Acrylate polymers based on tert-butyl acrylate and/or tert-butyl methacrylate

    公开(公告)号:AU2183002A

    公开(公告)日:2002-05-21

    申请号:AU2183002

    申请日:2001-11-09

    Applicant: BASF AG

    Abstract: The invention relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30° C., with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 14 to C 22. The invention also relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30° C., with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 10 to C 22 followed by a hydrogen peroxide treatment. The invention also relates to the use of these acrylate polymers as film formers as well as to their use in cosmetic preparations.

    ACRYLATE POLYMERS BASED ON TERT-BUTYL ACRYLATE AND/OR TERT-BUTYL METHACRYLATE

    公开(公告)号:CA2428309C

    公开(公告)日:2010-01-12

    申请号:CA2428309

    申请日:2001-11-09

    Applicant: BASF AG

    Abstract: The invention relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 w t. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monome r A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monom er B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radical ly copolymerizable monomer mixture designated as monomer C, whereby at least on e of monomers C yields a homopolymer with a glass-transition temperature lower than 30 ~C, with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chai n length of C 14 to C 22. The invention also relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert - butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30 ~C, with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 10 to C 22 followed by a hydrogen peroxide treatment. The invention also relates to the use of these acrylate polymers as film formers as well as to their use in cosmetic preparations.

    47.
    发明专利
    未知

    公开(公告)号:BRPI0607038A2

    公开(公告)日:2009-12-01

    申请号:BRPI0607038

    申请日:2006-01-24

    Applicant: BASF AG

    Abstract: The present invention relates to the use of, if appropriate present in the form of an aqueous dispersion, polymers of ethylenically unsaturated anionic monomers for modifying the rheology of aqueous, alcoholic or aqueous/alcoholic cosmetic or dermatological compositions. The polymers are obtainable by free-radical emulsion copolymerization of water-soluble inorganic monomers in aqueous phase in the presence of, in each case, at least one stabilizing polymer of groups a) and b). The emulsion polymers are exceptionally suitable for thickening cosmetic or dermatological preparations based either on water or on alcohols.

    POLIMEROS CATIONICOS Y SU EMPLEO EN FORMULACIONES COSMETICAS.

    公开(公告)号:ES2286419T3

    公开(公告)日:2007-12-01

    申请号:ES03714814

    申请日:2003-03-13

    Applicant: BASF AG

    Abstract: Empleo de polímeros catiónicos obtenibles mediante polimerización de un 3 a un 30% en peso de al menos un monómero que contiene nitrógeno cuaternario, polimerizable a través de radicales (a1), y/o un producto previo directo (a2) del mismo, en presencia de un 70 a un 97% en peso de al menos un compuesto que contiene poliéter (b), seleccionado a partir del grupo constituido por compuestos de la fórmula general I (Ver fórmula) en la que las variables, independientemente entre sí, tienen el siguiente significado: R 1 hidrógeno, alquilo con 1 a 24 átomos de carbono, R 6 -C(=O)-, R 6 -NH-C(=O)-, resto polialcohol; R 5 hidrógeno, alquilo con 1 a 24 átomos de carbono, R 6 -C(=O)-, R 6 -NH-C(=O)-; R 2 a R 4 , independientemente entre sí, representan -(CH2)2-, -(CH2)3-, -(CH2)4-, -CH2-CH(R 6 )-, -CH2-CHOR 7 -CH2; R 6 alquilo con 1 a 24 átomos de carbono; R 7 hidrógeno, alquilo con 1 a 24 átomos de carbono, R 6 -C(=O)-, R 6 -NH-C(=O)-; A -C(=O)-O, -C(=O)-B-C(=O)-O, -CH2-CH(-OH)-B-CH(-OH)-CH2-O, -C(=O)-NH-B-NH-C(=O)-O, (Ver fórmula) B -(CH2)t -, arileno, en caso dado substituido; R 30 , R 31 , independientemente entre sí, representan hidrógeno, alquilo con 1 a 24 átomos de carbono, hidroxialquilo con 1 a 24 átomos de carbono, bencilo o fenilo; n 1 si R 1 no es un resto polialcohol, o n 1 a 1000 si R 1 es un resto polialcohol s 0 a 1000; t 1 a 12; u 1 a 5000; v 0 a 5000; w 0 a 5000; x 0 a 5000; y 0 a 5000; z 0 a 5000, derivados de silicona que contienen poliéter, y productos de reacción de polietileniminas con óxidos de alquileno, en caso dado un 0 a un 15% en peso de uno o varios monómeros polimerizables a través de radicales adicionales (c) con una solubilidad en agua por encima de 60 g/l a 25ºC, y en caso dado un 0 a un 15% en peso de uno o varios monómeros polimerizables a través de radicales adicionales (d) con una solubilidad en agua por encima de 60 g/l a 25ºC.

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