公开(公告)号：EP2432815B1

公开(公告)日：2013-10-23

申请号：EP10723038.5

申请日：2010-05-19

Applicant: BASF SE

Inventor： ELING, Berend ,  GÖTTKE, Stephan ,  BUYLINCKX, Ben ,  MÄGERLEIN, Wolfgang

IPC: C08G18/32 ,  C08G18/48 ,  C08G18/50 ,  C09D175/02 ,  C08G18/10

CPC classification number: C08G18/4866 ,  C08G18/10 ,  C08G18/324 ,  C08G18/4825 ,  C08G18/5024 ,  C09D175/02 ,  C08G18/6618 ,  C08G18/6685

公开(公告)号：EP2513037A1

公开(公告)日：2012-10-24

申请号：EP10787796.1

申请日：2010-12-13

Applicant: BASF SE

Inventor： MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  PASTRE, Jörg ,  EBERHARDT, Jan ,  KRUG, Thomas ,  KREITSCHMANN, Mirko

IPC: C07C209/28 ,  C07C215/10 ,  C07C215/12

CPC classification number: C07C215/12 ,  C07C213/08

Abstract: The invention relates to a method for producing ethanolamines by means of reacting glycol aldehyde with monoethanolamine and/or diethanolamine in the presence of a catalyst.

公开(公告)号：EP2225027B1

公开(公告)日：2012-05-23

申请号：EP08863967.9

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/76 ,  B01J23/835 ,  B01J23/843 ,  B01J23/883 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J23/883 ,  B01J23/002 ,  B01J23/76 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/44 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/68 ,  B01J2523/51 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/54

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, nickel and iron and 0.2 to 5.5% by weight of oxygen-containing compounds of tin, lead, bismuth, molybdenum, antimony and/or phosphorous, each calculated as SnO, PbO, Bi2O3, MoO3, Sb2O3 or H3PO4. The invention also relates to catalysts of the above type.

公开(公告)号：EP2225031A1

公开(公告)日：2010-09-08

申请号：EP08864035.4

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/84 ,  B01J27/188 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J27/188 ,  B01J23/002 ,  B01J23/84 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  C07C217/08

Abstract: Disclosed is a method for producing an amine by reacting a primary or secondary alcohol, aldehyde, and/or ketone with hydrogen and a nitrogen compound selected from among the group comprising ammonia and primary and secondary amines in the presence of a catalyst containing zirconium dioxide, copper, and nickel. Before being reduced with hydrogen, the catalytically active material of the catalyst contains oxygen-containing compounds of zirconium, copper, and nickel, 1.0 to 5.0 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and 0.2 to 5.0 percent by weight of a polyoxometallate. Also disclosed are catalysts as defined above.

公开(公告)号：EP2506966B1

公开(公告)日：2017-08-16

申请号：EP10784512.5

申请日：2010-11-29

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  HEIDEMANN, Thomas

IPC: B01J37/03 ,  B01J37/18 ,  B01J23/835 ,  C07C213/02 ,  C07D295/03 ,  C07D295/027

CPC classification number: C07C213/02 ,  B01J23/835 ,  B01J37/031 ,  B01J37/035 ,  B01J37/18 ,  C07D295/027 ,  C07D295/03 ,  Y02P20/582 ,  C07C217/08

公开(公告)号：EP2688861B1

公开(公告)日：2016-08-17

申请号：EP12710259.8

申请日：2012-03-21

Applicant: BASF SE

Inventor： WIGBERS, Christof, Wilhelm ,  MÜLLER, Christoph ,  MÄGERLEIN, Wolfgang ,  KUBANEK, Petr ,  HEIDEMANN, Thomas ,  MELDER, Johann-Peter ,  KRUG, Thomas ,  BEY, Oliver

IPC: C07C209/48

CPC classification number: C07C209/48 ,  C07C211/11 ,  C07C211/36

公开(公告)号：EP2225029B1

公开(公告)日：2016-08-03

申请号：EP08863552.9

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/835 ,  B01J37/03 ,  B01J37/18 ,  C07C213/02 ,  C07D295/023 ,  C07C209/16

CPC classification number: B01J23/835 ,  B01J23/002 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/02 ,  C07D295/06 ,  C07C217/08

公开(公告)号：EP2782898A1

公开(公告)日：2014-10-01

申请号：EP12788179.5

申请日：2012-11-13

Applicant: BASF SE

Inventor： ASPRION, Norbert ,  JULIUS, Manfred ,  BEY, Oliver ,  WERLAND, Stefanie ,  STEIN, Frank ,  KUMMER, Matthias ,  MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  HUYGHE, Kevin ,  MOORS, Maarten

IPC: C07C209/16 ,  C07C211/05 ,  C07C211/06

CPC classification number: C07C209/16 ,  C07C29/145 ,  C07C31/10 ,  C07C211/05 ,  C07C211/06

Abstract: Method for producing ethylamines and monoisopropylamine (MIPA), in which bioethanol is reacted with ammonia in the presence of hydrogen and a heterogeneous catalyst to form ethylamines, wherein the bioethanol contains sulphur and/or sulphur-containing compounds of ≥ 0.1 ppm by weight (calculated S), and then in the presence of the same catalyst, isopropanol is reacted with ammonia in the presence of hydrogen to form MIPA.

公开(公告)号：EP2688862A1

公开(公告)日：2014-01-29

申请号：EP12710488.3

申请日：2012-03-19

Applicant: BASF SE

Inventor： WIGBERS, Christof Wilhelm ,  MÜLLER, Christoph ,  MÄGERLEIN, Wolfgang ,  ERNST, Martin ,  HEIDEMANN, Thomas ,  MELDER, Johann-Peter ,  KÖNIGSMANN, Lucia ,  JOSHI, Milind ,  BEY, Oliver ,  STEIN, Bernd

IPC: C07C209/48

CPC classification number: C07C209/48 ,  C07C209/52 ,  C07C211/11 ,  C07C211/36

Abstract: The present invention relates to a process for hydrogenating organic nitriles by means of hydrogen in the presence of a catalyst in a reactor, where the shaped body catalyst is arranged in a fixed bed, wherein the shaped body in the shape of spheres or rods has in each case a diameter of 3 mm or less, in the shape of tablets a height of 4 mm or less, and in the case of all other geometries in each case has an equivalent diameter L = 1/a' of 0.70 mm or less, where a' is the external surface area per unit volume (mms 2/mmp 3), with: (I) where Ap is the external surface area of the catalyst particle (mms 2) and Vp is the volume of the catalyst particle (mmp 3). The present invention further relates to a process for preparing downstream products of isophoronediamine (IPDA) or N,N-dimethylaminopropylamine (DMAPA) from amines prepared according to the invention.

公开(公告)号：EP2506966A1

公开(公告)日：2012-10-10

申请号：EP10784512.5

申请日：2010-11-29

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  HEIDEMANN, Thomas

IPC: B01J23/00 ,  C07C211/16 ,  C07C211/10

CPC classification number: C07C213/02 ,  B01J23/835 ,  B01J37/031 ,  B01J37/035 ,  B01J37/18 ,  C07D295/027 ,  C07D295/03 ,  Y02P20/582 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group containing ammonia and primary and secondary amines, in the presence of a supported catalyst that contains copper, nickel and cobalt. According to the invention, the catalytically active mass of the catalyst, prior to the reduction of the same using hydrogen, contains oxygen-containing compounds of aluminium, copper, nickel and cobalt and an amount ranging between 0.2 and 5.0 wt. % of oxygen-containing compounds of tin, calculated as SnO. The invention also relates to catalysts defined as above.

Abstract translation: 本发明涉及一种通过使伯或仲醇，醛和/或酮与氢和选自含有氨和伯胺和仲胺的氮化合物在负载型催化剂存在下反应来制备胺的方法， 含有铜，镍和钴。 根据本发明，催化剂的催化活性物质在用氢气还原之前含有铝，铜，镍和钴的含氧化合物，用量范围为0.2-5.0wt％。 以SnO计算的锡的含氧化合物的％。 本发明还涉及如上定义的催化剂。