公开(公告)号：DE50103595D1

公开(公告)日：2004-10-21

申请号：DE50103595

申请日：2001-06-29

Applicant: BASF AG

Inventor： KAIBEL DR ,  STAMMER DR ,  STROEZEL MANFRED

IPC: B01J19/32

Abstract: In zig-zag sheet metal column packing, a proportion X of the openings has a spacing b which is no greater than 0.4a from a fold edge. The proportion X is at least 60%. Preferred Features: X is at least 80% or 90%. Dimension b is 0.3a or 0.2a at most. The angle of folding is 40-120 degrees , preferably 60-90 degrees . Openings take up 5-40%, preferably 10-20% of the folded area. Openings are rectangular with aspect ratio 5:1 to 1:1, preferably 3:1 to 2:1. The longer side of the opening, is parallel to the folded edges. In a packed column, folded edges of the packing include an angle of 20-70 degrees , preferably 30-45 degrees with the column axis.

公开(公告)号：DE59905169D1

公开(公告)日：2003-05-28

申请号：DE59905169

申请日：1999-11-13

Applicant: BASF AG

Inventor： OOST DR ,  STROEZEL MANFRED ,  ETZRODT DR ,  WELLER DR ,  KAIBEL DR ,  JAEDICKE DR

IPC: B01J31/12 ,  B01J19/18 ,  C07B61/00 ,  C07C45/67 ,  C07C45/68 ,  C07C45/70 ,  C07C49/203

Abstract: Preparation of unsaturated methyl ketones(I), from an unsaturated alcohol(II) and alkyl acetoacetate(III) in the presence of an organo-aluminum catalyst(IV) comprises: (a) supplying (II) and (IV) to a reactor with a distillation column, (b) making temperature to be 170-250 degrees C under elevated pressure, (c) dosing the mixture with (III) and (d) maintaining a constant (III) content of 0.1-10 wt.% during the reaction. Preparation of unsaturated ketones of formula (I) involves reaction of an unsaturated alcohol of formula (II) with an alkyl acetoacetate of formula (III), in presence of 0.1-5 mol. % (based on (II)) of an organo-aluminum compound catalyst (IV), with elimination and distillative separation of the alcohol R3OH formed in the reaction, in a reactor system provided with a distillation column. Reaction is carried out by: (a) supplying (I (which boils at less than 140 degrees C), without a solvent, and (IV) to the reaction vessel, (b) adjusting the temperature to a value as constant as possible in the range 170-250 degrees C under elevated pressure, (c) dosing the mixture with (III) and (d) maintaining a (III) content as constant as possible in the range 0.1-10 wt. % during the reaction. Dotted line = optional bond; R1 = Me or Et; R2, R3 = 1-4C alkyl.

公开(公告)号：SI0909750T1

公开(公告)日：2002-12-31

申请号：SI9830255

申请日：1998-10-12

Applicant: BASF AG

Inventor： OOST CARSTEN DR ,  STROEZEL MANFRED ,  ETZRODT HEINZ DR ,  BOCKSTIEGEL BERNHARD DR ,  JAEDICKE HAGEN DR ,  WELLER DIETMAR DR ,  LAUPICHLER LOTHAR DR ,  REIMER KLAUS

IPC: B01J31/22 ,  C07C45/67 ,  C07C49/203 ,  C07F5/06

公开(公告)号：DK0947493T3

公开(公告)日：2002-12-30

申请号：DK99105126

申请日：1999-03-26

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF DR ,  KAIBEL GERD DR ,  AQUILA WERNER DR ,  FUCHS HARTWIG ,  WEGNER GUENTER DR ,  STROEZEL MANFRED

IPC: B01J23/44 ,  B01J8/20 ,  B01J8/22 ,  B01J19/24 ,  B01J23/46 ,  C07B61/00 ,  C07C45/62 ,  C07C47/21 ,  C07C49/04

Abstract: Production of saturated carbonyl compounds (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds (II) is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. Production of saturated carbonyl compounds of formula R1-CH(R2)-CH(R3)-C(R4)=O (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds of formula R1-C(R2)=C(R3)-C(R4)=O (II) in the presence of a particulate palladium and/or rhodium catalyst and a base is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. R1 = H or an organic group; R2-R4 = H or 1-4C alkyl.

公开(公告)号：DE59903222D1

公开(公告)日：2002-12-05

申请号：DE59903222

申请日：1999-03-26

Applicant: BASF AG

Inventor： BROECKER DR ,  KAIBEL DR ,  AQUILA DR ,  FUCHS HARTWIG ,  WEGNER DR ,  STROEZEL MANFRED

IPC: B01J23/44 ,  B01J8/20 ,  B01J8/22 ,  B01J19/24 ,  B01J23/46 ,  C07B61/00 ,  C07C45/62 ,  C07C47/21 ,  C07C49/04

Abstract: Production of saturated carbonyl compounds (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds (II) is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. Production of saturated carbonyl compounds of formula R1-CH(R2)-CH(R3)-C(R4)=O (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds of formula R1-C(R2)=C(R3)-C(R4)=O (II) in the presence of a particulate palladium and/or rhodium catalyst and a base is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. R1 = H or an organic group; R2-R4 = H or 1-4C alkyl.

公开(公告)号：ES2172726T3

公开(公告)日：2002-10-01

申请号：ES97118174

申请日：1997-10-20

Applicant: BASF AG

Inventor： STROEZEL MANFRED ,  RHEUDE UDO DR ,  RAHN RALF-THOMAS DR ,  KAIBEL GERD DR

IPC: C07B49/00 ,  C07C29/124 ,  C07C29/40 ,  C07C31/00 ,  C07C33/02

Abstract: A process for carrying out exothermic reactions comprises (a) addition reaction of an organomagnesium halide of formula RMgX with a carbonyl compound; and (b) hydrolysis of the addition product in a solvent or solvent mixture, in which much of the heat liberated in the reaction is removed by evaporation of the solvent. R = 1-6C alkyl, alkenyl or alkynyl, or aryl; X = Cl, Br or I.

公开(公告)号：ES2172277T3

公开(公告)日：2002-09-16

申请号：ES99117101

申请日：1999-08-31

Applicant: BASF AG

Inventor： OOST CARSTEN DR ,  STROEZEL MANFRED ,  ETZRODT HEINZ DR ,  WELLER DIETMAR DR ,  BOCKSTIEGEL BERNHARD DR ,  REIMER KLAUS

IPC: B01J31/14 ,  B01D3/00 ,  B01D3/14 ,  B01D3/32 ,  B01J10/00 ,  B01J19/24 ,  C07B61/00 ,  C07C45/67 ,  C07C45/68 ,  C07C45/82 ,  C07C49/203 ,  C07C67/54 ,  C07C69/72

Abstract: Continuous production of 5-alken-2-one or 3,5-alkadien-2-one derivatives (I) by reacting a 1-alken-3-ol or 1-alkyn-3-ol derivative (II) with an alkyl acetoacetate (III) in a fractionation column to form an acetoacetate and alcohol involves (i) removing the alcohol and (ii) contacting the acetoacetate with catalyst in the lower part or bottom of the column to form (I). Continuous production of unsaturated ketones of formula (I) by reacting an unsaturated alcohol of formula (II) with an alkyl acetoacetate of formula (III) in the presence of an organoaluminum catalyst is carried out by: (a) reacting (II) with (III) on the plates of a fractionation column to form the acetoacetate of (II) and an alcohol of formula R OH; (b) removing the alcohol in the overhead stream from the column; (c) contacting the acetoacetate of (II) with the catalyst in the lower part or bottom of the column to form (I) and CO2; (d) removing the CO2 in the overhead stream from the column; and (e) withdrawing (I) in the bottoms stream from the column. R = 1-4C alkyl; R = 1-37C (un)saturated aliphatic hydrocarbyl (optionally substituted by methoxy groups), 4-12C cycloalkyl or 5-30C cycloalkylalkyl; and R = 1-5C alkyl.

公开(公告)号：AU8989701A

公开(公告)日：2002-04-02

申请号：AU8989701

申请日：2001-09-19

Applicant: BASF AG

Inventor： KAIBEL GERD ,  OOST CARSTEN ,  STROEZEL MANFRED ,  MEYER GERALD ,  TRUBENBACH PETER ,  SARTOR KARL-HEINZ ,  HENERS JURGEN

IPC: B01D3/14 ,  B01D3/32 ,  B01D3/42 ,  C07B63/00 ,  C10G7/00 ,  C10G7/02 ,  C10G7/12

Abstract: A process is proposed for the separation of C 5+ cuts by distillation into a low-boiler (A), a medium-boiler (B) and a high-boiler fraction (C) in one or more dividing-wall columns (TK), in which a dividing wall (T) is arranged in the longitudinal direction of the column with formation of an upper, common column region ( 1 ), a lower, common column region ( 6 ), a feed part ( 2, 4 ) with rectifying section ( 2 ) and stripping section ( 4 ), and a withdrawal part ( 3, 5 ) with rectifying section ( 5 ) and stripping section ( 3 ), with feed of the C 5+ cut (A, B, C) into the central region of the feed part ( 2, 4 ), discharge of the high-boiler fraction (C) from the bottom of the column, discharge of the low-boiler fraction (A) via the top of the column, and discharge of the medium-boiler fraction (B) from the central region of the withdrawal part ( 3, 5 ), wherein the dividing ratio of the liquid reflux at the upper end of the dividing wall (T) is set in such a way that the proportion of high-boiling key components in the liquid reflux over the stripping section ( 3 ) of the withdrawal part at the upper end of the dividing wall (T) is from 10 to 80%, preferably from 30 to 50%, of the limit value allowed in the medium-boiler fraction (B), and wherein the heating power in the evaporator at the bottom of the dividing-wall column (TK) is set in such a way that the concentration of the low-boiling key components in the liquid at the lower end of the dividing wall (T) is from 10 to 80%, preferably from 30 to 50%, of the limit value allowed in the medium-boiler fraction (B).

公开(公告)号：DE59706425D1

公开(公告)日：2002-03-28

申请号：DE59706425

申请日：1997-10-20

Applicant: BASF AG

Inventor： STROEZEL MANFRED ,  RHEUDE DR ,  RAHN DR ,  KAIBEL DR

IPC: C07B49/00 ,  C07C29/124 ,  C07C29/40 ,  C07C31/00 ,  C07C33/02

Abstract: A process for carrying out exothermic reactions comprises (a) addition reaction of an organomagnesium halide of formula RMgX with a carbonyl compound; and (b) hydrolysis of the addition product in a solvent or solvent mixture, in which much of the heat liberated in the reaction is removed by evaporation of the solvent. R = 1-6C alkyl, alkenyl or alkynyl, or aryl; X = Cl, Br or I.

公开(公告)号：DE59900446D1

公开(公告)日：2002-01-10

申请号：DE59900446

申请日：1999-03-05

Applicant: BASF AG

Inventor： RUFF DR ,  BURST WOLFRAM ,  KAISER DR ,  STROEZEL MANFRED

IPC: C07C45/72 ,  C07C45/74 ,  C07C49/603

Abstract: 2,5,6-trimethyl-cyclohex-2-en-1-one (I) is prepared by continuously pumping diethylketone (II), crotonaldehyde (III) and an aqueous strong base through a pressure vessel in such a fashion that the reaction temperature is 150-350 degrees C and the average residence time in the pressure vessel is only 0.1 seconds to 20 minutes. Preparation of 2,5,6-trimethyl-cyclohex-2-en-1-one (I) comprises reaction of (i) diethylketone (II) with (ii) crotonaldehyde (III) (or a compound which is converted to (III) under the selected reaction conditions), in the presence of basic agents, at elevated temperatures. Component (ii) (1 mol), component (i) (5-30 mol) and an aqueous solution or suspension of a strong base are pumped continuously, via separate supply points or in the form of a mixture, into an optionally heated pressure vessel which can guarantee intensive mixing. The components are pumped to the vessel in such a fashion that the reaction temperature is 150-350 degrees C and the average residence time in the pressure vessel is only 0.1 seconds to 20 minutes.