公开(公告)号：EP2225031A1

公开(公告)日：2010-09-08

申请号：EP08864035.4

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/84 ,  B01J27/188 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J27/188 ,  B01J23/002 ,  B01J23/84 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  C07C217/08

Abstract: Disclosed is a method for producing an amine by reacting a primary or secondary alcohol, aldehyde, and/or ketone with hydrogen and a nitrogen compound selected from among the group comprising ammonia and primary and secondary amines in the presence of a catalyst containing zirconium dioxide, copper, and nickel. Before being reduced with hydrogen, the catalytically active material of the catalyst contains oxygen-containing compounds of zirconium, copper, and nickel, 1.0 to 5.0 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and 0.2 to 5.0 percent by weight of a polyoxometallate. Also disclosed are catalysts as defined above.

公开(公告)号：EP2061747A1

公开(公告)日：2009-05-27

申请号：EP07765786.4

申请日：2007-07-04

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  HOFFER, Bram Willem ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till

IPC: C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08 ,  C07D295/02 ,  B01J23/89 ,  B01J23/825 ,  B01J23/835 ,  B01J23/843

CPC classification number: C07C209/16 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/14 ,  B01J37/18 ,  C07C209/26 ,  C07C213/02 ,  C07D295/02 ,  C07D295/023 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group comprising ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing catalyst and a nickel-containing catalyst. The invention is characterised in that the catalytically active weight of the catalyst, prior to reduction with hydrogen, contains oxygen-containing compounds of zirconium, copper and nickel and oxygen-containing compounds of one or more metals, selected from Sb, Pb, Bi and In.

Abstract translation: 本发明涉及一种通过伯或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在二氧化锆 - 二氧化锆存在下反应制备胺的方法， 含镍催化剂和含镍催化剂。 本发明的特征在于，催化剂的催化活性重量在用氢还原之前含有锆，铜和镍的含氧化合物和一种或多种选自Sb，Pb，Bi和 在。

公开(公告)号：EP2043997A1

公开(公告)日：2009-04-08

申请号：EP07787042.6

申请日：2007-07-04

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  HOFFER, Bram Willem ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till

IPC: C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07D295/02 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08 ,  B01J23/885

CPC classification number: C07C213/02 ,  B01J23/002 ,  B01J23/885 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/26 ,  C07D295/023 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group comprising ammonia, primary and secondary amines, in the presence of a zirconium dioxide and nickel-containing catalyst. The catalytically active mass of the catalyst, prior to its reduction with hydrogen, contains oxygen-containing compounds of zirconium, copper, nickel and cobalt and 5.5 to 12 wt% of oxygen-containing compounds of molybdenum, calculated as MoO3.

公开(公告)号：EP2688861A1

公开(公告)日：2014-01-29

申请号：EP12710259.8

申请日：2012-03-21

Applicant: BASF SE

Inventor： WIGBERS, Christof, Wilhelm ,  MÜLLER, Christoph ,  MÄGERLEIN, Wolfgang ,  KUBANEK, Petr ,  HEIDEMANN, Thomas ,  MELDER, Johann-Peter ,  KRUG, Thomas ,  BEY, Oliver

IPC: C07C209/48

CPC classification number: C07C209/48 ,  C07C211/11 ,  C07C211/36

Abstract: The invention relates to a method for hydrogenating nitriles with hydrogen in the presence of a catalyst in a reactor, said catalyst being arranged in a fixed bed. The invention is characterized in that the cross-sectional load in the reactor ranges from 5 kg/(m
2 s) to 50 kg/(m
2 s). The invention further relates to a method for producing secondary products of isophorondiamine (IPDA) or N,N-dimethylaminopropylamine (DMAPA) from amines produced according to the invention.

公开(公告)号：EP2061747B1

公开(公告)日：2013-04-17

申请号：EP07765786.4

申请日：2007-07-04

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  HOFFER, Bram Willem ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till

IPC: C07C211/10 ,  C07C215/08 ,  C07C217/08 ,  C07D295/023 ,  B01J23/89 ,  B01J23/825 ,  B01J23/835 ,  B01J23/843 ,  C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07D295/02 ,  B01J37/03

CPC classification number: C07C209/16 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/14 ,  B01J37/18 ,  C07C209/26 ,  C07C213/02 ,  C07D295/02 ,  C07D295/023 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

公开(公告)号：EP2043997B1

公开(公告)日：2012-09-12

申请号：EP07787042.6

申请日：2007-07-04

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  HOFFER, Bram Willem ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till

IPC: C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07D295/02 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08 ,  B01J23/885

CPC classification number: C07C213/02 ,  B01J23/002 ,  B01J23/885 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/26 ,  C07D295/023 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

公开(公告)号：EP2234717A1

公开(公告)日：2010-10-06

申请号：EP08865518.8

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/835 ,  B01J23/84 ,  B01J23/843 ,  B01J23/847 ,  B01J37/03 ,  B01J37/18 ,  B01J23/825 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J27/1853 ,  B01J23/002 ,  B01J23/755 ,  B01J23/825 ,  B01J23/835 ,  B01J23/84 ,  B01J23/8435 ,  B01J23/8474 ,  B01J27/055 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/78 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/56 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/44 ,  B01J2523/53 ,  C07C211/10 ,  C07C217/08

Abstract: Disclosed is a method for producing an amine by reacting a primary or secondary alcohol, aldehyde, and/or ketone with hydrogen and a nitrogen compound selected from among the group comprising ammonia and primary and secondary amines in the presence of a catalyst containing zirconium dioxide, copper, and nickel. Before being reduced with hydrogen, the catalytically active material of the catalyst contains oxygen-containing compounds of zirconium, copper, and nickel, 1.0 to 5.0 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and 0.2 to 5.0 percent by weight of oxygen-containing compounds of vanadium, niobium, sulfur, phosphorus, gallium, boron, tungsten, lead, and/or antimony, which are respectively calculated as V2O5, Nb2O5, H2SO4, H3PO4, Ga2O3, B2O3, WO3, PbO, or Sb2O3. Also disclosed are catalysts as defined above.

Abstract translation: 本发明公开了一种通过使伯或仲醇，醛和/或酮与氢和选自氨和伯胺和仲胺的氮化合物在含有二氧化锆的催化剂存在下反应来制备胺的方法， 铜和镍。 在用氢气还原之前，催化剂的催化活性材料含有锆，铜和镍的含氧化合物，以CoO计为1.0-5.0重量％的含钴含氧化合物，以及0.2-5.0重量％ 钒，铌，硫，磷，镓，硼，钨，铅和/或锑的含氧化合物的重量分别计算为V2O5，Nb2O5，H2SO4，H3PO4，Ga2O3，B2O3，WO3，PbO或 三氧化二锑。 还公开了如上定义的催化剂。

公开(公告)号：EP2225030A1

公开(公告)日：2010-09-08

申请号：EP08864424.0

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/835 ,  B01J23/843 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J23/835 ,  B01J23/002 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/44 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/53 ,  B01J2523/43 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing, copper-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, copper, nickel, 0.2 to 40% by weight of oxygen-containing compounds of cobalt, calculated as CoO, 0.1 to 5% by weight of oxygen-containing compounds of iron, calculated as Fe2O3, and 0.1 to 5% by weight of oxygen-containing compounds of lead, tin, bismuth and/or antimony, each calculated as PbO, SnO, Bi2O3 or Sb2O3. The invention also relates to catalysts of the above type.

Abstract translation: 本发明涉及一种通过使伯或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在二氧化锆 - 二氧化锆存在下反应来制备胺的方法， 含铜含镍含镍催化剂，催化剂的催化活性物质在用含氢的含氧化合物锆，铜，镍，0.2至40重量％的含氧化合物钴， （以CoO计），0.1至5重量％的以Fe 2 O 3计的铁的含氧化合物和0.1至5重量％的铅，锡，铋和/或锑的含氧化合物，各自以PbO计算， SnO，Bi2O3或Sb2O3。 本发明还涉及上述类型的催化剂。

公开(公告)号：EP2046721A1

公开(公告)日：2009-04-15

申请号：EP07787621.7

申请日：2007-07-17

Applicant: BASF SE

Inventor： ANDERS, Joachim-Thierry ,  MELDER, Johann-Peter ,  KUBANEK, Petr ,  SCHWAB, Ekkehard ,  MACKENROTH, Wolfgang ,  HÖLEMANN, Karl ,  VAN LAAR, Frederik

IPC: C07C209/02 ,  C07C211/46

CPC classification number: C07C209/02 ,  B01J23/002 ,  B01J23/78 ,  B01J23/88 ,  B01J23/885 ,  B01J2523/00 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/68 ,  C07C211/46

Abstract: Disclosed is a method for aminating hydrocarbons with ammonia. Said method is characterized in that the amination process is carried out in the presence of an additive which reacts with hydrogen. At least one organic-chemical compound, N2O, hydroxylamine, hydrazine, and/or carbon monoxide is/are used as an additive.

公开(公告)号：EP2043998A1

公开(公告)日：2009-04-08

申请号：EP07787044.2

申请日：2007-07-04

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  HOFFER, Bram Willem ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter

IPC: C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08 ,  C07D295/02 ,  B01J23/89

CPC classification number: C07C209/16 ,  B01J23/002 ,  B01J23/8926 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/26 ,  C07C213/02 ,  C07D295/023 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group comprising ammonia, primary and secondary amines, in the presence of a zirconium dioxide and nickel-containing catalyst. The invention is characterised in that the catalytically active mass of the catalyst contains, prior to reduction with hydrogen, oxygen-containing compounds of zirconium, copper, nickel and 0.5 to 6 wt% of oxygen-containing compounds of silver, calculated as AgO.

Abstract translation: 本发明涉及一种通过使伯或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在二氧化锆存在下反应来制备胺的方法，和 含镍催化剂。 本发明的特征在于，催化剂的催化活性物质在用氢还原之前含有锆，铜，镍的含氧化合物和以AgO计算的0.5-6wt％的含氧的含氧化合物。