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公开(公告)号:CA1129703A
公开(公告)日:1982-08-17
申请号:CA331828
申请日:1979-07-13
Applicant: BASF AG
Inventor: LECHTKEN PETER , BRONSTERT BERND , HOFFMANN GERHARD , VYVIAL RUDOLF , LYNCH JOHN
IPC: C07F9/32 , C07F9/40 , C07F9/46 , C07F9/48 , C07F9/53 , C08F2/48 , C08F2/50 , C08F283/00 , C08F291/18 , G03F7/029
Abstract: of the disclosure: A photopolymerizable recording composition which comprises a mixture, containing a photoinitiator, of a) a photopolymerizable olefinically unsaturated monomer and b) an organic polymeric binder, wherein the photoinitiator is an acylphosphine oxide compound of the formula R1R2PO-CO-R3, where R1 and R2 are certain organic radicals and R3 is tert.-alkyl or a cyclic radical with two substituents in the ortho-position to the carbonyl group. The recording compositions have a high reactivity when irradiated with W light and are used in particular for the preparation of printing plates, relief plates and photoresists.
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公开(公告)号:NO841028A
公开(公告)日:1980-01-15
申请号:NO841028
申请日:1984-03-16
Applicant: BASF AG
Inventor: LECHTKEN PETER , BUETHE INGOLF , BRONSTERT BERND , HESSE ANTON , HOFFMANN GERHARD , JACOBI MANFRED , LYNCH JOHN , TRIMBORN WERNER , VYVIAL RUDOLF
IPC: C08K20060101 , C08K5/53 , C08K
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公开(公告)号:NO792333A
公开(公告)日:1980-01-15
申请号:NO792333
申请日:1979-07-13
Applicant: BASF AG
Inventor: LECHTKEN PETER , BUETHE INGOLF , BRONSTERT BERND , HESSE ANTON , HOFFMANN GERHARD , JACOBI MANFRED , LYNCH JOHN , TRIMBORN WERNER , VYVIAL RUDOLF
IPC: C07F20060101 , C07F
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44.
公开(公告)号:ES2021586B3
公开(公告)日:1991-11-16
申请号:ES86117726
申请日:1986-12-19
Applicant: BASF AG
Inventor: HOFFMANN GERHARD , KURTZ KARL-RUDOLF
Abstract: PROCEDIMIENTO PARA LA FABRICACION DE FORMAS DE RELIEVE RETICULADAS MEDIANTE POLIMERIZACION: EXPOSICION GRAFICA CON LUZ ACTINICA DE UNAS CAPAS QUE PUEDEN SER RETICULADAS MEDIANTE FOTOPOLIMERIZACION Y LAVADO DE LAS PARTES NO RETICULADAS DE ESTAS CAPAS CON DISOLVENTES REVELADORES. SE UTILIZAN DISOLVENTES REVELADORES CUYOS COMPONENTES BASICOS SON: HIDROCARBUROS, ALCOHOLES O CETONAS (CON 8 - 15 ATOMOS DE CARBONO), CICLICOS Y ALIFATICOS, NO SATURADOS SIMPLE O TRIPLE OLEFINICAMENTE Y RAMIFICADOS O NO RAMIFICADOS, O LAS MISMAS SUSTANCIAS RAMIFICADAS O NO RAMIFICADAS, NO SATURADAS O SATURADAS SIMPLE O TRIPLE OLEFINICAMENTE Y ACICLICAS.
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公开(公告)号:DK160595C
公开(公告)日:1991-09-02
申请号:DK124382
申请日:1982-03-19
Applicant: BASF AG
Inventor: HOFFMANN GERHARD , GRASER FRITZ , LEYRER REINHOLD J
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公开(公告)号:DK160339C
公开(公告)日:1991-07-29
申请号:DK124282
申请日:1982-03-19
Applicant: BASF AG
Inventor: HOFFMANN GERHARD , NEUMANN PETER
IPC: C07D209/46 , C07D209/50 , G03G5/06
Abstract: An electrophotographic recording medium which consists essentially of an electrically conductive base and a photosemiconductive double layer which comprises a first layer containing charge carrier-producing dyes, and a second layer containing one or more compounds which are charge carrier-transporting when exposed to light, wherein the charge carrier-producing dyes are those of the general formula (I) where R1, R2, R3 and R4 are each hydrogen or a non-ionic substituent, X is the radical of a methyleneactive compound, or of an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic amine or hydrazine, and Z is hydrogen, methyl or phenyl, and the production of this recording medium.
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公开(公告)号:CA1252330A
公开(公告)日:1989-04-11
申请号:CA443943
申请日:1983-12-21
Applicant: BASF AG
Inventor: BRONSTERT BERND , HOFFMANN GERHARD , LYNCH JOHN
Abstract: A layer of a photopolymerizable mixture for the production of relief plates and printing plates contain (a) one or more photopolymerizable olefinically unsaturated compounds, (b) one or more photoinitiators which, on exposure, initiate rapid photopolymerization in the layer, and (c) a combination, which on exposure does not initiate any appreciable photopolymerization in the layer and comprises (c1) a soluble acridinium, phenothiazinium, phenoxazinium or phenazinium dye and (c2) a mild reducing agent for the dye (c1). The layer gives an improved relief image (greater shadow well depths) in the production of relief plates, and is also advantageous in the production of gravure printing plates. On exposure, it undergoes a color change which facilitates evaluation of the exposed layers before development.
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48.
公开(公告)号:AU6553586A
公开(公告)日:1987-05-28
申请号:AU6553586
申请日:1986-11-20
Applicant: BASF AG
Inventor: HOFFMANN GERHARD , KOCH HORTS , SCHULZ GUENTHER
Abstract: The invention relates to a novel photosensitive recording material which can be developed in aqueous solvents after its imagewise irradiation with actinic light and which consists essentially of a dimensionally stable base (A) and of a photosensitive recording layer (B). The said photosensitive recording layer (B) contains from about 48 to about 85% by weight, based on the photosensitive recording layer (B) of one or more elastomeric graft copolymers (B1) which are selected from the group consisting of polyalkylene oxide - vinyl ester - graft copolymers whose vinyl ester structural units have been hydrolyzed to a degree of not less 50 mol.-% from about 0.01 to about 10% by weight, based on the photosensitive recording layer (B), of one or more photoinitiators (B2), and from about 5 to about 30% by weight, based on the photosensitive recording layer (B), of one or more photopolymerizable monomers (B3). In addition to these components, the photosensitive recording layer (B) might contain further assistants or additives. The novel photosensitive recording material is especially well suited for the production of lithographic printing plates, resists and relief plates, in particular relief printing plates. The invention is furthermore related to a process for preparing the novel photosensitive recording material by polymerizing vinylesters in the presence of polyalkylene oxides to yield polyalkylene oxide - vinylester - graft copolymers, hydrolyzing or transesterifying said polyalkylene oxide - vinylester - graft copolymers to yield the said elastomeric graft copolymer (B1), mixing the said elastomeric graft copolymers (B1) with the other components of the photosensitive recording layer (B), and forming the said photosensitive recording layer (B) from the mixture consisting of its components on the dimensionally stable base (A).
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公开(公告)号:NO870012D0
公开(公告)日:1987-01-02
申请号:NO870012
申请日:1987-01-02
Applicant: BASF AG
Inventor: HOFFMANN GERHARD , KURTZ KARL-RUDOLF
Abstract: Relief plates crosslinked by photopolymerization are produced by exposing layers which are crosslinkable by photopolymerization imagewise to actinic light and washing out the noncrosslinked parts of the layers with a developer, by a process in which the developer used contains, as an essential component, a branched or straight-chain, monoolefinically, diolefinically or triolefinically unsaturated acryclic or saturated or monoolefinically, diolefinically or triolefinically unsaturated cyclic aliphatic hydrocarbon, alcohol or ketone of 8 to 15 carbon atoms.
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公开(公告)号:DK1187D0
公开(公告)日:1987-01-02
申请号:DK1187
申请日:1987-01-02
Applicant: BASF AG
Inventor: HOFFMANN GERHARD , KURTZ KARL-RUDOLF
Abstract: Relief plates crosslinked by photopolymerization are produced by exposing layers which are crosslinkable by photopolymerization imagewise to actinic light and washing out the noncrosslinked parts of the layers with a developer, by a process in which the developer used contains, as an essential component, a branched or straight-chain, monoolefinically, diolefinically or triolefinically unsaturated acryclic or saturated or monoolefinically, diolefinically or triolefinically unsaturated cyclic aliphatic hydrocarbon, alcohol or ketone of 8 to 15 carbon atoms.
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