公开(公告)号：BR0312308A

公开(公告)日：2005-04-12

申请号：BR0312308

申请日：2003-06-30

Applicant: BASF AG

Inventor： AMMERMANN EBERHARD ,  STIERL REINHARD ,  SCHOEFL ULRICH ,  SCHELBERGER KLAUS ,  SCHERER MARIA ,  HENNINGSEN MICHAEL ,  GOLD RANDALL EVEN

IPC: A01N43/32 ,  A01N43/50 ,  A01N43/76

Abstract: Fungicidal mixtures, comprising A) a phenylhydrazide I selected from the compounds Ia and Ib and B) the compound of the formula II in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II and the use of the compounds I and II for preparing such mixtures are described.

公开(公告)号：BR0311996A

公开(公告)日：2005-03-29

申请号：BR0311996

申请日：2003-06-30

Applicant: BASF AG

Inventor： AMMERMANN EBERHARD ,  STIERL REINHARD ,  SCHOEFL ULRICH ,  SCHELBERGER KLAUS ,  SCHERER MARIA ,  HENNINGSEN MICHAEL ,  GOLD RANDALL EVEN

IPC: A01N25/06 ,  A01N43/32 ,  A01N43/40

Abstract: Fungicidal mixtures, comprising A) the compound of the formula I B) a biphenylamide of the formula II, in which Z is a pyridyl ring or a five-membered heteroaryl ring which, in addition to carbon atoms, contains one or two nitrogen atoms or one nitrogen atom and one oxygen or sulfur atom, where Z carries one to three identical or different substituents from the group consisting of halogen, methyl and trifluoromethyl, and X is halogen, in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II and the use of the compounds I and II for preparing such mixtures are described.

公开(公告)号：BR0311461A

公开(公告)日：2005-03-29

申请号：BR0311461

申请日：2003-06-06

Applicant: BASF AG

Inventor： NOACK RAINER ,  SANDER MICHAEL ,  HENNINGSEN MICHAEL

IPC: C07D405/06 ,  C07D521/00

Abstract: The present invention relates to a process for the preparation of 1,2,4-triazol-1-ylmethyloxiranes of the formula I in which A and B are identical or different and, independently of one another, are C 1 -C 4 -alkyl, phenyl-C 1 -C 2 -alkyl, C 3 -C 6 -cycloalkyl, C 3 -C 6 -cycloalkenyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl or phenyl, where the phenyl radical can carry one to three substituents chosen from the group: halogen, nitro, C 1 -C 4 -alkyl, C l -C 4 -alkyloxy, phenoxy, amino, C 1 -C 2 -haloalkyl or phenylsulfonyl, which comprises reacting a) an oxirane of the formula II in which A and B have the meanings given above and L is a nucleophilically substitutable leaving group, with 4-amino-1,2,4-triazole of the formula III to give 4-amino-1,2,4-triazolium salts of the formula IV and b) deaminating the 4-amino-1,2,4-triazolium salts IV with alkali metal nitrites and acid or organic nitrites to give 1,2,4-triazol-1-ylmethyloxiranes of the formula I, and to 4-aminotriazolium salts of the formula IV as intermediates.

公开(公告)号：AU2003242775A1

公开(公告)日：2004-02-09

申请号：AU2003242775

申请日：2003-06-30

Applicant: BASF AG

Inventor： HENNINGSEN MICHAEL ,  GOLD RANDALL EVEN ,  AMMERMANN EBERHARD ,  STIERL REINHARD ,  SCHOFL ULRICH ,  SCHELBERGER KLAUS ,  SCHERER MARIA

IPC: A01N47/12 ,  A01N43/32

Abstract: Fungicidal mixtures, comprising A) at least one valinamide derivative of the formula I in which R is halogen, and B) the compound of the formula II in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II and the use of the compounds I and II for preparing such mixtures are described.

公开(公告)号：SK11412003A3

公开(公告)日：2004-02-03

申请号：SK11412003

申请日：2002-03-15

Applicant: BASF AG

Inventor： HENNINGSEN MICHAEL ,  KUSCHE ANDREAS ,  HULLMANN MICHAEL ,  RUB LOTHAR ,  KASHAMMER STEFAN ,  GERLACH TILL

IPC: C07D265/30 ,  C07B61/00 ,  C07D295/02 ,  C07D295/023 ,  C07D295/03 ,  C07D295/033 ,  A01N43/84

Abstract: The present invention relates to a process for the preparation of N-substituted 2,6-dialkylmorpholines of the formula I in which R 1 and R 2 , independently of one another, are hydrogen, alkyl or cycloalkyl, or R 1 and R 2 together with the carbon atom to which they are bonded are a 5- to 14-membered carbocycle, and R 3 and R 4 , independently of one another, are alkyl or cycloalkyl, by reacting at least one carbonyl compound of the formula II in which R 1 and R 2 have the meanings given above, with at least one morpholine of the formula III in which R 3 and R 4 have the meanings given above, in the presence of hydrogen and at least one metal-containing catalyst, wherein the active component of the catalyst consists essentially of platinum group metals.

公开(公告)号：AU2003246635A1

公开(公告)日：2004-02-02

申请号：AU2003246635

申请日：2003-06-30

Applicant: BASF AG

Inventor： SCHERER MARIA ,  HENNINGSEN MICHAEL ,  GOLD RANDALL EVEN ,  AMMERMANN EBERHARD ,  STIERL REINHARD ,  SCHOFL ULRICH ,  SCHELBERGER KLAUS

IPC: A01N25/04 ,  A01N43/32 ,  A01N43/653

Abstract: New fungicidal mixtures contain dithianon (I) and at least one 1,2,4-triazole derivative (II) in synergistic amounts, where (II) is metconazole, epoxiconazole, fluquinconazole, tebuconazole (IIa), tetraconazole, difenconazole and/or prothioconazole (preferably metconazole, epoxiconazole or (IIa)). Independent claims are included for: (1) a fungicidal composition comprising the (I)/(II) mixture plus a solid or liquid carrier; and (2) a method for controlling harmful fungi, by applying (I) and (II) to the fungi, their habitat or plants, seeds, soil, surfaces, materials or regions to be protected. ACTIVITY : Fungicide. In tests against Botrytis cinerea in paprika seedlings, (I) at 16 ppm or (IIa) at 4 ppm gave no control, whereas a combination of 16 ppm (I) and 4 ppm (IIa) gave 59% control. MECHANISM OF ACTION : Synergist.

公开(公告)号：CA2811012A1

公开(公告)日：2004-01-22

申请号：CA2811012

申请日：2003-06-30

Applicant: BASF AG

Inventor： AMMERMANN EBERHARD ,  STIERL REINHARD ,  SCHOEFL ULRICH ,  SCHELBERGER KLAUS ,  SCHERER MARIA ,  HENNINGSEN MICHAEL ,  GOLD RANDALL EVEN

IPC: A01N43/653 ,  A01N25/04 ,  A01N43/32 ,  A01P3/00

Abstract: New fungicidal mixtures contain dithianon (I) and at least one 1,2,4-triazole derivative (II) in synergistic amounts, where (II) is metconazole, epoxiconazole, fluquinconazole, tebuconazole (IIa), tetraconazole, difenconazole and/or prothioconazole (preferably metconazole, epoxiconazole or (IIa)). Independent claims are included for: (1) a fungicidal composition comprising the (I)/(II) mixture plus a solid or liquid carrier; and (2) a method for controlling harmful fungi, by applying (I) and (II) to the fungi, their habitat or plants, seeds, soil, surfaces, materials or regions to be protected. ACTIVITY : Fungicide. In tests against Botrytis cinerea in paprika seedlings, (I) at 16 ppm or (IIa) at 4 ppm gave no control, whereas a combination of 16 ppm (I) and 4 ppm (IIa) gave 59% control. MECHANISM OF ACTION : Synergist.

公开(公告)号：CA2708350A1

公开(公告)日：2004-01-22

申请号：CA2708350

申请日：2003-06-30

Applicant: BASF AG

Inventor： AMMERMANN EBERHARD ,  STIERL REINHARD ,  SCHOEFL ULRICH ,  SCHELBERGER KLAUS ,  SCHERER MARIA ,  HENNINGSEN MICHAEL ,  GOLD RANDALL EVEN

IPC: A01N43/32 ,  A01N25/04 ,  A01N43/653 ,  A01P3/00

Abstract: The invention relates to fungicidal mixtures containing, in a synergistically effective amount: A) the compound of formula (I) and; B) at least one azole derivative II selected from the group consisting of compounds (II-1) to (II-7). The invention also relates to methods for controlling harmful fungi by using mixtures of compounds (I) and (II), and to the use of compounds (I) and (II) for producing mixtures of this type. (see formula I) (see formula II-1)(see formula II-2) (see formula II-3)(see formula II-4) (see formula II-5)(see formula II-6) (see formula II-7)

公开(公告)号：CA2488828A1

公开(公告)日：2003-12-31

申请号：CA2488828

申请日：2003-06-06

Applicant: BASF AG

Inventor： HENNINGSEN MICHAEL ,  NOACK RAINER ,  SANDER MICHAEL

IPC: C07D405/06 ,  C07D521/00

Abstract: The invention relates to a method for the production of 1,2,4-triazol-1-yl- methyl-oxiranes of formula (I) wherein A and B are the same or different and independently represent C1-C4-alkyl, phenyl-C1-C2-alkyl,. C3 --C6-cycloalkyl , C3-C6-cycloalkenyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl or phenyl . The phenyl radical can contain 1 3 substituents selected form the group: halogen, nitro, C1-C4-alkyl, C1-C4-alkyloxy, phenoxy, amino, C1-C2- halogenalkyl or phenylsulfonyl, characterised in that a) an oxirane of formu la (II) wherein A and B have the above mentioned meaning and L represents a nucleophilically substitutable leaving group which is reacted with 4-amino- 1,2,4-triazol of formula (III), IV to form 4-amino-1,2,4-triazolium salts of formula (IV). The invention also relates to a method for the production of l,2,4-triazolylmethyl-oxiranes.

公开(公告)号：AU6912001A

公开(公告)日：2002-01-14

申请号：AU6912001

申请日：2001-07-04

Applicant: BASF AG

Inventor： KRAMER ANDREAS DR ,  KIEFER MATTHIAS ,  HENNINGSEN MICHAEL ,  SIEGEL WOLFGANG ,  SCHRODER JOCHEN

IPC: C07B61/00 ,  C07C249/06 ,  C07C249/08 ,  C07C251/40 ,  C07C251/58 ,  C07C251/60 ,  C07C49/12

Abstract: The present invention relates to a process for preparing trioxime derivatives of the formula I in which the substituents R 1 and R 2 are identical or different and each is cyano, alkyl, haloalkyl or cycloalkyl, and R 3 and R 4 are identical or different and each is alkyl, haloalkyl, cycloalkyl, alkylcarbonyl or arylalkyl, by the following reaction steps in water without isolation of the intermediates: A) nitrosation of 1,3-diketones of the formula II to give monooximes of the formula III, B) oximation of III with hydroxylamine derivatives of the formula IV H 2 N-OR 3' IV in which R 3' is hydrogen or a group R 3 to give bisoximes of the formula V, C) alkylation of V with alkylating agents or acylation of V with acylating agents to give compounds of the formula VI and D) subsequent oximation of VI with hydroxylamine to give compounds of the formula I.