公开(公告)号：EP1989173A1

公开(公告)日：2008-11-12

申请号：EP07712212.5

申请日：2007-02-13

Applicant: BASF SE

Inventor： VAN LAAR, Frederik ,  SCHWAB, Ekkehard ,  ANDERS, Joachim-Thierry ,  CRONE, Sven ,  HÖLEMANN, Karl ,  MACKENROTH, Wolfgang ,  KUBANEK, Petr

IPC: C07C209/02

CPC classification number: C07C209/02 ,  C07C211/46

Abstract: Disclosed is a method for aminating hydrocarbons with ammonia. Said method is characterized in that the N2 concentration in the mixture at the reactor outlet is less than 0.1 percent by volume relative to the total volume of the mixture at the reactor outlet (Formula (I)).

Abstract translation: 公开了用氨胺化烃的方法。 所述方法的特征在于，相对于反应器出口处的混合物的总体积（式（I）），反应器出口处混合物中的N 2浓度小于0.1体积％。

公开(公告)号：EP2780109B1

公开(公告)日：2016-04-13

申请号：EP12784011.4

申请日：2012-11-13

Applicant: BASF SE

Inventor： HEIDEMANN, Thomas ,  KUBANEK, Petr ,  COELHO TSOU, Joana ,  BAAS, Heiko

IPC: B01J23/14 ,  B01J23/835 ,  B01J37/02 ,  C07C211/00 ,  C07C213/00

CPC classification number: B01J23/14 ,  B01J23/835 ,  B01J37/0203 ,  B01J37/0213 ,  C07C51/418 ,  C07C227/14 ,  C07C229/76 ,  Y02P20/582 ,  C07C59/06 ,  C07C59/08 ,  C07C59/01 ,  C07C57/145 ,  C07C55/06 ,  C07C55/08 ,  C07C55/10 ,  C07C55/12 ,  C07C55/14 ,  C07C59/255 ,  C07C59/265

公开(公告)号：EP2451769B1

公开(公告)日：2015-01-07

申请号：EP10729890.3

申请日：2010-07-08

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  PANCHENKO, Alexander ,  FISCHER, Andreas ,  HEIDEMANN, Thomas

IPC: C25B3/00 ,  C07C209/02

CPC classification number: C07C209/02 ,  C25B3/00 ,  Y02P20/582 ,  C07C211/46

公开(公告)号：EP2451769A2

公开(公告)日：2012-05-16

申请号：EP10729890.3

申请日：2010-07-08

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  PANCHENKO, Alexander ,  FISCHER, Andreas ,  HEIDEMANN, Thomas

IPC: C07C209/02

CPC classification number: C07C209/02 ,  C25B3/00 ,  Y02P20/582 ,  C07C211/46

Abstract: The invention relates to a method for the direct amination of hydrocarbons to form amino hydrocarbons, comprising the following steps: conversion of an educt flow E containing at least one hydrocarbon and at least one amination reagent into a reaction mixture R containing amino hydrocarbons and hydrogen, and b) electrochemical separation of at least part of the hydrogen created during the conversion, from the reaction mixture R, by means of a gas-tight membrane electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane. On the retenate side of the membrane, at least part of the hydrogen is oxidised on the anode catalyst to form protons and, after passing through the membrane, on the permeate side, on the cathode catalyst, the protons are b1) reduced to hydrogen and/or b2) converted to water with oxygen, the oxygen originating from a flow O containing oxygen, brought into contact with the permeate side of the membrane.

公开(公告)号：EP2225030B1

公开(公告)日：2012-04-18

申请号：EP08864424.0

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/835 ,  B01J23/843 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J23/835 ,  B01J23/002 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/44 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/53 ,  B01J2523/43 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing, copper-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, copper, nickel, 0.2 to 40% by weight of oxygen-containing compounds of cobalt, calculated as CoO, 0.1 to 5% by weight of oxygen-containing compounds of iron, calculated as Fe2O3, and 0.1 to 5% by weight of oxygen-containing compounds of lead, tin, bismuth and/or antimony, each calculated as PbO, SnO, Bi2O3 or Sb2O3. The invention also relates to catalysts of the above type.

公开(公告)号：EP2043996A1

公开(公告)日：2009-04-08

申请号：EP07765787.2

申请日：2007-07-04

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  HOFFER, Bram Willem ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till

IPC: C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08 ,  C07D295/02 ,  B01J23/89 ,  B01J23/825 ,  B01J23/835 ,  B01J23/843

CPC classification number: C07C209/16 ,  B01J23/002 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/26 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/54 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/33 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group comprising ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing catalyst and a nickel-containing catalyst. The invention is characterised in that the catalytically active weight of the catalyst, prior to reduction with hydrogen, contains oxygen-containing compounds of zirconium, copper, nickel and cobalt and oxygen-containing compounds of one or more metals, selected from Pb, Bi, Sn, Sb and In.

Abstract translation: 本发明涉及一种通过伯或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在二氧化锆 - 二氧化锆存在下反应制备胺的方法， 含镍催化剂和含镍催化剂。 本发明的特征在于，催化剂的催化活性重量在用氢还原之前含有锆，铜，镍和钴的含氧化合物和一种或多种选自Pb，Bi， Sn，Sb和In。

公开(公告)号：EP2043779A1

公开(公告)日：2009-04-08

申请号：EP07787039.2

申请日：2007-07-04

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  HOFFER, Bram Willem ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till

IPC: B01J23/89 ,  C07C209/26 ,  C07D295/02

CPC classification number: B01J23/8926 ,  B01J37/03 ,  B01J37/14 ,  B01J37/18 ,  C07C213/02 ,  C07D295/023

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group comprising ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing catalyst and a nickel-containing catalyst. The catalytically active weight of the catalyst, prior to reduction with hydrogen, contains oxygen-containing compounds of zirconium, copper, nickel and cobalt and 0,5 to 6 wt.-% oxygen-containing compounds of silver, calculated as AgO.

公开(公告)号：EP1989172A1

公开(公告)日：2008-11-12

申请号：EP07704599.5

申请日：2007-02-15

Applicant: BASF SE

Inventor： VAN LAAR, Frederik ,  SCHWAB, Ekkehard ,  ANDERS, Joachim-Thierry ,  CRONE, Sven ,  HÖLEMANN, Karl ,  MACKENROTH, Wolfgang ,  KUBANEK, Petr

IPC: C07C209/02

CPC classification number: C07C209/02

Abstract: A process for aminating hydrocarbons with ammonia in the presence of catalyst (i) which catalyzes the amination, characterized in that oxidizing agent is supplied to the reaction mixture and the oxidizing agent is reacted with hydrogen which is formed in the amination in the presence of a catalyst (H) which catalyzes this reaction with hydrogen.

公开(公告)号：EP1937625A1

公开(公告)日：2008-07-02

申请号：EP06793775.5

申请日：2006-09-25

Applicant: BASF SE

Inventor： HOFFER, Bram Willem ,  EVERS, Holger ,  KUBANEK, Petr ,  GERLACH, Till ,  MELDER, Johann-Peter ,  FUNKE, Frank ,  FRAUENKRON, Matthias ,  SCHMIDTKE, Helmut

IPC: C07C213/02

CPC classification number: C07D295/023 ,  C07C213/02 ,  C07C217/08

Abstract: A method for preparing aminodiglycol (ADG) and morpholine by reaction of diethyleneglycol (DEG) with ammonia in the presence of a transition metal heterogeneous catalyst is characterised in that the catalytically active mass of the catalyst contains, before treatment with hydrogen, oxygen-containing compounds of aluminium and/or zirconium, copper, nickel and cobalt, and in that the catalyst moulding in pellet or strand form has a diameter of

公开(公告)号：EP1924355A1

公开(公告)日：2008-05-28

申请号：EP06778285.4

申请日：2006-08-21

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  SCHWAB, Ekkehard ,  VAN LAAR, Frederik ,  MACKENROTH, Wolfgang

IPC: B01J21/18 ,  B01J23/89 ,  B01J37/16 ,  B01J37/02 ,  C07C209/00

CPC classification number: C07C209/36 ,  B01J21/18 ,  B01J23/892 ,  B01J23/8953 ,  B01J37/0201 ,  B01J37/16 ,  Y02P20/52 ,  C07C211/50

Abstract: The invention relates to a method for producing aromatic amines by catalytically hydrogenating the corresponding nitro compounds, in particular, for producing toluylene diamine by hydrogenating dinitrotoluene. The invention is characterised in that hydrogenation catalysts are used in which a mixture of platinum, nickel and an additional metal are provided as active components.