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公开(公告)号：EA012614B1
公开(公告)日：2009-10-30
申请号：EA200701506
申请日：2006-01-16
Applicant: BASF AG
Inventor： KLANNER CATHARINA , SCHINDLER GOTZ-PETER , CRONE SVEN , BORGMEIER FRIEDER , DUDA MARK , SIMON FALK
IPC: C07C5/333 , C07C11/167
Abstract: Способполучениябутадиенаизн-бутана, включающийследующиестадии: А) подготовкаисходногогазовогопотокаа, содержащегон-бутан; В) подачасодержащегон-бутанисходногогазовогопотокаа, поменьшеймере, впервуюзонудегидрированияи неокислительноекаталитическоедегидрированиен-бутана, причемполучаютгазовыйпотокпродукта b, содержащийн-бутан, 1-бутен, 2-бутен, бутадиен, водород, низкокипящиепримеси, приизвестныхусловияхоксидыуглеродаи приизвестныхусловияхводянойпар; С) подводгазовогопотокапродукта b неокислительногокаталитическогодегидрированияи кислородсодержащегогаза, поменьшеймере, вовторуюзонудегидрированияи окислительноедегидрированиен-бутана, 1-бутенаи 2-бутена, причемполучаютгазовыйпотокпродуктас, содержащийн-бутан, 2-бутен, бутадиен, низкокипящиепримеси, оксидыуглеродаи водянойпар, сболеевысокимсодержаниембутадиена, чемв газовомпотокепродукта b; D) отделениенизкокипящихпримесейи водяногопара, причемполучаетсягазовыйпотокС-продукта d, восновномсостоящийизн-бутана, 2-бутенаи бутадиена; E) разделениеэкстрактивнойректификациейгазовогопотокаС-продукта d напоток el, состоящийв основномизн-бутанаи 2-бутена, ипотокценногопродуктае2, восновномсостоящийизбутадиена; F) возвратпотока el впервуюзонудегидрирования.
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公开(公告)号：NO327435B1
公开(公告)日：2009-06-29
申请号：NO20044561
申请日：2004-10-22
Applicant: BASF AG
Inventor： HESSE MICHAEL , HARTH KLAUS , HOFSTADT OTTO , SCHINDLER GOTZ-PETER , SIMON FALK
IPC: B01J21/06 , B01J23/62 , B01J23/63 , B01J32/00 , B01J35/00 , B01J35/06 , B01J35/10 , B01J37/00 , C07B61/00 , C07C5/333 , C07C11/06
Abstract: The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.
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公开(公告)号：NO326855B1
公开(公告)日：2009-03-02
申请号：NO20032501
申请日：2003-06-03
Applicant: BASF AG
Inventor： HARTH KLAUS , SCHINDLER GOTZ-PETER , MAGIN WERNER
Abstract: A process for regenerating a dehydrogenation catalyst comprises the steps (a)-(f): (a) flushing with inert gas at a pressure of from 0.5 to 2.0 bar and a gas hourly velocity of from 1000 to 50 000 h -1 ; (b) passing an oxygen-containing gas mixture comprising an inert gas through the catalyst at a pressure of from 2 to 20 bar and a gas hourly velocity of from 1000 to 50 000 h -1 for from 0.25 to 24 hours while increasing the oxygen concentration stepwise or continuously from an initial value of from 0.01 to 1% by volume of O 2 to a final value of from 10 to 25% by volume of O 2 ; (c) optionally passing an oxygen-containing gas mixture comprising an inert gas through the catalyst at a pressure of from 0.5 to 20 bar and a gas hourly velocity of from 10 to 500 h -1 for from 0.25 to 100 h, with the oxygen concentration being from 10 to 25% by volume of O 2 ; (d) optionally changing the pressure repeatedly, rapidly and in opposite directions by a factor of from 2 to 20 within the range from 0.5 to 20 bar; (e) flushing with an inert gas; (f) activating the catalyst by means of hydrogen; where at least one of the steps (c) or (d) is carried out and the entire regeneration process is carried out at from 300 to 800° C.
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公开(公告)号：NO20074272L
公开(公告)日：2007-09-27
申请号：NO20074272
申请日：2007-08-22
Applicant: BASF AG
Inventor： SCHINDLER GOTZ-PETER , MACHHAMMER OTTO , CRONE SVEN , BORGMEIER FRIEDER
IPC: C07C5/327
Abstract: The invention relates to a process for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the feed gas stream a comprising propane, if appropriate steam and if appropriate and an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide, steam, if appropriate hydrogen and if appropriate oxygen; C) the product gas stream b is cooled, if appropriate compressed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) uncondensable or low-boiling gas constituents are removed by contacting the product gas stream c with an inert absorbent and subsequently desorbing the gases dissolved in the inert absorbent to obtain a C 3 hydrocarbon stream d 1 and an offgas stream d 2 comprising methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide, if appropriate hydrogen and if appropriate oxygen; E) the Ca hydrocarbon stream d 1 is cooled and if appropriate compressed to obtain a gaseous or liquid Ca hydrocarbon stream e 1; F) the C 3 hydrocarbon stream e 1 is if appropriate fed into a first distillation zone and separated distillatively into a stream f 1 composed of propane and propene and a stream f 2 comprising ethane and ethene; G) the stream e 1 or f 1 is fed into a (second) distillation zone and separated distillatively into a product stream g 1 composed of propene and a stream g 2 composed of propane, the stream g 2 being recirculated at least partially into the dehydrogenation zone.
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公开(公告)号：NO20072874A
公开(公告)日：2007-09-17
申请号：NO20072874
申请日：2007-06-06
Applicant: BASF AG
Inventor： SCHINDLER GOTZ-PETER , MACHHAMMER OTTO , CRONE SVEN
CPC classification number: C07C5/3337 , C07C7/04 , C07C11/06
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Patent Agency Ranking
公开(公告)号：NO20072637A
公开(公告)日：2007-09-04
申请号：NO20072637
申请日：2007-05-24
Applicant: BASF AG
Inventor： SCHINDLER GOTZ-PETER , MACHHAMMER OTTO , CRONE SVEN
CPC classification number: C07C5/3337 , C07C7/04 , C07C11/06
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47.发明专利
公开(公告)号：MX2007005043A
公开(公告)日：2007-06-19
申请号：MX2007005043
申请日：2005-11-16
Applicant: BASF AG
Inventor： FRITZ PETER MATTHIAS , SCHINDLER GOTZ-PETER , SIMON FALK , CRONE SVEN , BOLT HEINZ
Abstract: El objeto de la invencion es un procedimiento para la hidrogenacion completa de corrientes de sustancias en plantas para la produccion de alquenos por deshidrogenacion catalitica de alcanos livianos, asi como un dispositivo para la realizacion del procedimiento. Toda la corriente de hidrocarburo hacia el reactor de deshidrogenacion, que se compone de alcano fresco y alcano reciclado, es sometida todavia antes de entrar en el reactor de deshidrogenacion a una hidrogenacion completa de todos los hidrocarburos no saturados contenidos en ella. De este modo se alcanza reducir drasticamente la formacion de coque en el reactor de deshidrogenacion. La energia necesaria para el precalentamiento de la corriente de eductos a la temperatura de reaccion es reducida, puesto que la energia librada en la hidrogenacion exotermica permanece caso por completo en la corriente de hidrocarburo.
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公开(公告)号：NO20043872L
公开(公告)日：2004-09-15
申请号：NO20043872
申请日：2004-09-15
Applicant: BASF AG
Inventor： HARTH KLAUS , HIBST HARTMUT , SCHINDLER GOTZ-PETER , WALSDORFF CHRISTIAN
Abstract: The invention relates to a process for preparing 4-vinylcyclohexene, which comprises the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into at least one dehydrogenation zone and dehydrogenating n-butane to butadiene to give a product stream comprising butadiene, n-butane, possibly 1-butene and 2-butene and possibly water vapor and other secondary constituents, (C) feeding the product stream from dehydrogenation, if appropriate after separating off water vapor and secondary constituents, into a dimerization zone and catalytically dimerizing butadiene to give a product stream comprising 4-vinylcyclohexene, n-butane and possibly 1-butene, 2-butene and unreacted butadiene, and (D) separating off 4-vinylcyclohexene from the product stream from the dimerization and recirculating n-butane and possibly 1-butene, 2-butene and unreacted butadiene to the dehydrogenation zone.
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49.发明专利
公开(公告)号：AU2003277867A1
公开(公告)日：2004-04-23
申请号：AU2003277867
申请日：2003-09-18
Applicant: BASF AG
Inventor： SCHINDLER GOTZ-PETER , PETZOLDT JOCHEN , ADAMI CHRISTOPH , MACHHAMMER OTTO , MULLER-ENGEL KLAUS JOACHIM , MARTAN HANS , HECHLER CLAUS
IPC: B01J23/00 , B01J23/887 , C07C5/32 , C07C5/48 , C07C7/05 , C07C11/06 , C07C27/00 , C07C45/35 , C07C51/215 , C07C51/25 , C07C235/24 , C07C253/24 , C07C253/26 , C07C255/08 , C07D301/10
Abstract: In a process for preparing at least one partial oxidation and/or ammoxidation product of propylene, the propylene is obtained from crude propane by dehydrogenating and subjected in the presence of unconverted propane as a constituent of a gas mixture 2 which comprises a total C 4 -hydrocarbon content of
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公开(公告)号：CA2495290A1
公开(公告)日：2004-03-04
申请号：CA2495290
申请日：2003-08-14
Applicant: BASF AG
Inventor： SCHINDLER GOTZ-PETER , HARTH KLAUS
Abstract: The invention relates to an isothermal method for dehydrogenating alkanes to form corresponding alkenes on a catalyst bed containing a dehydrogenating catalyst. Said method is characterised in that the catalyst bed contains a catalytically inactive, inert diluting material. Preferably, said catalytically inactive, inert diluting material is selected from the group consisting of the oxides of the main groups II, III and IV, and the subgroup s III, IV and V, the mixtures thereof and nitrides and carbides of elements of the main groups III and IV, and preferably has a BET surface of
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