CATALYST AND METHOD FOR THE CONVERSION OF OXYGENATES TO OLEFINS

    公开(公告)号:CA2877560A1

    公开(公告)日:2014-01-03

    申请号:CA2877560

    申请日:2013-06-26

    Applicant: BASF SE

    Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, the catalyst containing one or more zeolites of an MFI-, MEL- and/or MWW-type structure and particles of one or more metal oxides, wherein the one or more zeolites of the MFI-, MEL- and/or MWW-type structure contain one or more alkaline earth metals, and the particles of the one or more metal oxides contain phosphorus, the phosphorus being at least partially present as an oxide, and the one or more alkaline earth metals being selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more of these elements. The invention also relates to the production and use of said catalyst and to a method for the conversion of oxygenates to olefins using the catalyst.

    PROCESO PARA REVESTIR SUPERFICIE DE SOPORTE POROSA CON ARMAZON ORGANOMETALICO.

    公开(公告)号:MX2013006021A

    公开(公告)日:2013-07-29

    申请号:MX2013006021

    申请日:2011-12-05

    Applicant: BASF SE

    Abstract: Se proporciona un procedimiento para revestir por lo menos parte de una superficie de un soporte con una estructura de metal orgánico poroso que comprende por lo menos un compuesto orgánico, por lo menos bidentado coordinado con por lo menos un ion de metal. El procedimiento comprende los siguientes pasos: (a) aspersión de por lo menos una parte de la superficie de soporte con una primera solución que comprende por lo menos un ion metálico; (b) aspersión de por lo menos una parte de la superficie de soporte con una segunda solución que comprende por lo menos un compuesto orgánico, por lo menos bidentado; en donde el paso (b) se lleva a cabo antes, después o simultáneamente con el paso (a), para formar una capa de la estructura de metal-orgánico poroso.

    Process for coating support surface with porous metal-organic framework

    公开(公告)号:AU2011340166A1

    公开(公告)日:2013-06-13

    申请号:AU2011340166

    申请日:2011-12-05

    Applicant: BASF SE

    Abstract: Provided is a process for coating at least part of a surface of a support with a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion. The process comprises the following steps: (a) spraying the at least one part of the support surface with a first solution comprising the at least one metal ion; (b) spraying the at least one part of the support surface with a second solution comprising the at least one at least bidentate organic compound; wherein step (b) is carried out before, after or simultaneously with step (a), to form a layer of the porous metal-organic framework.

    PROCESS FOR THE CONVERSION OF OXYGENATES TO OLEFINS

    公开(公告)号:ZA201504264B

    公开(公告)日:2021-04-28

    申请号:ZA201504264

    申请日:2015-06-12

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the conversion of oxygenates to olefins comprising (i) providing a gas stream comprising one or more oxygenates; and (ii) contacting the gas stream with a catalyst; wherein the catalyst comprises a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, said zeolitic material being obtainable and/or obtained according to a method comprising (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; wherein the mixture crystallized in step (2) contains 3 wt.-% or less of the one or more elements M based on 100 wt.-% of YO2, wherein M stands for sodium.

    PROCESS FOR THE CONVERSION OF OXYGENATES TO OLEFINS

    公开(公告)号:CA2891248C

    公开(公告)日:2020-07-28

    申请号:CA2891248

    申请日:2013-11-11

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the conversion of oxygenates to olefins comprising (i) providing a gas stream comprising one or more oxygenates; and (ii) contacting the gas stream with a catalyst; wherein the catalyst comprises a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, said zeolitic material being obtainable and/or obtained according to a method comprising (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; wherein the mixture crystallized in step (2) contains 3 wt.-% or less of the one or more elements M based on 100 wt.-% of YO2, wherein M stands for sodium.

    ПОСЛЕДУЮЩАЯ ОБРАБОТКА ДЕБОРИРОВАННОГО ЦЕОЛИТА MWW

    公开(公告)号:RU2638851C2

    公开(公告)日:2017-12-18

    申请号:RU2015118225

    申请日:2013-10-09

    Applicant: BASF SE

    Abstract: Изобретениеотноситсяк способупоследующейобработкицеолитногоматериала, обладающегокаркаснойструктурой MWW, атакжек цеолитномуматериалу, которыйполучаютилиможнополучитьэтимспособом, икоторыйможноприменитьв качествепредшественникакатализатора. Способвключает (i) получениецеолитногоматериала, обладающегокаркаснойструктурой MWW, причемкаркаснаяструктурацеолитногоматериалавключает XOи YO, где Y означаетчетырехвалентныйэлементи X означаеттрехвалентныйэлементи гдемолярноеотношение XO:YOпревышает 0,02:1, (ii) обработкуполученногоцеолитногоматериала, полученногонастадии (i), жидкойсистемойрастворителейи темсамымполучениецеолитногоматериала, обладающегомолярнымотношением XO:YO, составляющимнеболее 0,02:1, частичноевыделениецеолитногоматериалаизжидкойсистемырастворителей, (iii) обработкуцеолитногоматериала, полученногонастадии (ii), жидкойводнойсистемой, обладающейзначением pH, находящимсяв диапазонеот 5,5 до 8, ипритемпературенениже 75°C взакрытойсистемеприавтогенномдавлении, причемзначение pH воднойсистемы, использующейсянастадии (iii), определяютс помощьюстеклянногоэлектродадляизмерения pH. Изобретениеобеспечиваетэффективнуюобработкуцеолитногоматериала, позволяясохранитьстепенькристалличностипостояннойилидажеувеличитьстепенькристалличности. 3 н. и 28 з.п. ф-лы.

    POST-TREATMENT OF DEBORONATED MWW ZEOLITE

    公开(公告)号:ZA201503155B

    公开(公告)日:2017-11-29

    申请号:ZA201503155

    申请日:2015-05-08

    Applicant: BASF SE

    Abstract: A process for the post-treatment of a zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure, wherein the framework structure of the zeolitic material comprises X2O3 and YO2, wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X2O3:YO2 is greater than 0.02:1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X2O3:YO2 of at most 0.02:1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.

    POST-TREATMENT OF DEBORONATED MWW ZEOLITE

    公开(公告)号:SG11201503019SA

    公开(公告)日:2015-05-28

    申请号:SG11201503019S

    申请日:2013-10-09

    Applicant: BASF SE

    Abstract: A process for the post-treatment of a zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure, wherein the framework structure of the zeolitic material comprises X2O3 and YO2, wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X2O3:YO2 is greater than 0.02:1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X2O3:YO2 of at most 0.02:1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.

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