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公开(公告)号:DE102005054151A1
公开(公告)日:2007-05-16
申请号:DE102005054151
申请日:2005-11-14
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , HOFMANN JUERGEN , WASMER KARL-HEINZ , LOTH WOLFGANG , SCHIERHOLZ JENS-UWE , SCHMAUS PAULUS , MOURS MARIAN , SCHADE CHRISTIAN , ITTEMANN PETER , HEINEN HARTMUT , CZAUDERNA BERNHARD , SAUER MICHAEL , BARDON RAINER , KRUEGER MARCO
Abstract: The invention relates to a tube bundle heat exchanger (R) for removing dissolved substances from a polymer solution (P) by degassing, having a bundle of tubes (R) which are arranged parallel to one another and vertically and are fastened at both ends in each case in one tube plate (B), and having a degassing region below the lower tube plate (B), having an insert (1) in each tube (R), which insert (1) narrows the free throughflow cross section through the tube (R), and wherein the polymer solution (P) is supplied into the tubes (R) in a single-phase liquid state, and having a casing space around the tubes (R) which is traversed by a heat carrier, wherein the degassing takes place by means of a pressure drop between the inlet pressure of the polymer solution (P) in the tube bundle heat exchanger (R) and the degassing region, characterized in that each insert (1) is designed in such a way as to generate a pressure step between the inlet pressure and the pressure in the degassing region, by means of which pressure step a predefined low residual content of dissolved substances is obtained in the degassed polymer, and an additional heat input which is necessary for this purpose takes place via the heat carrier into the single-phase liquid polymer solution (P).
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公开(公告)号:DE102005027485A1
公开(公告)日:2006-12-28
申请号:DE102005027485
申请日:2005-06-14
Applicant: BASF AG
Inventor: WEBER MARTIN , MUEHLBACH KLAUS , ITTEMANN PETER , GRUTKE STEFAN , INCHAURRONDO NICOLAS
Abstract: Molding compositions comprising: a composition (I) present in an amount of 10 to 100% by weight, based on the molding composition, wherein the composition (I) comprises: (A) 40 to 95% by weight, based on the composition (I), of a copolymer comprising: α-methylstyrene in an amount of 55 to 90% by weight, acrylonitrile in an amount of 10 to 50% by weight, and one or more other monomers in an amount of 0 to 5% by weight, wherein the percentages by weight of the α-methylstyrene, the acrylonitrile and the one or more other monomers are based on the weight of component (A); (B) 2.5 to 75% by weight, based on the composition (I), of a polymer comprising: a vinylaromatic monomer in an amount of 60 to 90% by weight, acrylonitrile in an amount of 8.01 to 39.8% by weight, and maleic anhydride in an amount of 0.2 to 1.99% by weight, wherein the percentages by weight of the vinylaromatic monomer, the acrylonitrile and the maleic anhydride are based on the weight of component (B); and (C) 2.5 to 60% by weight, based on the composition (I), of glass fibers.
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公开(公告)号:DE102004059241A1
公开(公告)日:2006-06-14
申请号:DE102004059241
申请日:2004-12-08
Applicant: BASF AG
Inventor: WEBER MARTIN , RITTIG FRANK , HAENSEL WERNER , HECKMANN WALTER , HOENL HANS , ITTEMANN PETER , SAMPATH BANGARU
Abstract: The invention relates to thermoplastic molding compositions, comprising A) from 35 to 95% by weight of at least one graft copolymer A), which is obtainable via reaction of A1) from 5 to 95% by weight of a polymer A1), which is obtained from at least one dicarboxylic anhydride a11) and from at least one vinylaromatic comonomer a12), and A2) from 5 to 95% by weight of a polyamide A2), B) from 5 to 40% by weight of at least one ungrafted or grafted, non-particulate rubber without core-shell structure B), which has functional groups which can react with the end groups of component A), C) from 0 to 50% by weight of at least one particulate or fibrous filler or particulate or fibrous reinforcing material C), D) from 0 to 60% by weight of at least one copolymer D) composed of vinyl aromatic monomers d1) and of comonomers d2), and E) from 0 to 40% by weight of at least one other additive E), where the entirety of components A) to E) gives 100% by weight, and also to processes for preparation of the thermoplastic molding compositions, to the use of the thermoplastic molding compositions for production of moldings, of foils, of fibers, or of foams, and finally to the moldings, foils, fibers, and foams obtainable from the thermoplastic molding compositions.
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公开(公告)号:ES2229799T3
公开(公告)日:2005-04-16
申请号:ES99963561
申请日:1999-12-16
Applicant: BASF AG
Inventor: GUNTHERBERG NORBERT , WUNSCH JOSEF , ITTEMANN PETER , KNOLL KONRAD , NIESSNER NORBERT
IPC: C08F265/04 , C08F265/06 , C08L25/08 , C08L51/04 , C08L53/02 , C08L69/00
Abstract: Masas de moldeo termoplásticas, que contienen (A) de un 5 hasta un 98 % en peso, referido a la totalidad del peso de las masas de moldeo, de un copolímero de injerto del tipo caucho, formado por, (a1) un 30 hasta un 90 % en peso, referido a (A) de una base de injerto con una temperatura de transición vítrea (Tg) menor que -10ºC, formado por (a11) un polímero de éster acrílico reticulado al menos parcialmente, formado por (a111) de un 50 hasta un 99, 9 % en peso, referido a (a11), de al menos un acrilato de alquilo con 1 a 10 átomos de carbono en el resto alquilo, (a112) de un 0, 1 hasta un 5 % en peso, referido a (a11), de al menos un monómero con efecto reticulante, polifuncional, y (a113) de un 0 hasta 49, 9 % en peso, referido a (a11), de al menos otro monómero copolimerizable con (a111), formado por el grupo de los éteres vinilalquílicos con 1 a 8 átomos de carbono en el resto alquilo, butadieno, isopreno, estireno, acrilonitrilo, metacrilonitrilo y/o metacrilato de metilo.
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公开(公告)号:DE59910537D1
公开(公告)日:2004-10-21
申请号:DE59910537
申请日:1999-12-16
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , WUENSCH JOSEF , ITTEMANN PETER , KNOLL KONRAD , NIESSNER NORBERT
IPC: C08F265/04 , C08F265/06 , C08L25/08 , C08L51/04 , C08L53/02 , C08L69/00
Abstract: Thermoplastic molding compositions comprising(A) 5 to 98%-wt., based on components (A) through (E), of at least one elastomeric graft copolymer,(B) 1 to 90%-wt., based on components (A) through (E), of a further copolymer,(C) 1 to 70%-wt., based on components (A) though (D), of an elastomeric block copolymer composed ofat least one block CA (hard phase) having copolymerized units of a vinylaromatic monomer, andat least one elastomeric block C(B/A) (soft phase) having copolymerized units of a vinylaromatic monomer, and of a diene,(D) 0 to 300%-wt., based on components (A) through (C), of a polycarbonate, and(E) 0 to 30%-wt., based on components (A) through (E), of conventional additives and processing aids,are useful for producing films, moldings or fibers.
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公开(公告)号:AT276316T
公开(公告)日:2004-10-15
申请号:AT99963561
申请日:1999-12-16
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , WUENSCH JOSEF , ITTEMANN PETER , KNOLL KONRAD , NIESSNER NORBERT
IPC: C08F265/04 , C08F265/06 , C08L25/08 , C08L51/04 , C08L53/02 , C08L69/00
Abstract: Thermoplastic molding compositions comprising(A) 5 to 98%-wt., based on components (A) through (E), of at least one elastomeric graft copolymer,(B) 1 to 90%-wt., based on components (A) through (E), of a further copolymer,(C) 1 to 70%-wt., based on components (A) though (D), of an elastomeric block copolymer composed ofat least one block CA (hard phase) having copolymerized units of a vinylaromatic monomer, andat least one elastomeric block C(B/A) (soft phase) having copolymerized units of a vinylaromatic monomer, and of a diene,(D) 0 to 300%-wt., based on components (A) through (C), of a polycarbonate, and(E) 0 to 30%-wt., based on components (A) through (E), of conventional additives and processing aids,are useful for producing films, moldings or fibers.
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公开(公告)号:DE59803025D1
公开(公告)日:2002-03-21
申请号:DE59803025
申请日:1998-06-23
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , KOCH JUERGEN , ITTEMANN PETER , SEIBRING JOACHIM , GRABOWSKI SVEN , MC KEE EDMUND , MOSBACH NORBERT , HEINEN HARTMUT , CZAUDERNA BERNHARD , NIESSNER NORBERT
Abstract: A thermoplastic molding composition having little intrinsic color is produced from a graft copolymer and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base obtained by polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer, upon which is grafted a vinylaromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer. The thermoplastic polymer is a copolymer of a vinylaromatic monomer and acrylonitrile and optionally an additional monoethylenically unsaturated monomer. The thermoplastic molding composition has a low level of intrinsic color coupled with good mechanical properties and can be processed by, for example, extrusion, injection molding, calendaring, blow molding, compression molding, or sintering.
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公开(公告)号:DE19946519A1
公开(公告)日:2001-08-16
申请号:DE19946519
申请日:1999-09-28
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , CZAUDERNA BERNHARD , HOFMANN JUERGEN , ITTEMANN PETER , KURPS ARMIN
IPC: B01F7/00 , C08K5/00 , C09K15/08 , C09K15/14 , C09K15/20 , C08J3/20 , C08K5/13 , C08K5/36 , C08K5/524 , B01F5/16
Abstract: The invention relates to a method for producing stabilizer dispersions for stabilizing plastic dispersions, containing the following: f) a dispersing agent, liquor A; g) at least one compound B, which acts as a tensile; h) optionally, at least one phenolic antioxidant C; i) optionally, at least one co-stabilizer D, containing sulfur or phosphorus; and j) optionally, other auxiliary materials and/or additives. At least one of the components C or D is present in the stabilizer dispersion and the components B, C and D are in powder or liquid form. The components A to D are continuously mixed using a mixer and are homogenized in a dispersing mechanism. The finished stabilizer dispersion is continuously removed from the dispersing mechanism. The invention also relates to the use of a device consisting of a housing in which one or more rotors rotate at high speed in corresponding stators on a motor-driven shaft, for the continuous production of stabilizer dispersions.
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公开(公告)号:DE19962570A1
公开(公告)日:2001-07-05
申请号:DE19962570
申请日:1999-12-23
Applicant: BASF AG
Inventor: ITTEMANN PETER , THEYSOHN RAINER
Abstract: The invention relates to a method for processing plastic materials of the acrylnitril-butadiene-styrene type (ABS) or the acrylnitril-styrene-acrylic ester type (ASA) by extrusion and/or injection molding. The inventive method is characterized in that a magnesium oxide that has a citric acid number of
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公开(公告)号:CZ20000010A3
公开(公告)日:2000-07-12
申请号:CZ20000010
申请日:1998-06-23
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , KOCH JUERGEN , ITTEMANN PETER , SEIBRING JOACHIM , GRABOWSKI SVEN , MC KEE GRAHAM EDMUND , MOSBACH NORBERT , CZAUDERNA BERNHARD , NIESSNER NORBERT , HEINEN HARTMUT
IPC: C08F297/04 , C08L51/06 , C08L55/02
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