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    42.
    发明专利
    未知

    公开(公告)号：DE19546481C2

    公开(公告)日：1998-08-13

    申请号：DE19546481

    申请日：1995-12-13

    Applicant: DAIMLER BENZ AG ,  BASF AG

    Inventor： HARTWEG MARTIN ,  SEIBOLD ANDREA ,  WALZ LEONHARD ,  FETZER THOMAS ,  MORSBACH BERND

    IPC: B01D53/94 ,  B01J23/00 ,  B01J23/76 ,  B01J23/80 ,  B01J23/84 ,  B01J23/847 ,  B01J23/89

    Abstract: The catalyst comprises a spinel consisting of copper, zinc and aluminium. The spinel of formula CaaZnbAlcO4 is mixed with palladium, platinum, rhodium, ruthenium, osmium, iridium or rhenium and/or rare earth such as lanthanum and cerium, vanadium, titanium, niobium, molybdenum, tungsten and/or their salts; where a + b + c = 3 and a > 0, b > 0 and c > O. Also claimed is the production of the catalyst in which a spinel is produced from copper oxide, zinc oxide and aluminium oxide, and to the spinel is added Pd, Pt, Rh, Re, Os, Ir, Ru and/or rare earths, e.g. Ln and Ce, V, Ti, Mo, W and their salts and oxides. The spinel is preferably impregnated with cerium oxide in an amount of 0.5-15 wt.% especially 1-8 wt.%.

    43.
    发明专利
    未知

    公开(公告)号：DE19653200A1

    公开(公告)日：1998-06-25

    申请号：DE19653200

    申请日：1996-12-19

    Applicant: BASF AG ,  DAIMLER BENZ AG

    Inventor： FETZNER THOMAS DR ,  MORSBACH BERND ,  KUMBERGER OTTO DR ,  HARTWEG MARTIN DR ,  WALZ LEONHARD DR ,  ROITZHEIM ROLF-DIRC DR ,  SEIBOLD ANDREA

    IPC: B01D53/94 ,  B01J23/00 ,  B01J23/89 ,  F01N3/10 ,  B01D53/86 ,  F01N3/20

    Abstract: In accordance with the invention, for the reduction of NOx, in particular in burner gases, a catalyst is used consisting of: (a) 20-97 wt.% Al2O3, (b) 1-40 wt.% CuO, (c) 1-50 wt.% ZnO, (d) 1-40 wt.% Ag, (e) 0-2 wt.% Pt, (f) 0-20 wt.% oxides of rare earth metals, elements of the third subgroup of the periodic system or their mixtures, with relation to the total weight of components (a) to (e), which is 100 wt.% In this catalyst, up to half the weight of component (a) can be replaced by FE2O3, Cr2O3, Ga2O3 or their mixtures; up to half the weight of component (b) can be replaced by CoO; up to half the weight of component (c) can be replaced by MgO; up to half the weight of component (d) can be replaced by Au, and up to half the weight of component (e) can be replaced by Pd, Ru, Os, Ir, Rh, Re or their mixtures. Components (a), (b) and (c) form a spinel which can be doped with the components (d), (e) and (f).

    44.
    发明专利
    未知

    公开(公告)号：DE19635893A1

    公开(公告)日：1998-03-05

    申请号：DE19635893

    申请日：1996-09-04

    Applicant: BASF AG

    Inventor： MORSBACH BERND ,  HESSE MICHAEL DR

    IPC: B01D53/86 ,  B01D53/94 ,  B01J21/16 ,  B01J23/22 ,  B01J23/30 ,  B01J35/10 ,  B01J37/00 ,  B01D53/56

    Abstract: Supported catalyst composition comprises TiO2, WO3 and V2O5 or their precursors and has a bimodal pore size distribution in the regions of 5-30 nm and 45-100 nm, preferably 10-30 nm and 50-100 nm. The V2O5 is distributed on the larger pores of the bimodal pore size distribution. Production of the catalyst composition is also claimed.

    45.
    发明专利
    未知

    公开(公告)号：DE19546481A1

    公开(公告)日：1997-06-19

    申请号：DE19546481

    申请日：1995-12-13

    Applicant: DAIMLER BENZ AG ,  BASF AG

    Inventor： HARTWEG MARTIN ,  SEIBOLD ANDREA ,  WALZ LEONHARD ,  FETZER THOMAS ,  MORSBACH BERND

    IPC: B01D53/94 ,  B01J23/00 ,  B01J23/76 ,  B01J23/80 ,  B01J23/84 ,  B01J23/847 ,  B01J23/89

    Abstract: The catalyst comprises a spinel consisting of copper, zinc and aluminium. The spinel of formula CaaZnbAlcO4 is mixed with palladium, platinum, rhodium, ruthenium, osmium, iridium or rhenium and/or rare earth such as lanthanum and cerium, vanadium, titanium, niobium, molybdenum, tungsten and/or their salts; where a + b + c = 3 and a > 0, b > 0 and c > O. Also claimed is the production of the catalyst in which a spinel is produced from copper oxide, zinc oxide and aluminium oxide, and to the spinel is added Pd, Pt, Rh, Re, Os, Ir, Ru and/or rare earths, e.g. Ln and Ce, V, Ti, Mo, W and their salts and oxides. The spinel is preferably impregnated with cerium oxide in an amount of 0.5-15 wt.% especially 1-8 wt.%.

    50.
    发明专利
    未知

    公开(公告)号：ES2217891T3

    公开(公告)日：2004-11-01

    申请号：ES99973824

    申请日：1999-11-26

    Applicant: BASF AG

    Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND

    IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

    Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.

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