Abstract:
The present invention relates to a method of manufacturing a quality CZTSe light absorption thin film based on a simultaneous vacuum evaporation process. The method includes: (a) a step of depositing Cu, Zn, Sn, and Se onto a substrate by evaporating the same simultaneously; and (b) a step of lowering the temperature of the substrate and depositing Zn, Sn, and Se by evaporating the same simultaneously. By performing a simultaneous vacuum evaporation process and then performing an additional evaporation process while lowering the temperature of the substrate, the present invention is able to resolve the problems due to the loss of Sn accompanied in a high-temperature simultaneous vacuum evaporation process. A CZTSe light absorption thin film manufactured by the manufacturing method given in the present invention has excellent membranous property so that a CZTSe solar cell manufactured using the same is able to have improved photoelectric conversion efficiency.
Abstract:
Disclosed are a vacuum evaporation source with a source residue discharge type shutter and an evaporation device including the same. The vacuum evaporation source with the source residue discharge type shutter comprises a vacuum evaporation source body including an outer container which provides a cylindrical inner space, a crucible which is mounted inside the outer container, and a heater which is arranged between the outer container and the crucible and heats the crucible; and a shutter which is disposed at the output side of the vacuum evaporation source body to open and close the output of the crucible and has multiple flow guides extended from an area corresponding to the output of the crucible to the outer area of the outer container to discharge a source residue condensed at the inner surface facing the output of the crucible to the outside of the outer container. The evaporation device according to the present invention has the above-described configuration and comprises multiple vacuum evaporation sources disposed to be inclined to the center of a substrate in a vacuum chamber.
Abstract:
이성분계 나노입자를 포함하는 슬러리의 숙성 단계가 도입된 CI(G)S계 박막의 제조방법 및 그 방법에 의해 제조된 CI(G)S계 박막이 제공된다. 본 발명의 CI(G)S계 박막의 제조방법은, CI(G)S계의 이성분계 나노입자를 제조하는 단계; 상기 이성분계 나노입자, CI(G)S계 원소를 포함하는 용액 전구체, 용매 및 킬레이트제를 혼합하여 하이브리드형 슬러리를 제조하는 단계; 상기 하이브리드형 슬러리를 5일 내지 10일 동안 숙성하는 단계; 숙성된 하이브리드형 슬러리를 코팅하여 CI(G)S계 박막을 형성하는 단계; 및 상기 형성된 CI(G)S 박막에 열처리하는 단계를 포함한다. 이에 의하여, CI(G)S계 태양전지 박막 제조 시 우수한 재현성 확보가 가능하고, 따라서 생산된 박막의 신뢰도를 향상시킬 수 있다.
Abstract:
PURPOSE: A method for forming a ZnO concavo-convex structure and a solar cell using the same are provided to form a uniform thin film on a concavo-convex structure by using a wet etching method. CONSTITUTION: A substrate (10) is prepared. A nanostructure (20) of which height and width is nanometer scale is formed. A zinc oxide thin film (30) is formed on the substrate having the nanostructure. The zinc oxide thin film is wet-etched. A concavo-convex structure (35) is formed by etching the periphery of the nanostructure.
Abstract:
PURPOSE: A rear reflective film for a thin film solar cell, a forming method thereof and the thin film solar cell including the same are provided to improve the scattering reflectance of a wavelength area by improving the surface illumination of the rear reflective film. CONSTITUTION: An aluminum layer(22) is formed on a substrate. One or more materials selected from Si, O, Cu and Pt dope the aluminum layer. The doped aluminum layer intensifies crystal growth. A transparent conductive film(24) is formed on the surface of the doped aluminum layer. A silver coating layer(23) is formed on the doped aluminum layer.