公开(公告)号：JP2002069068A

公开(公告)日：2002-03-08

申请号：JP2000258770

申请日：2000-08-29

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  TANAKA TOSHINORI ,  TAWARA HIDEO ,  NAGUMO HIROSHI

IPC: C07D317/24 ,  C07B61/00 ,  C07C67/297 ,  C07C69/003 ,  C07C69/58

Abstract: PROBLEM TO BE SOLVED: To provide a method simply and effectively preparing a high purity monoglyceride ketal a component of fat and fatty acid and a method of preparing a monoglyceride a component of fat and fatty acid by using the same. SOLUTION: This method prepares a monoglyceride ketal expressed by general formula (3) by reacting fat, a ketone or an aldehyde and glycerins in the presence of a catalyst and a method preparing monoglyceride expressed by general formula (4) by carrying out a deketalization of the monoglyceride ketal obtained therefrom [R1 is a 5-23C saturated or unsaturated hydrocarbon group, R2 and R3 are each H, a linear or branched 1-22C alkyl or an alkenyl group or a 6-30C aryl group optionally having an alkyl substituent and the sum of the carbon atoms of R2 and R3>=3].

公开(公告)号：JP2001131100A

公开(公告)日：2001-05-15

申请号：JP2000203393

申请日：2000-07-05

Applicant: KAO CORP

Inventor： TAWARA HIDEO ,  TANAKA TOSHINORI ,  OMAE KAORU ,  IMANAKA TAKEHIRO ,  NAGUMO HIROSHI

IPC: B01J29/04 ,  C07B61/00 ,  C07C29/10 ,  C07C31/42 ,  C07C41/26 ,  C07C43/178 ,  C07C67/29 ,  C07C69/30

Abstract: PROBLEM TO BE SOLVED: To provide a method for industrially simply and efficiently deprotecting a compound in which a specific hydroxy group of a polyhydric alcohol or its derivative is protected with a ketal or an acetal. SOLUTION: In producing a polyhydroxy compound of formula (II) (X is R3O or a halogen; A is a 2-4C alkylene group; n is a number of 0-100) by deprotecting a compound of (I), (R1 and R2 are each H, a 1-22C alkyl group or the like; R3 is H or a 1-23C aliphatic hydrocarbon group, a 1-22C aliphatic acyl group or the like), the deprotection is carried out by bringing the compound into contact with steam is the presence of a solid acid catalyst.

公开(公告)号：JP2000344705A

公开(公告)日：2000-12-12

申请号：JP15797099

申请日：1999-06-04

Applicant: KAO CORP

Inventor： MURATA DAIYA ,  IMANAKA TAKEHIRO ,  NAGUMO HIROSHI

IPC: C07C41/28 ,  C07C41/16 ,  C07C43/10

Abstract: PROBLEM TO BE SOLVED: To provide a process for producing diglycerol having high purity by using glycerol ketal or acetal as a raw material. SOLUTION: This process for the production of diglycerol contains a step to produce diglycerol ketal or acetal expressed by formula III (R1, R2, R3 and R4 are each same or different hydrogen atom or a hydrocarbon group; when R1 and R2 or R3 and R4 are each hydrocarbon group, R1 and R2 or R3 and R4 may together form a carbon ring) by reacting a glycerol ketal or acetal compound with sulfuric acid ester salt of glycerol ketal or acetal and a step to obtain the diglycerol by removing ketal or acetal from the diglycerol ketal or acetal.

公开(公告)号：JPH10137592A

公开(公告)日：1998-05-26

申请号：JP30161096

申请日：1996-11-13

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  TANAKA TOSHINORI ,  TAWARA HIDEO ,  NAGUMO HIROSHI

IPC: B01J31/26 ,  C07B61/00 ,  C07C67/26 ,  C07C69/16 ,  C07C69/28

Abstract: PROBLEM TO BE SOLVED: To produce an ester alkoxylate with little amt. of unreacted source material and by-products with a high reaction rate and high yield by using a catalyst containing an org. acid salt of alkali metal, alkaline-earth metal or rare earth metal and multiple metal oxide of MgO and Al2 O3 . SOLUTION: This catalyst is used for the production of ester alkoxylate having one group expressed by -COO(AO)m R which is produced by adding 2 to 4C alkylene oxide to an ester compd. having one group expressed by -COOR. The catalyst is prepared by incorporating on org. acid salt of alkali metal, alkaline-earth metal or rate earth metal and a multiple metal oxide of MgO and Al2 O3 . In the formula, R is a residue of alcohol or phenol from which one hydroxyl group is removed, A is 2 to 4C alkylene group, and (m) As may be same different, and (m) is the average moles of the alkylene oxide added.

公开(公告)号：JPH1099693A

公开(公告)日：1998-04-21

申请号：JP25621496

申请日：1996-09-27

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  TANAKA TOSHINORI ,  TAWARA HIDEO ,  NAGUMO HIROSHI

IPC: C07D303/16 ,  B01J23/02 ,  B01J23/10 ,  B01J31/26 ,  B01J31/38 ,  C07B61/00 ,  C07C69/30

Abstract: PROBLEM TO BE SOLVED: To narrow additional molar number distribution and to reduce unreacted materials in reacted products by allowing a catalyst with which an ester alkoxylate is manufactured by adding an alkylene oxide to an ester compound to contain a compound of an alkali metal and the like and a metal oxide of Ti and the like. SOLUTION: In a catalyst used for manufacturing an ester alkoxylate having one group represented by the formula II (R is an alcohol or a residue obtained by removing one hydroxyl group from phenol, A is a 2-4 alkylene group and m is a mean additional molar number of an alkylene oxide) by adding an alkylene oxide to an ester compound (methyl laurate or the like) having one group represented by the constitutional formula I, the catalyst is allowed to contain a compound (1) (barium laurate and the like) selected from the group consisting of alkali metals, hydroxides of alkali earth metals or rare earth metals, oxides, organic acid salt or alcholate and a metal oxide (titanium oxide and the like) (2) containing at least one kind of atoms selected from the group consisting of alkali earth metals, Zr, Ti, and Al.

公开(公告)号：JPH06279352A

公开(公告)日：1994-10-04

申请号：JP9525393

申请日：1993-03-29

Applicant: KAO CORP

Inventor： KIMURA HIROSHI ,  IMANAKA TAKEHIRO ,  YOKOTA YUKINAGA

IPC: B01J23/44 ,  B01J23/56 ,  B01J23/62 ,  B01J23/63 ,  B01J23/64 ,  B01J23/644 ,  B01J27/057 ,  C07B61/00 ,  C07C51/235 ,  C07C59/245

Abstract: PURPOSE:To produce tartronate salt in high a yield by catalytic oxidation of glycerol with an oxidizing agent in the presence of a specific metal catalyst on a carrier. CONSTITUTION:In the presence of a catalyst which comprises (A) the first component of Pd, (B) the second component of one or more selected from Sn, Pb, Sb, Bi, Se and Te, and (C) the third component of one or more of Pt, rare earth elements where the B/A molar ratio is 0.01 to 2 in A+B; the C/A molar ratio is 0.1 to 2 in A+C; B/A and C/A molar ratios are 0.01 to 2 in A +B+C, respectively; and the composition or only A are supported on a carrier such as activated carbon, carbon black or calcium carbonate or silica, glycerol or glyceric acid (or its salt) is catalytically oxidized with an oxidizing agent such as air, oxygen or an oxygen and nitrogen mixture gas to give tartronate salt. The amount of the first component supported on the carrier is 2 to 4wt.% in the single component, while 1 to 10wt.% in combination.

公开(公告)号：JPH05339200A

公开(公告)日：1993-12-21

申请号：JP14919592

申请日：1992-06-09

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  TERASAKI HIROYUKI ,  FUJIO AKIRA

IPC: C07C51/02 ,  C07C51/235 ,  C07C51/41 ,  C07C51/43 ,  C07C59/10

Abstract: PURPOSE:To efficiently provide the subject compound useful as an intermediate raw material for organic synthesis leading to medicines, etc. CONSTITUTION:An impure-contg. glyceric acid alkaline earth metal salt, including the salt converted from impurity-contg. glyceric acid or salt thereof (except alkaline earth metal salt), is crystallized to eliminate the impurities followed by recovering the glyceric acid alkaline earth metal salt; and, if needed, an acid is added to this salt to produce glyceric acid, or salt exchange reaction is made, thus affording the objective glyceric acid or a salt thereof improved in purity.

公开(公告)号：JPH05331099A

公开(公告)日：1993-12-14

申请号：JP13349992

申请日：1992-05-26

Applicant: KAO CORP

Inventor： TERASAKI HIROYUKI ,  IMANAKA TAKEHIRO ,  FUJIO AKIRA ,  YOKOTA YUKINAGA

IPC: B01J23/02 ,  B01J23/42 ,  B01J23/44 ,  B01J31/08 ,  B01J31/12 ,  C02F1/62 ,  C07B61/00 ,  C07C51/41 ,  C07C59/01 ,  C07C59/10 ,  C07C59/125 ,  C07C59/235 ,  C09K3/00 ,  C11D3/20

Abstract: PURPOSE:To enable industrially advantageous production of a new glyceric acid derivative which is useful as a water-soluble metal dispersant or a chelating agent by reaction of glyceric acid with a specific halogen-substituted aliphatic carboxylic acid chloride in the presence of an alkaline substance followed by salt interchange. CONSTITUTION:The reaction of glyceric acid of formula I (R is H, cationic group, 1 to 5C alkyl) such as DL-glyceric acid) with a compound of formula II [A is halogen; R is H, formula: COOM (M is alkali, alkaline earth metal or ammonium or 1 to 36C alkylammonium), formula: CH2COOM; is 1-20C alkylene; n is 1, 0] such as sodium monochloracetate is effected in the presence of an alkaline substance such as tetrabutylammonium bromide to give the objective glyceric acid derivative of formula III [X, Y is H, group of formula IV and group of formula V (R is 2 to 3C alkylene; p is 0 to 10)].

公开(公告)号：JPH05148203A

公开(公告)日：1993-06-15

申请号：JP31605991

申请日：1991-11-29

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  SAWADA HIROKI ,  FUJIO AKIRA ,  YOKOTA YUKINAGA

IPC: C11D1/10 ,  C07C231/02 ,  C07C233/47 ,  C07C233/49

Abstract: PURPOSE:To provide a new compound mild to the skin, excellent in hard water resistance and useful as an excellent surfactant. CONSTITUTION:Compounds of formula I (R is a 1-21C alkyl or alkenyl; M is H, an alkaline metal ion, ammonium ion, a basic amino acid, etc. (n) is 1-2), e.g. N-(1,2-dicarboxyethyl)-N-lauroyl-glutamic acid 4-sodium salt. The compound of formula I is obtained by reacting a compound of formula II (E is a 1-5C alkyl) with a maleic acid diester of formula III, then reacting the resultant compound of formula IV with a compound of formula RCOX (X is OH, a halogen, a 1-5C alkoxy, etc.) and further hydrolyzing the resultant compound of formula V.

公开(公告)号：JPH05140031A

公开(公告)日：1993-06-08

申请号：JP30630491

申请日：1991-11-21

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  MIZUSHIMA YOUSEN ,  FUJIO AKIRA ,  YOKOTA YUKINAGA

IPC: B01F17/00 ,  C07C59/305 ,  C11D1/08

Abstract: PURPOSE:To obtain a new carboxylic acid or its salt, excellent in curing resistance and foaming properties and useful as a surfactant capable of contributing to improvement in detergency. CONSTITUTION:A carboxylic acid expressed by formula 1 [R is 3-22C straight- chain or branched chain alkyl or alkenyl; M to M are H, alkali metal, ammonium, 2-9C alkanolammonium, 1-5C alkyl-substituted ammonium or basic amino acid group; M and M together form alkaline earth metal; (m) is 1-9] or its salt, e.g. trisodium carboxymethyloxy-decylmalonate. The compound expressed by formula 1 is obtained by reacting, e.g. a compound expressed by formula 2 as a starting raw material with halogen molecules X2, providing a compound expressed by formula 3, then hydrolyzing the resultant compound with an alkali metallic hydroxide, affording a compound expressed by formula 4, subsequently reacting a compound expressed by formula (c) or (d), providing a compound expressed by formula 5, finally hydrolyzing the compound expressed by formula 5 and, as necessary, carrying out salt exchange.