公开(公告)号：MX9905080A

公开(公告)日：2000-04-30

申请号：MX9905080

申请日：1999-05-31

Applicant: CLOROX CO

Inventor： DELINE JAMES E ,  ZIELSKE ALFRED G ,  SUDBURY BARRY A ,  SMITH WILLIAM L ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  ALVAREZ VINCENT E ,  FOLAND LAFAYETTE D

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：ZA9710686B

公开(公告)日：1998-07-22

申请号：ZA9710686

申请日：1997-11-27

Applicant: CLOROX CO

Inventor： CHOY CLEMENT K ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  GARABEDIAN ARAM JR ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  PHILLIPPI MARTIN A ,  SMITH WILLIAM L

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/04 ,  C11D17/08 ,  D06L3/02 ,  H04B7/06 ,  C11D ,  C07D

Abstract: The invention provides liquid cleaning or bleaching compositions containing compounds having the structure of Formula I wherein A is a saturated ring formed by five atoms in addition to the N1 atom, the five saturated ring atoms being four carbon atoms and a heteroatom, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3CN where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, and wherein Y is a generally anionic counterion and Z is in the range of 0 to 10. Additional, adjunct materials commonly found in liquid cleaning and bleaching compositions can be added.

公开(公告)号：AU5445898A

公开(公告)日：1998-06-22

申请号：AU5445898

申请日：1997-11-18

Applicant: BASF AG ,  CLOROX CO

Inventor： CASELLA VICTOR M ,  BROCKEL ULRICH ,  CHOY CLEMENT K ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  HUESTIS SUSAN P ,  KLOTTER KEVIN A ,  PERKINS SARAH A ,  PETERSON DAVID ,  PETRIN MICHAEL J ,  PHILLIPPI MARTIN A ,  SIBERT WILLIAM P ,  SCHONHERR MICHAEL ,  SEELMANN-EGGEBERT HANS PETER ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/12 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/06 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  B29C67/00 ,  B29C59/00 ,  D04H1/64 ,  C07D265/12 ,  C07D295/12 ,  C07D295/26 ,  C07D211/26 ,  C07D211/34

Abstract: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source. These granules include a salt having the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is a counterion. The salt is carried by, coated with, or admixed with a solid particulate such as silica gel, silicic acid, silicate, aluminum oxide, clay, aluminum silicate, or mixtures thereof.

公开(公告)号：CA2273089A1

公开(公告)日：1998-06-04

申请号：CA2273089

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： DELINE JAMES E ,  ZIELSKE ALFRED G ,  SUDBURY BARRY A ,  SMITH WILLIAM L ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  ALVAREZ VINCENT E ,  FOLAND LAFAYETTE D

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34 ,  C11D7/38

Abstract: The invention comprises heterocyclic cationic activators with the structure of Formula (I) that are capable of forming a peroxyimidic acid with a source of active oxygen in aqueous solution or being in a peroxyimidic form wherein A, R1, R2, R3, Y, and Z are as defined in the disclosure. The activators of Formula (I) are admixed with another compound selected from anionic species either capable of forming a peracid with a source of active oxygen in aqueous solution, or being in a peracid form, or a non-ionic polarizable activator and suitable counterion.

公开(公告)号：CA2273087A1

公开(公告)日：1998-06-04

申请号：CA2273087

申请日：1997-11-18

Applicant: CLOROX CO ,  BASF AG

Inventor： SCHURMANN GREGOR ,  SCHAFER WOLFGANG ,  PHILLIPPI MARTIN A ,  KLOTTER KEVIN A ,  ZIELSKE ALFRED G ,  WIDDER RUDI ,  DELINE JAMES E ,  ANNEN ULRICH ,  MUNDINGER KLAUS ,  RULAND ALFRED ,  FOLAND LAFAYETTE D ,  MULLER JOSEPH ,  MULLER MICHAEL

IPC: C07D295/14 ,  C07D265/12 ,  C07D291/00 ,  C07D295/15 ,  C11D3/39 ,  C07D295/12 ,  C07D211/26 ,  C07D211/34

Abstract: A process for the preparation of a compound having the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the soreacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of a pH control substantially prevents formation of an undesirable protonated intermediate.

公开(公告)号：CZ62297A3

公开(公告)日：1997-07-16

申请号：CZ62297

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D1/58 ,  C11D1/62

Abstract: Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.

公开(公告)号：CA2196902A1

公开(公告)日：1996-12-19

申请号：CA2196902

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C07D451/02 ,  C07D205/04 ,  C07D209/08 ,  C07D203/12

Abstract: Bleaching compositions are provided that comprise a nitrile containing compound that has the nitrile bonded to a quaternary nitrogen through a methylene unit (where one or both of the normal hydrogens can be substituted), and two of the quaternary nitrogen bonds are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitrile for bleaching applications. Particularly preferred nitrile containing compounds are N-alkyl morpholinium acetonitrile salts.

公开(公告)号：AT259791T

公开(公告)日：2004-03-15

申请号：AT97947607

申请日：1997-11-18

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  KLOTTER KEVIN A ,  MUELLER MICHAEL ,  MUNDINGER KLAUS ,  PERKINS SARAH A ,  PHILLIPPI MARTIN A ,  SCHOLTISSEK MARTIN ,  SCHOENHERR MICHAEL ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/39 ,  C11D3/395 ,  D06L3/02 ,  D06L4/12 ,  C07D265/30 ,  C07D295/12 ,  C07D211/26 ,  C07D211/34 ,  C01B3/00 ,  C11D7/38

Abstract: A substantially solid composition, the composition having therein a compound with the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure.

公开(公告)号：MX217031B

公开(公告)日：2003-10-20

申请号：MX9905076

申请日：1999-05-31

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KLOTTER KEVIN A ,  MUELLER JOSEF ,  MUELLER MICHAEL ,  MUENDINGER KLAUS ,  PHILLIPPI MARTIN A ,  RULAND ALFRED ,  SCHAEFER WOLFGANG ,  SCHUERMANN GREGOR ,  WIDDER RUDI ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D265/12 ,  C07D291/00 ,  C07D295/15 ,  C11D3/39

Abstract: A process for the preparation of a compound having the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of a pH control substantially prevents formation of an undesirable protonated intermediate.

公开(公告)号：CO5221047A1

公开(公告)日：2002-11-28

申请号：CO00037686

申请日：2000-05-23

Applicant: CLOROX CO

Inventor： DELINE JAMES E ,  OTT MICHAEL M ,  KLOTTER KEVIN A

IPC: C07D257/10 ,  C07D471/08

Abstract: Un método para la síntesis de un macrociclo de tetraamido que comprende:disolver una cantidad de un 1,2 bis(2-aminoalcanamido) benceno en un solvente orgánico para producir una primera solución de reacción;disolver una cantidad de un dihaluro de malonilo en una solución de acetato de etilo, para producir una; segunda solución de reacción;agregar la primera solución de reacción y la segunda solución de reacción a un recipiente de reacción que contiene una tercera solución de reacción compuesta de acetato de etilo y un depurador de ácido, para formar una mezcla de reacción; yaislar un producto sólido compuesto de un macrociclo de tetraamido de la mezcla de reacción.Un método para sintetizar un macrociclo de tetraamido, que comprende:formar una primera solución compuesta de una cantidad de una 1,2-fenilendiamina, un depurador de ácido y tetrahidrofurano;agregar un volumen de un bromuro bromoácido a la primera solución, para producir una primera mezcla de reacción;aislar un primer producto sólido compuesto de un 1,2-bis (2-bromoalcanamido)benceno de la primera mezcla de reacción por filtración; convertir el primer producto sólido en un segundo producto sólido compuesto de un 1,2-bis(2-aminoalcanamido) benceno;disolver el segundo producto sólido en un segundo solvente orgánico, para producir una primera solución de reacción;disolver una cantidad de un dihaluro de malonilo en una solución de acetato de etilo,para producir una segunda solución de reacción;agregar la primera solución de reacción y la segunda solución de reacción a un recipiente de reacción que contiene una tercera solución de reacción compuesta de acetato de etilo y un depurador de ácido, para formar una segunda mezcla de reacción;y aislar un tercer producto sólido compuesto de una macrociclo de tetraamido, de la segunda mezcla de reacción.-Un método para sintetizar un macrociclo de tetraamido, que comprende:formar una primera solución compuesta de una cantidad deuna 1,2-fenilendiamina, un depurador de ácido y tetrahidrofurano; ...