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公开(公告)号:AU6829500A
公开(公告)日:2001-02-13
申请号:AU6829500
申请日:2000-07-26
Applicant: BASF AG
Inventor: AUER HEINZ , DAHLHAUS JURGEN , FISCHER KARL , HAMMER HANS , KELLENBENZ JOCHEN , SCHULZ MICHAEL , THIEL JOACHIM , VICARI MAXIMILIAN
IPC: B01D3/00 , B01J3/00 , B01J3/02 , B01J19/00 , C07B61/00 , C07C29/80 , C07C31/04 , C07C67/36 , C07C69/06
Abstract: A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity. Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.
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公开(公告)号:DE59700760D1
公开(公告)日:1999-12-30
申请号:DE59700760
申请日:1997-02-27
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , WALTER MARC , SCHWAB EKKEHARD , MUELLER HANS-JOACHIM , KONS GERMAIN , DILLING STEPHAN , POLANEK PETER
IPC: B01J23/755 , C10G45/36 , C10G67/02
Abstract: PCT No. PCT/EP97/00960 Sec. 371 Date Sep. 3, 1998 Sec. 102(e) Date Sep. 3, 1998 PCT Filed Feb. 27, 1997 PCT Pub. No. WO97/32944 PCT Pub. Date Sep. 12, 1997In the process for the selective hydrogenation of dienes in diene-containing feed streams, a diene-containing feed stream is hydrogenated over a nickel-containing precipitated catalyst at from 40 to 100 DEG C., a pressure of from 3 to 20 bar and a WHSV (weight hourly space velocity) of from 1 to 10 kg/(lxh) in the presence of free hydrogen.
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公开(公告)号:AT186942T
公开(公告)日:1999-12-15
申请号:AT97905112
申请日:1997-02-27
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , WALTER MARC , SCHWAB EKKEHARD , MUELLER HANS-JOACHIM , KONS GERMAIN , DILLING STEPHAN , POLANEK PETER
IPC: B01J23/755 , C10G45/36 , C10G67/02
Abstract: PCT No. PCT/EP97/00960 Sec. 371 Date Sep. 3, 1998 Sec. 102(e) Date Sep. 3, 1998 PCT Filed Feb. 27, 1997 PCT Pub. No. WO97/32944 PCT Pub. Date Sep. 12, 1997In the process for the selective hydrogenation of dienes in diene-containing feed streams, a diene-containing feed stream is hydrogenated over a nickel-containing precipitated catalyst at from 40 to 100 DEG C., a pressure of from 3 to 20 bar and a WHSV (weight hourly space velocity) of from 1 to 10 kg/(lxh) in the presence of free hydrogen.
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公开(公告)号:AT177346T
公开(公告)日:1999-03-15
申请号:AT95942679
申请日:1995-12-16
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , FLICK KLEMENS , MELDER JOHANN-PETER , SCHNURR WERNER , WULFF-DOERING JOACHIM
IPC: B01J25/00 , B01J25/02 , B01J37/00 , C07B31/00 , C07C253/30
Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.
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公开(公告)号:HUT77249A
公开(公告)日:1998-03-02
申请号:HU9701898
申请日:1995-12-16
Applicant: BASF AG
Inventor: FLICK KLEMENS , MELDER JOHANN-PETER , SCHNURR WERNER , VICARI MAXIMILIAN , WULFF-DOERING JOACHIM
IPC: B01J25/00 , B01J25/02 , B01J37/00 , C07B31/00 , C07C253/30
Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.
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公开(公告)号:DE4339713A1
公开(公告)日:1995-05-24
申请号:DE4339713
申请日:1993-11-22
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , POLANEK PETER DR
IPC: C07C2/10 , C07C11/02 , C08F4/26 , C08F4/64 , C08F4/70 , C08F4/80 , C08F10/00 , C10G50/00 , B01J23/78 , C08F4/76
Abstract: PCT No. PCT/EP94/03838 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 21, 1994 PCT Pub. No. WO95/14647 PCT Pub. Date Jun. 1, 1995Straight-chain C2-C6-olefins are oligomerized to their dimers, trimers and tetramers by means of a fixed-bed catalyst, at superatmospheric pressure and at room temperature or elevated temperatures, by a process in which the catalyst used is one which contains, as active components, after deduction of the loss on ignition following heating at 900 DEG C., from 10 to 70% by weight of nickel oxide, calculated as NiO, from 5 to 30% by weight of titanium dioxide or zirconium dioxide, from 0 to 20% by weight of alumina, from 20 to 40% by weight of silica and from 0.01 to 1% by weight of an alkali metal oxide, with the proviso that the contents of the individual components in the catalyst sum to 100% by weight.
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公开(公告)号:NO327829B1
公开(公告)日:2009-10-05
申请号:NO20023513
申请日:2002-07-23
Applicant: BASF AG
Inventor: AUER HEINZ , HAMMER HANS , BESSLING BERND , HASSE HANS , SAUER FRIEDRICH , WAGNER GERHARD , ADRIAN TILL , VICARI MAXIMILIAN
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid in which, during the work-up, a compound of the general formula Iwhere the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1-C4-alkyl group,is employed simultaneously as extractant for formic acid and as antifoam for a distillation process.
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公开(公告)号:DE502004003979D1
公开(公告)日:2007-07-12
申请号:DE502004003979
申请日:2004-07-03
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , RUDLOFF MARTIN , KRAMER ANDREAS , DREWS RONALD
IPC: C07C29/42 , C07C33/042
Abstract: In the production of propargyl alcohol (I) by conversion of an aqueous formaldehyde solution containing acetylene in presence of a catalyst containing copper acetylide at 1-15 (preferably 3-7) bars and 70-120[deg]C without formation of a coherent gas phase, the aqueous formaldehyde solution contains an organic solvent for acetylene and the catalyst is arranged in a fluidized bed.
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公开(公告)号:DE50014201D1
公开(公告)日:2007-05-10
申请号:DE50014201
申请日:2000-07-26
Applicant: BASF AG
Inventor: AUER HEINZ , DAHLHAUS JUERGEN , FISCHER KARL , HAMMER HANS , KELLENBENZ JOCHEN , SCHULZ MICHAEL , THIEL JOACHIM , VICARI MAXIMILIAN
IPC: B01D3/00 , C07C67/36 , B01J3/00 , B01J3/02 , B01J19/00 , C07B61/00 , C07C29/80 , C07C31/04 , C07C69/06
Abstract: A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity. Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.
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公开(公告)号:DE102004060654A1
公开(公告)日:2006-07-06
申请号:DE102004060654
申请日:2004-12-16
Applicant: BASF AG
Inventor: ALEMANY AURELIE , VICARI MAXIMILIAN , KIRCHNER TANJA , STEGLICH FRANK
IPC: C07D207/24 , C07C7/11
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