245009
申请日:1998-09-23
Applicant: BASF AG
Inventor: WIEGMANN WERNER , ROTERMUND UDO , REICHELT MICHAEL , BIEDERMANN ANJA , HEINZ MARION
Abstract: In a process for producing open-celled rigid foams by reacting a) polyisocyanates with b) compounds containing hydrogen atoms which are reactive toward isocyanates, in the presence of c) water, d) if desired, organic compounds acting as physical blowing agents, e) catalysts, auxiliaries and/or additives, the compounds containing reactive hydrogen atoms used are substances having the structure I: where m is 0 - 15 n is 0 - 1 o is 0 - 15 p is 0 - 1 q is 0 - 15 r is 0 - 1 s is 0 - 15 t is 0 - 1 u is 0 - 10 v is 0 - 15 x is 1 - 5 y is 1 - 4 or mixtures of 1 - 3 where r + n ~ 0 z is 0 - 3 z i is 0.1 -3 R1 is an aliphatic structure without OH groups based on the structure of polyhydric alcohols, preferably ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol and dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, 1,3-butanediol, trimethylolpropane, trimethylolethane, glycerol, pentaerythritol, where these substances can also be used in the esterification as any mixture among one another and R1 can therefore also be a mixture of the corresponding structures, R2 is the radical of a polycarboxylic acid without COOH groups, eg. adipic acid, terephthalic acid, o-phthalic acid, R3 is an alcohol radical like R1.
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公开(公告)号:DE102004041125A1
公开(公告)日:2006-03-02
申请号:DE102004041125
申请日:2004-08-24
Applicant: BASF AG
Inventor: GUETTES BERND , WETTERLING MONIKA , IHLE THOMAS , HEINZ MARION , BOEHLER FRANK
Abstract: Preparation of flame-protected polyurethane (I) (preferably polyurethane-foam materials) comprises reaction of polyisocyanate with compounds with at least two hydrogen atoms reactive with isocyanate group, where the reaction is carried out in the presence of (a) foamed melamine formaldehyde condensation products and/or (b) hydroxyl groups containing reaction products of (a) with alkylene oxide. Independent claims are also included for: (1) a hydroxyl group containing compounds (II), producible by reaction of (a) with alkylene oxide; (2) a method for the preparation of (II) comprising reaction of (a) with alkylene oxide; and (3) a flame protected polyurethane, produced by the preparation method.
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公开(公告)号:ES2238742T3
公开(公告)日:2005-09-01
申请号:ES98117895
申请日:1998-09-22
Applicant: BASF AG
Inventor: ROTERMUND UDO DR , BIEDERMANN ANJA , HEMPEL RENATE , WIEGMANN WERNER , HEINZ MARION
IPC: C08J3/02 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/66 , C08G101/00 , C08J9/12 , C08J9/14 , C08L75/04
Abstract: EL OBJETO DE LA INVENCION SON EMULSIONES SIN HALOGENOS QUE CONTIENEN AGENTES POROGENOS QUE SON ESTABLES EN ALMACENAMIENTO PARA LA FABRICACION DE ESPUMAS DURAS A BASE DE ISOCIANATO QUE CONTIENEN A) COMPUESTOS QUE CONTIENEN ATOMOS DE HIDROGENO QUE SON REACTIVOS CON LOS GRUPOS ISOCIANATO, B) AGUA, C) AGENTES POROGENOS SIN HALOGENOS QUE ACTUAN FISICAMENTE, ASI COMO OPCIONALMENTE D) ADYUVANTES Y/O ADITIVOS USUALES EN LA QUIMICA DEL POLIURETANO, CARACTERIZADO PORQUE COMO COMPONENTE A) SE UTILIZAN POLIETERALCOHOLES CON UNA FUNCIONALIDAD MAYOR DE 1,5, UN INDICE DE HIDROXILO DE 10 A 100 MG DE KOH/G EN UNA CANTIDAD DE 0,2 % HASTA 80 % EN MASA, CON RELACION A LA MASA DEL COMPONENTE A), Y COMO ESPUMANTES QUE ACTUAN DE MANERA FISICA Y SIN HALOGENOS SE PUEDEN UTILIZAR C) HIDROCARBUROS CON 3 A 10 ATOMOS DE CARBONO.
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公开(公告)号:DE59812630D1
公开(公告)日:2005-04-14
申请号:DE59812630
申请日:1998-09-22
Applicant: BASF AG
Inventor: ROTERMUND DR , BIEDERMANN ANJA , HEMPEL RENATE , WIEGMANN WERNER , HEINZ MARION
IPC: C08J3/02 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/66 , C08G101/00 , C08J9/12 , C08J9/14 , C08L75/04
Abstract: Emulsions containing polyether alcohols are used in the production of hard foams based on isocyanates to improve the temperature stability of the foams. Storage-stable halogen-free emulsions used in the production of hard foams based on isocyanates contain: (a) compounds containing hydrogen atoms reactive towards isocyanate groups; (b) water; (c) halogen-free propellants; and optionally (d) usual auxiliary aids and/or additives. (a) is used in an amount of 0.2-80 wt.% and has a functionality of more than 1.5, and an OH number of 10-100 mg KOH/g. (c) consists of 3-10 C hydrocarbons. Independent claims are also included for: (1) the production of the hard foams described; (2) the foams, and (3) the use of the polyether alcohols described.
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