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公开(公告)号：KR100750291B1
公开(公告)日：2007-08-20
申请号：KR1020060080709
申请日：2006-08-24
Applicant: 한국화학연구원
Abstract: Provided are a polystyrene-based nanocomposite which is improved in compatibility and heat resistance, and a method for preparing the polystyrene-based nanocomposite. A polystyrene-based nanocomposite is prepared from an aluminosilicate layered inorganic material and a polystyrene-based resin, wherein the aluminosilicate layered inorganic material is an organized aluminosilicate layered inorganic material comprising a polystyrene-based copolymer having an amine salt represented by a formula 2 introduced into the interlayer of an aluminosilicate layered inorganic material. In the formula 2, m is an integer of 1-100; x is an integer of 2-200; and X is F, Cl, Br or I.
Abstract translation: 本发明提供相容性和耐热性提高的聚苯乙烯系纳米复合材料以及该聚苯乙烯系纳米复合材料的制造方法。 由硅铝酸盐层状无机材料和聚苯乙烯基树脂制备聚苯乙烯基纳米复合材料，其中硅铝酸盐层状无机材料是有组织的硅铝酸盐层状无机材料，该有机材料包含具有由式2表示的胺盐的聚苯乙烯基共聚物， 铝硅酸盐层状无机材料的中间层。 在式2中，m是1-100的整数; x是2-200的整数; X是F，Cl，Br或I.
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公开(公告)号：KR100604351B1
公开(公告)日：2006-07-25
申请号：KR1020040069217
申请日：2004-08-31
Applicant: 한국화학연구원
IPC: B05D3/02 , B05D3/06 , C09D201/00
Abstract: 본 발명은 내화학성이 우수한 플라스틱 기판과 그의 제조방법에 관한 것으로서, 더욱 상세하게는 플라스틱 기판 표면에, 상기 기판을 이루는 고분자와 동일한 주쇄 구조를 가지는 고분자에 클로로메틸기를 매개로 하여 광경화성기가 결합된 고분자를 유기용매에 용해시킨 고분자 용액을 용액 주형(solvent casting) 또는 스프레이 법에 의해 상기 플라스틱 기판의 표면에 코팅하여 막을 형성하고 이를 자외선 경화 및 가열건조하여 사용된 용매를 제거함으로, 플라스틱 기판의 내화학성이 향상되고 평활도가 개선되는 효과를 얻을 수 있는 내화학성이 우수한 플라스틱 기판과 그의 제조방법에 관한 것이다.
디스플레이, 플라스틱 기판, 광경화, 스프레이 코팅, 내화학성-
公开(公告)号：KR100495096B1
公开(公告)日：2005-06-10
申请号：KR1020020074077
申请日：2002-11-26
Applicant: 한국화학연구원 , 대림에이치앤엘(주)
IPC: C08G73/10
Abstract: 본 발명은 할로겐계 수지 분말을 함유한 방향족 폴리이미드계 복합 소재 분말과 이의 제조방법에 관한 것으로서, 보다 상세하게는 알콕시 알코올과 페놀계 유기 극성 용매로 이루어진 혼합 용매계에, 테트라카르복시산 이무수물과 방향족 디아민 등의 폴리이미드 제조용 단량체와 할로겐계 수지 분말 및 무기입자 분말을 투입한 후 특이성 있게 구성된 조건으로 승온하는 단일 단계로 중합반응에 의해 할로겐계 수지 분말의 입자와 무기입자가 폴리이미드 수지 분말 내에 균일하게 분산되어 기존의 폴리이미드 수지의 특성을 유지하면서도 내열성, 열팽창 특성 및 기계적 특성이 개선된 할로겐계 수지 분말을 함유한 방향족 폴리이미드계 복합 소재 분말과 이의 제조방법에 관한 것이다.
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公开(公告)号：KR1020050040542A
公开(公告)日：2005-05-03
申请号：KR1020030075908
申请日：2003-10-29
Applicant: 한국화학연구원
Abstract: 본 발명은 고내열 친유기성 층상 실리케이트 및 이를 이용한 폴리이미드 나노 복합재에 관한 것으로서, 더욱 상세하게는 층상 실리케이트 무기물이 말단기가 아민기로 치환된 올리고 아믹산 유기화제로 양이온 교환반응되어 개질된 고내열 친유기성 층상 실리케이트와, 상기 층상 실리케이트를 통상의 폴리이미드에 나노 복합화하여 제조된 열적 특성 및 열팽창계수 특성이 향상된 폴리이미드 나노 복합재에 관한 것이다.
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公开(公告)号：KR1020050038109A
公开(公告)日：2005-04-27
申请号：KR1020030073318
申请日：2003-10-21
Applicant: 한국화학연구원
IPC: C08G73/10
Abstract: 본 발명은 평탄화 특성이 우수한 감광성 투명 폴리아믹산 올리고머와 이를 경화하여 제조된 폴리이미드 수지에 관한 것으로서, 보다 상세하게는 방향족 테트라카르복시산 이무수물과 방향족 디아민의 단량체를 중합반응시킴에 있어 특정 구조의 지방족 고리 함유 테트라카르복시산 이무수물과 감광성 기능기 함유 디아민 단량체 및 감광성기를 갖는 모노아민 화합물을 함유시켜 올리고머 수준으로 중합 반응하여 제조한 신규 구조의 폴리아믹산 올리고머와, 상기한 폴리아믹산 올리고머를 경화하여 제조된 것으로 자체 광반응이 가능하고 투명성 및 평탄화도가 개선되어 투명 유기 절연 재료 및 액정 소재의 고분자 격벽 재료로서 유용한 효과가 있는 고평탄화도를 갖는 감광성 투명 폴리이미드 수지에 관한 것이다.
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Patent Agency Ranking
公开(公告)号：KR100443269B1
公开(公告)日：2004-08-04
申请号：KR1020010019537
申请日：2001-04-12
Applicant: 한국화학연구원
Abstract: PURPOSE: Provided is a polyolefin resin composition which uses the polyolefin resin as a matrix by nano compositing the delaminated organophilic layered silicate, polyolefin compatibilizer and the conventional fire retardant. The composite has excellent properties of mechanical strength, heat resistance, impact resistance, fabricability and fire resistance compared with conventional material. CONSTITUTION: The composite comprises: 10- 35wt.%(based on 100wt.% of the polyolefin resin) of organohalogen-based fire retardant; 0.5-10wt.% of the organophilic layered silicate in which the silicate is emulsified with organophosphorus acid salt and organo ammonium salt which are substituted with C12-36 alkyl groups or aromatic groups; 1-30wt.% polyolefin compatibilizer grafted with maleic acid, having average mol wt. of 5,000-90,000 and graft rate of 0.2-10 and more than one additive selected from a photo-stabilizer, a UV absorber, an anti-static agent, wax, pigments, an ignition delaying agent and a filler.
Abstract translation: 目的：提供一种聚烯烃树脂组合物，其通过纳米复合分层的亲有机层状硅酸盐，聚烯烃增容剂和常规阻燃剂，使用聚烯烃树脂作为基体。 与传统材料相比，该复合材料具有优异的机械强度，耐热性，耐冲击性，可加工性和耐火性能。 组成：该复合材料包含：10-35wt％（基于100wt。％的聚烯烃树脂）有机卤素基阻燃剂; 0.5-10重量％的亲有机层状硅酸盐，其中硅酸盐用被C12-36烷基或芳基取代的有机磷酸盐和有机铵盐乳化; 1-30wt％用马来酸接枝的聚烯烃增容剂，其平均分子量wt。 5,000〜90,000的接枝率和0.2〜10的接枝率和选自光稳定剂，UV吸收剂，抗静电剂，蜡，颜料，点火延迟剂和填充剂的多于一种添加剂。
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公开(公告)号：KR1020040050167A
公开(公告)日：2004-06-16
申请号：KR1020020077803
申请日：2002-12-09
Applicant: 한국화학연구원
IPC: C08G73/10
Abstract: PURPOSE: A polyamic acid derivative having an imide side chain containing double bond for a liquid crystal alignment layer and a monomer for the preparation of the polyamic acid derivative are provided, to improve heat resistance, solubility, surface strength, transparency, vertical alignment of liquid crystal and rubbing resistance. CONSTITUTION: The polyamic acid derivative is represented by the formula 1, wherein n is an integer of 1-300 and m is an integer of 1-30. Preferably the polyamic acid derivative has an intrinsic viscosity of 0.3-1.5 dL/g, a molecular weight of 10,000-150,000 g/mol, a surface pencil hardness of H to 7H, a pretilt angle of 88-89.9 degree and a pretilt angle after rubbing of 70-89.9 degree, is soluble in a solvent selected from the group consisting of dimethyl acetamide, dimethyl formamide, N-methyl-2-pyrrolidone, tetrahydrofuran, chloroform, acetone, ethyl acetate and γ-butyrolactone, and has an imidation temperature of 200-300 deg.C. The monomer is represented by the formula 2, wherein m is an integer of 1-30.
Abstract translation: 目的：提供具有用于液晶取向层的具有双键的酰亚胺侧链和用于制备聚酰胺酸衍生物的单体的聚酰胺酸衍生物，以提高液体的耐热性，溶解性，表面强度，透明性，垂直取向 水晶和耐摩擦性。 构成：聚酰胺酸衍生物由式1表示，其中n为1-300的整数，m为1-30的整数。 优选聚酰胺酸衍生物的特性粘度为0.3-1.5dL / g，分子量为10,000-150,000g / mol，表面铅笔硬度为H至7H，预倾角为88-89.9度，预倾角为 摩擦70-89.9度，可溶于选自二甲基乙酰胺，二甲基甲酰胺，N-甲基-2-吡咯烷酮，四氢呋喃，氯仿，丙酮，乙酸乙酯和γ-丁内酯的溶剂，并具有酰亚胺化温度 200-300摄氏度 单体由式2表示，其中m为1-30的整数。
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公开(公告)号：KR1020040046236A
公开(公告)日：2004-06-05
申请号：KR1020020074077
申请日：2002-11-26
Applicant: 한국화학연구원 , 대림에이치앤엘(주)
IPC: C08G73/10
Abstract: PURPOSE: A powdered aromatic polyimide-based composite containing a halogen-based resin powder and its preparation method are provided, to improve heat resistance, thermal expansion and mechanical properties without deterioration of characteristics of a polyimide resin. CONSTITUTION: The method comprises the steps of adding a mixture of tetracarboxylic acid·2H2O monomer and aromatic diamine monomer, halogen-based resin powder and inorganic material powder to a solvent mixture of alkoxy alcohol and phenol-based organic polar solvent; raising temperature to 60-80 deg.C for 2-3 hours; maintaining the temperature for 2-3 hours; raising temperature to 160-200 deg.C for 2-3 hours; and stirring it for 5 min to 6 hours with maintaining the temperature. The powdered polyimide composite comprises aromatic polyamic acid or polyimide resin having a repeating unit represented by the formula 2, halogen-based resin powder and inorganic material powder, wherein 0
Abstract translation: 目的：提供含有卤素类树脂粉末的芳香族聚酰亚胺基复合粉末及其制备方法，以改善耐热性，热膨胀性和机械性能，而不会降低聚酰亚胺树脂的特性。 方案：该方法包括将四羧酸·2H 2 O单体和芳族二胺单体，卤素类树脂粉末和无机材料粉末的混合物加入到烷氧基醇和苯酚类有机极性溶剂的溶剂混合物中的步骤; 升温至60-80℃2-3小时; 保持温度2-3小时; 升温至160-200℃2-3小时; 并在保持温度下搅拌5分钟至6小时。 粉状聚酰亚胺复合材料包括具有式2重复单元的芳族聚酰胺酸或聚酰亚胺树脂，卤素类树脂粉末和无机材料粉末，其中0
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公开(公告)号：KR1020030018153A
公开(公告)日：2003-03-06
申请号：KR1020010051727
申请日：2001-08-27
CPC classification number: G03F7/0387 , G03F7/0226 , G03F7/0233 , G03F7/037 , G03F7/0392 , G03F7/0751 , G03F7/38
Abstract: PURPOSE: An acid liable polyamide polymer and a photosensitive heat resisting insulator composition containing the polymer are provided, which are improved in the photosensitivity, the resolution, the mechanical properties and the flatness of coating. CONSTITUTION: The acid liable polyamide polymer has a repeating unit represented by the formula 1, and contains an acetal or carbonate side group as an acid liable group and a terminal group containing an acetylene group, wherein Ar1 is a tetravalent aromatic group; Ar2 is a divalent aromatic group; R1 and R2 are the same or different each other and are an acid liable group comprising carbonate or acetal; T1 and T2 are the same or different each other and are a terminal group comprising acetylene group; and m and n are an integer of 5-100, respectively. The acid liable polyamide polymer can be a homopolymer or a copolymer according to the combination of Ar1 and Ar2. The photosensitive heat resisting insulator composition comprises the polyamide polymer; and 0.3-15 wt% of a photoacid generator.
Abstract translation: 目的：提供含有聚合物的耐酸聚酰胺聚合物和含有聚合物的感光耐热绝缘体组合物，其改善了光敏性，分辨率，机械性能和涂层的平整度。 构成：酸性聚酰胺聚合物具有式1表示的重复单元，含有作为酸性基团的缩醛或碳酸酯侧基和含有乙炔基的末端基，其中Ar1为四价芳香族基团; Ar2是二价芳族基团; R1和R2彼此相同或不同，是含有碳酸酯或缩醛的酸性基团; T1和T2彼此相同或不同，并且是包含乙炔基的末端基团; m和n分别为5-100的整数。 耐酸的聚酰胺聚合物可以是根据Ar1和Ar2的组合的均聚物或共聚物。 感光耐热绝缘体组合物包含聚酰胺聚合物; 和0.3-15重量％的光酸产生剂。
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公开(公告)号：KR1020030012536A
公开(公告)日：2003-02-12
申请号：KR1020010046592
申请日：2001-08-01
Applicant: 한국화학연구원
IPC: C01B33/26
CPC classification number: C01B33/26 , C01P2002/20
Abstract: PURPOSE: Organic aluminosilicate based lamellar inorganic materials which are usefully used as a core material of various ultramodern industries such as electric, electronic, space and aviation industries by having superior heat resistance and organic affinity and low hygroscopic, and a method for preparing the same are provided. CONSTITUTION: In organic lamellar inorganic materials in which organic polymers are introduced between layers of aluminosilicate based lamellar inorganic materials, the organic aluminosilicate based lamellar inorganic materials are characterized in that the organic polymers introduced between layers of the aluminosilicate based lamellar inorganic materials are low polarity siloxane amine oligomer selected from siloxane amine oligomers represented as in chemical formulae 1a and 1b and siloxane amine oligomer in which alkyl group produced by reaction of alkyl carbonyl chloride is substituted represented as in chemical formula 2, where R1 and R2 are -(CH2)pX1(CH2)q- or formula 3 respectively, wherein X1 is -CH2- or -O-; R is -(CH2)nX2(CH2)k-, wherein X2 is -CH2- or -CH=CH-; l and m are an integral number between 1 to 300 respectively, and p, q, n and k are an integral number between 1 to 30 respectively.
Abstract translation: 目的：通过具有优异的耐热性和有机亲和力以及低吸湿性有机地用作电气，电子，空间和航空工业等各种超现代工业的核心材料的有机铝硅酸盐基层状无机材料及其制备方法 提供。 构成：在硅酸铝基层状无机材料层之间引入有机聚合物的有机层状无机材料中，有机硅铝酸盐层状无机材料的特征在于，在硅铝酸盐基层状无机材料层之间引入的有机聚合物是低极性硅氧烷 选自由化学式1a和1b表示的硅氧烷胺低聚物的胺低聚物和其中取代由烷基碳酰氯反应生成的烷基的硅氧烷胺低聚物如化学式2表示，其中R1和R2是 - （CH2）pX1（ CH 2）q-或式3，其中X 1是-CH 2 - 或-O-; R是 - （CH 2）n X 2（CH 2）k - ，其中X 2是-CH 2 - 或-CH = CH-; 1和m分别为1至300之间的整数，p，q，n和k分别为1至30之间的整数。
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