Abstract:
The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
Abstract:
La presente invención se refiere a un material estructural o de entramado, orgánico, de metal poroso, formado de iones de Mg2+ el cual se enlaza en forma coordinada mediante iones de 5-terc-butilisoftalato, durante la formación de una estructura de entramado. La invención también se refiere a métodos para la producción y aplicación de la misma, por ejemplo, para el almacenamiento, separación, o liberación controlada de una sustancia tal como un gas o mezcla de gases.