公开(公告)号：AU4614699A

公开(公告)日：2000-01-24

申请号：AU4614699

申请日：1999-06-22

Applicant: BASF AG

Inventor： QUEISSER JOACHIM ,  SLANY MICHAEL ,  GEPRAGS MICHAEL ,  LINDNER EKKEHARD ,  SCHMID MARKUS ,  WALD JOACHIM ,  WEGNER PETER

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  C07F9/50 ,  C07F15/00 ,  C08G67/02

Abstract: Water-soluble transition metal complexes of the formula (I)where R to R are linear or branched C2- to C28-alkyl, C3- to C14-cycloalkyl or alkylaryl where the alkyl moiety is of 1 to 28 carbon atoms and the aryl moiety is of 6 to 15 carbon atoms, each of which is substituted by at least one polar protic or ionic functional group based on nonmetallic elements of groups IVA to VIA of the Periodic Table of Elements.

公开(公告)号：DE19829519A1

公开(公告)日：2000-01-05

申请号：DE19829519

申请日：1998-07-02

Applicant: BASF AG

Inventor： QUEISSER JOACHIM ,  SLANY MICHAEL ,  GEPRAEGS MICHAEL ,  LINDNER EKKEHARD ,  SCHMID MARKUS ,  WALD JOACHIM ,  WEGNER PETER

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  C07F9/50 ,  C07F15/00 ,  C08G67/02 ,  B01J31/22

Abstract: The invention relates to water-soluble transition metal complexes of the general formula (I), in which the rests R to R are linear or branched C2-C28 alkyl substituted by at least one polar functional group which is ionic or has a protonic action and based on elements of groups IVA to VIA of the periodic table, C3-C14 cycloalkyl or alkyl aryl with between 1 and 28 C-atoms in the alkyl part and between 6 and 15 C-atoms in the aryl part.

公开(公告)号：DE19651685C1

公开(公告)日：1998-08-20

申请号：DE19651685

申请日：1996-12-12

Applicant: BASF AG

Inventor： SLANY MICHAEL ,  HOEHN ARTHUR DR

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  C07F9/50 ,  C07F15/00 ,  C08F4/42 ,  C08G67/02

公开(公告)号：DE50202933D1

公开(公告)日：2005-06-02

申请号：DE50202933

申请日：2002-07-17

Applicant: BASF AG

Inventor： SLANY MICHAEL ,  LUINSTRA GERRIT ,  SAVA XAVIER

IPC: C08G63/78 ,  C08G63/06 ,  C08G63/82 ,  C08L101/16

Abstract: A process for preparing thermoplastic poly(3-hydroxyalkanoates) with a molar mass greater than 6 000 g/mol and a melting point in the range from 70 to 170° C., by reacting an oxirane compound with carbon monoxide in the presence of a transition metal catalyst which has rhodium(0), nickel(0), iron(0), cobalt(0) or palladium(0) as central metal and has been chelated with neutral Lewis bases, and also in the presence of diisocyanates, ortho esters, acetals, anhydrides, P 2 O 5 , MgO, MgCl 2 , MgSO 4 , zeolites, or a mixture of these, at a pressure in the range from 1 to 250 bar and at from room temperature to 150° C.

公开(公告)号：BR0115853A

公开(公告)日：2004-01-06

申请号：BR0115853

申请日：2001-12-03

Applicant: BASF AG

Inventor： SLANY MICHAEL ,  SCHOFER MARTIN ,  RUPER MICHAEL

IPC: C07B61/00 ,  C07C51/14 ,  C07C67/38 ,  C07C69/44 ,  C07C253/30 ,  C07C255/19 ,  C07C53/00 ,  C07C51/02 ,  C07C67/36

Abstract: Process for the carbonylation of n-pentenoic acid or its derivatives of the formula (I)where R is -CN or COOR where R is hydrogen, alkyl or aryl by reaction of a compound of the formula (I) with carbon monoxide and a compound (II) containing a hydroxyl group in the presence of a catalyst system, wherein the catalyst system is obtainable by reaction ofa) a source for a metal ion of a metal (III) of the 8th subgroup of the Periodic Table of the Elements withb) a bidentate phosphine ligand of the formula (IV)whereR , R , R , R , R , R , R , R , R , R , R , R independently of one another is an organic radical which in each case contains a carbon atom, via which the respective radical is linked to the relevant tertiary carbon atom mentioned in formula (IV);L , L independently of one another are a lower alkylene group;X is an arylene group.

公开(公告)号：DE10154715A1

公开(公告)日：2003-05-22

申请号：DE10154715

申请日：2001-11-09

Applicant: BASF AG

Inventor： SLANY MICHAEL ,  SCHAEFER MARTIN ,  KARL JOERN ,  ROEPER MICHAEL

IPC: A01N1/00 ,  A23K3/00 ,  A23K50/15 ,  A61L2/16 ,  B09B3/00 ,  C07C20060101 ,  C07C51/41 ,  C07C53/06 ,  A23K1/22

Abstract: A process for the production of formic acid formates comprises reaction of methyl formate with water and a basic compound having a pKa value of the corresponding dissociation step of a least 3 (measured at 25 deg C in aqueous solution), separation of the formed methanol and optionally addition of formic acid to the desired acid content.

公开(公告)号：CA2464762A1

公开(公告)日：2003-05-15

申请号：CA2464762

申请日：2002-10-29

Applicant: BASF AG

Inventor： SLANY MICHAEL ,  KARL JORN ,  ROPER MICHAEL ,  SCHAFER MARTIN

IPC: A23K1/16 ,  C07C27/02 ,  C07C51/09 ,  C07C51/41 ,  C07C53/02 ,  C07C53/06

Abstract: The invention relates to a method for the production of formic acid formates , by reacting formic acid methyl esters with water and a basic compound, havin g a pKa value of the corresponding acid of the corresponding dissociation degr ee which is >= 3, measured at 25 ~C in aqueous solution, by separating the obtained methanol and by optionally adjusting the desired degree of acidity by adding formic acid.

公开(公告)号：DE10148712A1

公开(公告)日：2003-04-17

申请号：DE10148712

申请日：2001-10-02

Applicant: BASF AG

Inventor： SAVA XAVIER ,  SLANY MICHAEL ,  ROEPER MICHAEL

IPC: B01J31/24 ,  C07B61/00 ,  C07C51/14 ,  C07C57/03 ,  C07C67/38 ,  C07C69/533 ,  C07F9/6568 ,  C07F9/6571 ,  B01J31/28 ,  C07F9/6564 ,  C07B41/06 ,  C07B41/08 ,  C07B41/12 ,  C07B43/06

Abstract: Diphosphines (I) containing a 2-phosphatricyclo(3.3.1.1 .7)decyl group are new. Diphosphines of formula R \>P-(CH2)n-PR2R3 (I) are new: R = a divalent group forming with P an (un)substituted 2-phosphatricyclo(3.3.1.1 .7)decyl group in which one or more C atoms can be replaced with heteroatoms; R , R = 1-20C monovalent groups or together form a 2-20C divalent group; n = 4 or 5. Independent claims are also included for: (1) a carbonylation catalyst comprising a compound (I) and palladium or a palladium compound; (2) production of derivatives by liquid-phase carbonylation of a conjugated diene in the presence of a hydroxylic compound and a carbonylation catalyst as above.

公开(公告)号：CA2461920A1

公开(公告)日：2003-04-17

申请号：CA2461920

申请日：2002-09-26

Applicant: BASF AG

Inventor： ROEPER MICHAEL ,  SLANY MICHAEL ,  SAVA XAVIER

IPC: B01J31/28 ,  B01J31/24 ,  C07B61/00 ,  C07C51/14 ,  C07C57/03 ,  C07C67/38 ,  C07C69/533 ,  C07F9/6568 ,  C07F9/6571

Abstract: The invention relates to diphosphine of formula Rl>P-(CH)n-PR2R3 wherein Rl is a bivalent radical which together with the phosphorous atom to which it is linked represents an unsubstituted or substituted 2-phospha- tricyclo[3.3.1.1{3,7}]decyl-group or a derivative thereof, wherein one or several carbon atoms are replaced by heteroatoms, R2, R3 independently represent a monovalent radical having 1 -20 atoms or a joint bivalent radica l having 2 - 20 atoms, n is 4 or 5, and the mixtures thereof as a suitable carboxylation system containing palladium or a palladium compound and said type of diphosphin. The invention also relates to a method for the carbonylation of a conjugated diene in the presence of said system.

公开(公告)号：AU2002238521A1

公开(公告)日：2002-08-28

申请号：AU2002238521

申请日：2002-01-26

Applicant: BASF AG

Inventor： SCHAFER MARTIN ,  SLANY MICHAEL ,  ROPER MICHAEL

IPC: B01J31/22 ,  B01J31/24 ,  C07B61/00 ,  C07C67/38 ,  C07C69/24 ,  C07C69/34 ,  C07C253/30 ,  C07C255/19 ,  C07F9/50 ,  C07F9/6568

Abstract: A compound of formula (I) suitable as a catalyst or for the preparation of a catalyst system: L 1 -X-L 2 (I) is provided, in which X is a lower alkylene group, an arylene group or an alkarylene group; L 1 is in which Y 1 is oxygen, sulfur or N-R 17 , R 11 , R 12 , R 13 , R 14 , R 15 , R 16 and R 17 independently of one another being hydrogen, alkyl or aryl; and L 2 is in which Y 2 is oxygen, sulfur or N-R 27 , R 21 , R 22 , R 23 , R 24 , R 25 , R 26 and R 27 independently of one another being hydrogen, alkyl or aryl, it being possible for L 1 and L 2 to be identical or different.